CAS: 1185-59-7; Tetraethylammonium Acetate

该化合物是一种四硝基铵盐,其特点是四乙酰丙酸和乙酸阴离子,通常是在水和极有机溶剂中溶解的白色晶状固体,其使用是有机合成中的分阶段转移催化剂,便利不同阶段之间反应器的转移,从而提高反应率和产量;四乙酰乙酸乙酸盐展示四硝基铵化合物的典型特性,如非挥发性,具有较高的热稳定性;还认识到它能够与各种蚂蚁形成稳定的复合体,并能影响溶解中其他化合物的溶解性和再活性;安全考虑包括对皮肤和眼睛的潜在刺激,应在实验室中以适当的防范方式加以处理;

结构式图片

相似化合物

56-34-8 71-91-0 68-05-3

欧盟法规

ECHA物质C&L通报REACH预注册

上下游产品

diethyl sulfate triethylamine tetraethylammonium bromide acetic acidcis-1,4-diacetoxy-2-cyclopentene cis-4-cyclopentene-1,3-diol O2-acetyl-O5-(toluene-4-sulfonyl)-1,4;3,6-dianhydro-L-iditolO2-acetyl-O5-(toluene-4-sulfonyl)-1,4;3,6-dianhydro-L-iditol 3-acetoxy-2-methyl-1,1-diphenylprop-1-ene

合成工艺路线路线简述

    Et4N(Uo2Acet3) 以 Neat (No Solvent) 用作溶剂,化学反应生成四乙基醋酸铵,三乙胺
    参考文献:Santalova,N. A.; Seisenbaeva,G. A.; Dunaeva,K. M.,Doklady Chemistry,1988,Vol. 300,P. 182-184
    标题:Santalova,N. A.; Seisenbaeva,G. A.; Dunaeva,K. M.,Doklady Chemistry,1988,Vol. 300,P. 182-184

    海关参考信息

    专利信息


    专利号:US-7247287-B2
    优先权日:2003-06-11
    标 题 :Synthesis of aluminophosphates and silicoaluminophosphates
    发明人:CAO GUANG; SHAH MATU J
    权利人:EXXONMOBIL CHEM PATENTS INC
    摘要:The invention is directed to a method of synthesising silicoaluminophosphate and aluminophosphate molecular sieves using synthesis templates that contain at least one template of general formula R 1 R 2 N—R 3 , wherein R 1 and R 2 are independently selected from the group consisting of alkyl groups having from 1 to 3 carbon atoms and hydroxyalkyl groups having from 1 to 3 carbon atoms; R 3 is selected from the group consisting of 4- to 8-membered cycloalkyl groups, optionally substituted by 1 to 3 alkyl groups having from 1 to 3 carbon atoms, and 4- to 8-membered heterocyclic groups having from 1 to 3 heteroatoms, said heterocyclic groups being optionally substituted by 1 to 3 alkyl groups having from 1 to 3 carbon atoms and the heteroatoms in said heterocyclic groups being selected from the group consisting of O, N, and S. In particular, the present invention relates to the synthesis of silicoaluminophosphate molecular sieves of the CHA framework type having a low silicon to aluminium atomic ratio.

    专利号:US-6540970-B1
    优先权日:1999-11-18
    标题:Method for the synthesis of molecular sieves
    发明人:STROHMAIER KARL G; VAUGHAN DAVID E W
    权利人:EXXON MOBIL CHEM PATENTS INC
    摘要:The present invention provides a method for the synthesis of MeAPO molecular sieves which includes the following steps: providing a source of alumina, a source of phosphorus, water, and a template suitable for forming a MeAPO molecular sieve; providing a source of metal (Me) including metal particles, the metal particles measuring, in their largest dimension, equal to or less than five nanometers; providing a water soluble organic solvent capable of solubilizing the source of metal; forming a synthesis mixture from the source of alumina, the source of phosphorus, the water, the template, the source of metal, and the solvent; and forming a MeAPO molecular sieve from the synthesis mixture.

    专利号:US-6620983-B1
    优先权日:2002-06-12
    标 题 :Synthesis of aluminophosphates and silicoaluminophosphates
    发明人:CAO GUANG; SHAH MATU J; STROHMAIER KARL G; HALL RICHARD B
    权利人:EXXONMOBIL CHEM PATENTS INC
    摘要:The invention is directed to a method of synthesizing aluminophosphate or silicoaluminophosphate molecular sieves and in particular to the synthesis of silicoaluminophosphate molecular sieves using synthesis templates in combination with a source of fluoride comprising at least two fluoride substituents. The use of such fluorine containing compounds results in good quality low silica SAPO molecular sieves of CHA framework type.

    专利号:US-4879389-A
    优先权日:1986-06-25
    标题:Chiral phosphinopyrrolidine compounds and their use for asymmetric synthesis of optically active compounds
    发明人:ACHIWA KAZUO
    权利人:ACHIWA KAZUO
    摘要:New chiral phosphinopyrrolidine compounds of the general formula: (I) or (I') wherein R1 is a hydrogen atom, -COR, -COOR, -CONHR or -SO2-R where R is an alkyl or aryl group, R2 and R3 each represents independently an aryl group which may have a substituent or substituents, and R4 and R5 each represents independently an aliphatic or cycloaliphatic hydrocarbyl group which may have a substituent or substituents, as well as the use of these compounds as ligand for a metal complex catalyst for asymmetric synthesis of optically active compounds. The new chiral phosphinopyrrolidine compounds are useful ligands which attain both of high optical yield and high reaction efficiency in catalytic asymmetric reduction.

    专利号:US-6767858-B1
    优先权日:2003-02-20
    标题:Synthesis of alumino- and silicoalumino-phosphates of CHA framework type
    发明人:CAO GUANG; SHAH MATU J
    权利人:EXXONMOBIL CHEM PATENTS INC
    摘要:The invention is directed to a method of synthesizing aluminophosphate and silicoaluminophosphate molecular sieves and in particular to the synthesis of aluminophosphate and silicoaluminophosphate molecular sieves using N-methylethanolamine as template with or without a source of fluoride. The use of N-methylethanolamine as template results in good quality AlPO4 of CHA framework type and SAPO molecular sieves of CHA framework type with low levels of silicon in high yield.

    专利号:US-7375050-B2
    优先权日:2003-04-28
    标 题 :Synthesis and use of aluminophosphates and silicoaluminophosphates
    发明人:MERTENS MACHTELD M; JANSSEN MARCEL J G; XU TENG
    权利人:EXXONMOBIL CHEM PATENTS INC
    摘要:Disclosed are methods and compositions of synthesis mixtures for the synthesis of aluminophosphates and silicoaluminophosphate molecular sieves, which enable the control and adjustment of the crystal particle size of aluminophosphates and silicoaluminophosphate molecular sieves. The synthesis mixture compositions used have two or more organic templates present at a molar ratio of total template to aluminum of ≦1.25; such a synthesis mixture is susceptible to control of product particle size through variation in the amount of seeds used in the synthesis.
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