CAS: 100-40-3; 4-Vinyl-1-Cyclohexene

该化合物是有机化合物,其特点是循环结构,包括环己环和乙烯组;在室温下,无色可粉黄液,呈现出独特的甜味;该化合物以其反应性而著称,特别是在聚合反应方面,使其在生产各种聚合物和共聚物方面有用;乙烯环己烷在水中相对不溶,但在乙醇和乙醇等有机溶剂中可溶.其化学配方为C8H12,其分子重量反映其结构;该化合物可经受各种化学反应,包括因双联苯乙烯组中存在而增加的反应.安全考虑在处理乙烯环己烷时十分重要,因为它可能因吸入或皮肤接触而造成健康风险,因此需要在实验室和工业环境中采取适当的安全措施.

结构式图片

欧盟法规

统一分类与标签REACH注册ECHA物质工作场所安全标识要求ECHA物质食品接触材料-禁用CMR物质C&L通报化妆品禁用物质清单REACH预注册废弃物危险特性清单

上下游产品

CAS号106-99-0 丁二烯 | CAS号16388-31-1 4-Ethinylcyclohexen | CAS号3322-93-8 1,2-二溴-4-(1,2-二... | CAS号51-80-9 四甲基甲烷二胺 | CAS号110-89-4 六氢吡啶 | CAS号934-79-2 4-Vinyl-1,2-dib... | CAS号87-72-9 L-阿拉伯糖 | CAS号108-24-7 乙酸酐 | CAS号1552-12-1 1,5-环辛二稀 | CAS号5441-51-0 4-乙基环己酮 | CAS号64847-85-4 (S)-(-)-3-ethyl... | CAS号3322-93-8 1,2-二溴-4-(1,2-二... | CAS号4442-85-7 2-环己基乙胺 | CAS号923-42-2 1,2,4-丁烷三羧酸 | CAS号64-18-6 甲酸 | CAS号110-15-6 琥珀酸; 丁二酸 | CAS号99-14-9 1,2,3-丙烷三甲酸 | CAS号123-76-2 乙酰丙酸 | CAS号21130-56-3 4-(2-iodoethyl)...

合成工艺路线路线简述

    1-Phenylethyl Acetate置于quartz Tube体系中,化学反应生成4-乙烯基-1-环己烯
    参考文献:Petrow; Sopow,Zhurnal Obshchei Khimii,1957,Vol. 27,P. 1795,1797,1804; Engl. Ausg. S. 1862,1864,1870
    标题:Petrow; Sopow,Zhurnal Obshchei Khimii,1957,Vol. 27,P. 1795,1797,1804; Engl. Ausg. S. 1862,1864,1870

    专利信息


    专利号:US-6479599-B1
    优先权日:1997-04-04
    标题:Catalyst system for high yield synthesis of polyolefins
    发明人:PEIL KEVIN P; WILSON DAVID R
    权利人:BP CHEM INT LTD
    摘要:This invention relates to a supported metallocene catalyst system for the high yield synthesis of polyolefins, to methods of preparation of the catalyst system, to polymerization processes which use the catalyst system and to polyolefin polymers produced by the polymerization processes.

    专利号:US-2005240037-A1
    优先权日:2002-07-23
    标 题 :Method for the continuous intermediate separation of the solvent used in the oxirane synthesis with no coupling product
    发明人:BASSLER PETER; GOBBEL HANS-GEORG; TELES JOAQUIN H; RUDOLF PETER
    权利人:BASF AG
    摘要:Process for the continuously operated distillation of the solvent used in the synthesis of an oxirane by reaction of a hydroperoxide with an organic compound, wherein the mixture comprising the solvent which is obtained in the synthesis and subsequent work-up is separated in a dividing wall column into a low-boiling fraction, an intermediate-boiling fraction and a high-boiling fraction and the solvent is taken off as intermediate-boiling fraction from the side offtake of the column.

