硬脂醇 以87%的收率获得抗氧剂1076 参考文献:Process For The Preparation Of Sterically Hindered 标题:Process For The Preparation Of Sterically Hindered 摘要:如果以催化量的有机或无机锌盐处理ii式酯(##str1##)和iii式醇(a--Oh).Sub.M进行酯交换反应,并随后在特定条件下用短时间蒸馏装置蒸馏所得熔体,则可以几乎定量地得到式##str2##的化合物,其中式i,Ii和iii N为0至2的数字,M为1或2,A是从m价脂肪醇派生的基团,该基团包含2至18个碳原子,B为甲基或叔丁基,R为甲基或乙基.因此得到的产品不含有问题的副产物,无需额外纯化.
专利号:US-12338202-B2 优先权日:2021-09-10 标 题 :One pot synthesis of urea (meth)acrylates 发明人:BESTGEN SEBASTIAN; BEYER SILVIA 权利人:EVONIK OPERATIONS GMBH 摘要:A one-pot synthesis of polymerizable and acyclic urea (meth)acrylates, preferably mono(meth)acrylates, can be performed via in-situ synthesis of urea alcohols or amines followed by direct reaction with a (meth)acrylate reactive diluent. The urea alcohol/amine is obtained from isocyanates and alcohols, amines, or hydroxyamines. Subsequently, the reaction with the (meth)acrylate reactive diluent takes place and the urea (meth)acrylate is directly obtained either in solution with the reactive diluent, or as a pure material after removal of the reactive diluent.
专利号:US-6329543-B1 优先权日:1999-05-06 标题:Process for synthesis of isobornyl (Meth) acrylate 发明人:KNEBEL JOACHIM; SAAL DORIS 权利人:ROEHM GMBH 摘要:The present invention relates to processes for synthesis of isobornyl (meth)acrylate by reacting camphene with (meth)acrylic acid in the presence of sulfuric acid and at least one compound having inhibiting action. Aqueous sulfuric acid with an acid concentration in the range of 65 to 85 wt % is used. Isobornyl (meth)acrylate can advantageously be distilled from a mixture containing sulfuric acid in the presence of 2,6-di-tert-butyl-alpha-(dialkylamino)-p-cresol.
专利号:US-2023047214-A1 优先权日:2020-02-03 标题:Methods for microwave synthesis of degradable polymers for drug delivery 发明人:MURATOGLU ORHUN K; ORAL EBRU; GRINDY SCOTT 权利人:MASSACHUSETTS GEN HOSPITAL 摘要:Provided herein are methods of making degradable, additive-blended polymeric materials using microwave radiation and catalysts. The methods can include incorporation of therapeutic materials into the polymeric materials. There also are provided polymeric materials made by the methods and medical devices comprising the polymeric materials made by the methods.
专利号:US-7803959-B2 优先权日:2006-04-05 标 题 :Synthesis of aromatic silicon-containing compounds 发明人:COGGAN JENNIFER A; BENDER TIMOTHY P; TOTH ALAN EDWARD JOHN 权利人:XEROX CORP 摘要:Methods are provided for preparing aromatic silicon-containing compounds. The methods include providing an aromatic starting material; reacting the aromatic starting material with a base to form an aromatic salt; and reacting the aromatic salt with a halo-alkylene-silane to form an aromatic silicon-containing compound. Compositions prepared by these methods, protective layers that include hydrolysis and condensation products of such compositions, electrophotographic photoreceptors that include such protective layers, and image forming apparatuses that include such electrophotographic photoreceptors are also provided. In addition, method for preparing electrophotographic photoreceptors that include protective layers including hydrolysis and condensation products of aromatic silicon-containing compounds prepared by the methods for preparing aromatic silicon-containing compounds are provided.
专利号:EP-1633799-B1 优先权日:2003-06-03 标 题 :Production of polyether alcohols by using dmc catalysis 发明人:OSTROWSKI THOMAS; RUPPEL RAIMUND; BAUM EVA; HARRE KATHRIN 权利人:BASF SE 摘要:The present invention relates to polyetherols are prepared by a process comprising the reaction of at least one alkylene oxide with at least one initiator compound in the presence of at least one double metal cyanide compound to give a polyetherol and the treatment of the resulting polyetherol with steam or with an inert gas and steam, and the polyetherols obtainable by such a process as well as the use thereof for the synthesis of polyurethanes.
专利号:US-9827555-B2 优先权日:2013-07-31 标 题:Catalyst for conversion of synthesis gas 发明人:KARIM KHALID; RAKIB MOHAMMAD ABDUR; KHAN ASAD AHMAD; AL-SEMAHI MOHAMMED 权利人:SAUDI BASIC IND CORP 摘要:The disclosed subject matter presents a catalyst or catalyst composition as well as the methods of making and using the catalyst or catalyst composition. In one aspect, the disclosed subject matter relates to a catalyst comprising CoMn a Si b X c Y d O x wherein in X comprises an element from Group 11; Y comprises an element from Group 12; a ranges from 0.8 to 1.2; b ranges from 0.1 to 1; c ranges from 0.01 to 0.05; d ranges from 0.01 to 0.05; x is a number determined by the valency requirements of the other elements present; and wherein the catalyst converts synthesis gas to at least one olefin.
摘要:YOSHIDA Y; MUTAGENICITY OF PHOTOREACTION PRODUCTS OF 2,6-DI-TERT-BUTYL-4- METHYL-4-TERT-BUTYLPEROXY-2,5-CYCLOHEXADIENONE AND OF PHOTOREACTION PRODUCTS OF OCTADECYL 3-(1-TERT-BUTYLPEROXY-3,5-DI-TERT-BUTYL-4-OXO-CYCLOHEXA-2,5- DIEN-1-YL)PROPIONATE; OSAKA-FURITSU KOSHU EISEI KENKYUSHO KENKYU HOKOKU SHOKUHIN EISEI HEN 12: 95 (1981) 摘要:LAKE BG ET AL; THE INDUCTION OF RAT HEPATIC MICROSOMAL XENOBIOTIC METABOLISM BY N-OCTADECYL BETA-(3',5'-DI-TERT-BUTYL-4'-HYDROXYPHENYL)PROPIONATE; FOOD COSMET TOXICOL 18(1) 47 (1980) 摘要:Hawley, G.G. The Condensed Chemical Dictionary. 9th ed. New York: Van Nostrand Reinhold Co., 1977., p. 472 摘要:S47 | ECHAPLASTICS | A list from the Plastic Additives Initiative Mapping Exercise by ECHA | DOI:10.5281/zenodo.2658139 摘要:S120 | DUSTCT2024 | Substances from Second NORMAN Collaborative Dust Trial | DOI:10.5281/zenodo.13835254