CAS: 13537-18-3; Thulium(Iii) Chloride

该化合物是一种无机化合物,由+3氧化状态的组成,通常以无水或六氢化物形式提供,通常作为湿性固体,通常以无水或六氢化物形式提供,因其在专门应用中的作用而得到重视,包括在激光和光学设备中作为硫酸材料合成的前体,其高纯度和再活性使其适合研究稀土化学和催化.TmCl3还用于通过减少过程生产金属.建议,由于水分敏感,在惰性条件下进行适当处理.

结构式图片

相似化合物

1331-74-4 19423-86-0 114363-74-5

欧盟法规

ECHA物质ECHA物质C&L通报REACH预注册

上下游产品

aluminium trichloride hydrogenchloride chlorine thulium(III) chloride hydratethulium

合成工艺路线路线简述

    Thulium(III) Chloride Hexahydrate 反应生成氯化铥(III)
    参考文献:二价稀土的新混合卤化物化合物m F X(m = Sm,Eu,Tm和yb;X = Cl,Br和i)
    标题:二价稀土的新混合卤化物化合物m F X(m = Sm,Eu,Tm和yb;X = Cl,Br和i)
    摘要:据报道合成了新的二价稀土混合卤化物化合物m F X(m = Sm,Eu,Tm,Yb; X = Cl,Br,I).给出了这些化合物的晶格参数和x射线衍射图,所有这些化合物均以四方pbfcl型排列形式结晶.讨论了这种结构类型内的几何变化及其与fesi 2结构的关系.
    Doi:10.1016/0022-4596(78)90067-1

    专利信息


    专利号:US-11926589-B2
    优先权日:2019-07-09
    标 题 :Process for the synthesis of non-racemic cyclohexenes
    发明人:REISMAN SARAH; ROMBOLA MICHAEL; LADD CAROLYN L; MCLAUGHLIN MARTIN JOHN; ZUEND STEPHAN; GOETZ ROLAND
    权利人:BASF CORP; CALIFORNIA INST OF TECHN
    摘要:This invention relates to a process for the synthesis of a non-racemic cyclohexene compound of formula (I) by a Diels-Alder reaction of a compound of formula (II) with a compound of formula (III) wherein R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 and Y have the meanings as defined in the description in the presence of a catalyst comprising at least one m-valent metal cation M m+ wherein the metal M is selected from Scandium (Sc), Yttrium (Y), Lanthanum (La), Cerium (Ce), Praseodymium (Pr), Neodymium (Nd), Promethium (Pm), Samarium (Sm), Europium (Eu), Gadolinium 15 (Gd), Terbium (Tb), Dysprosium (Dy), Holmium (Ho), Erbium (Er), Thulium (Tm), Ytterbium (Yb), Lutetium (Lu), Gallium (Ga) and Indium (In), and m is an integer of 1, 2 or 3, and a chiral ligand of the formula (IV) wherein R 10a , R 10b , R 10c , R 10d , R 10a′ , R 10b′ , R 10c′ , R 10d′ , Z and Z′ have the meanings as defined in the description.

    专利号:US-11986886-B2
    优先权日:2019-06-06
    标题:Rapid synthesis of metal nanoparticles
    发明人:LEE KYUWAN; SINGER ROBERT H
    权利人:ALBERT EINSTEIN COLLEGE MEDICINE
    摘要:Described herein is a method of making a reduced metal nanoparticle, the method including mixing a reactive reducing agent with a metal salt in a solution at a temperature of 4-100° C., and forming the reduced metal nanoparticles in the solution. Also described is a kit including a reactive reducing agent that is sensitive to ßgalactosidase, a metal salt, and optionally a modifying agent/functionalizing agent for reduced metal nanoparticles. A 3,4-cyclohexeneoesculetin-B-D-galacto pyranoside (SGNP) gold nanoparticle and its use for measuring ßgalactosidase enzyme activity, comprising by detecting a structural change in the SGNPs caused by the ßgalactosidase are described. Further described are a point of care device, a chip, a biosensor, a laboratory animal, a gene delivery agent, a drug delivery agent, a diagnostic agent, or a disease targeting agent including SGNPs.

    专利号:US-2025082793-A1
    优先权日:2021-11-09
    标 题 :Macrocyclic compounds and methods of making the same
    发明人:CLEATOR EDWARD; MATON WILLIAM MARC; SALTER RHYS
    权利人:JANSSEN BIOTECH INC
    摘要:The present invention is directed to the preparation of key intermediates and synthesis of compounds (macrocyclic compounds) and pharmaceutically acceptable salts thereof, immunoconjugates, radioimmunoconjugates thereof, pharmaceutical compositions containing said compounds and immunoconjugates, radioimmunoconjugates thereof.

    专利号:CN-1721418-A
    优先权日:2005-06-22
    标题:Method for catalytic synthesis of lactide from lactic acid

    专利号:US-2022267247-A1
    优先权日:2019-07-09
    标题:Process for the synthesis of non-racemic cyclohexenes

    专利号:CN-1273821-C
    优先权日:2003-10-28
    标题:Characterization Method for In Situ Synthesis of Rare Earth Organic Complexes in Inorganic Solid Matrix
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    主要参考文献

    [参考文献]: M Meignan, Et Al. Ion Microscopy, A Method For Imaging The Distribution Of Trace Elements In The Lung. Phys Med Biol. 1984 Aug;29(8):927-37.

    合成参考文献


    参考文献:10.1007/978-1-4613-0669-6_27
    摘要:Environmental Quality and Safety, Supplement., 1(1), 1975 []
    摘要:Archives of Environmental Health., 5(437), 1962 []
    摘要:Hou, Z.; Wakatsuki, Y., Science of Synthesis, (2003) 2, 883.
    摘要:Hou, Z.; Wakatsuki, Y., Science of Synthesis, (2003) 2, 891.
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