    专利号:WO-03051942-A1
    优先权日:2001-12-14
    标 题:Procedure for the formulation of a catalyst for the manufacture of cis-1,4-polybutadiene of controllable molecular weight
    发明人:EDEL HANS A R; STILLER HARTMUT K; STOCK GUENTHER H; SCHMUDDE ANKE
    权利人:DOW GLOBAL TECHNOLOGIES INC; EDEL HANS A R; STILLER HARTMUT K; STOCK GUENTHER H; SCHMUDDE ANKE
    摘要:The invention is a two-step procedure for the formulation of a mixed catalyst of a nickel compound preferably with diene addition, boron trifluoride and an organo-aluminum compound, for the synthesis of cis-1,4-polybutadiene rubber, in which in each case, in a first step boron trifluoride was reacted as an etherate complex (BF3OEt2) with triethyl-aluminum (AlEt3) in toluene, with a contact time in each case of between 10 and 120 minutes; the active component of the catalyst formulation here was the amorphous AlF3 formed and where in a second step nickel carboxylate-also in toluene- was added to the mixture. The procedure is suitable for the synthesis of cis-1,4-polybutadiene rubber with a high cis-1,4 content and a molecular weight controllable over a wide range, with the goal of minimizing gel formation during the polymerization process.

    专利号:US-10669160-B2
    优先权日:2018-04-30
    标题:Heterogeneous wet synthesis process for preparation of high purity tungsten pentahalide
    发明人:LIU YUMIN; LI FENG; WAN ZHIWEN; FAFARD CLAUDIA; WIESE STEFAN; HUSSON GUILLAUME; NIKIFOROV GRIGORY; SUI BIN; GIRARD JEAN-MARC
    权利人:AIR LIQUIDE; AIR LIQUIDE AMERICAN
    摘要:Synthesis of tungsten pentahalide compositions having low impurity profiles are disclosed. The specific impurity profile permits deposition of high purity tungsten-containing films using vapor deposition processes or other semiconductor manufacturing processes without introduction of performance-impacting contaminants.

    专利号:US-7129197-B2
    优先权日:2001-08-31
    标题 :Synthesis of poly-alpha olefin and use thereof
    发明人:SONG WEI; HEILMAN WILLIAM J
    权利人:SHELL OIL CO
    摘要:One or more oligomers of an olefin are prepared in the presence of a single-site catalyst. Preferably, the olefin is an α-olefin, and the oligomers are a poly-alpha-olefin (PAO). The PAO so prepared is completely or substantially free of tertiary hydrogen resulting from isomerization. Consequently, the PAO possesses improved biodegradability, improved oxidation resistance, and/or a relatively higher viscosity index. The PAO has many useful applications, such as a component of a lubricant.

    专利号:US-2023348657-A1
    优先权日:2020-07-23
    标题 :Synthesis of linear polyoxazolidinones using uretdiones as diisocyanate component
    发明人:QUELL AGGELIKI; THOMAS HANS-JOSEF; ELING BEREND
    权利人:BASF SE
    摘要:A process for preparing a thermoplastic polymer involves reacting at least components (a) to (b), in the presence of a catalyst composition (c). Component (a) is an isocyanate composition containing at least one uretdione diisocyanate (a-i), and component (b) is an epoxide composition containing at least one diepoxide (b-i). The catalyst composition (c) contains at least one ionic liquid (c-i), preferably selected from 1-ethyl-3-methyl imidazolium bromide, 1-benzyl-3-methyl imidazolium chloride. 1-butyl-1-methylpiperidinium chloride, 1-ethyl-2,3-dimethylimidazolium bromide, 1-(2-hydroxyethyl)-3-methyl imidazolium chloride, butyl-1-methylpiperidinium acetate, or mixtures of two or more thereof. A thermoplastic polymer obtained or obtainable from the process is useful for the preparation of a fibre or a molded article or as a modifier for another thermoplastic material.
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    合成参考文献


    摘要:Schramm, M. P., Science of Synthesis, (2009) 46, 463.
    摘要:Merino, P., Science of Synthesis Knowledge Updates, (2010) 4, 354.
    摘要:Bonrath, W.; Medlock, J. A.; Müller, M.-A., Science of Synthesis: Catalytic Reduction in Organic Synthesis, (2017) 1, 204.
    摘要:Yoshida, H., Science of Synthesis: Advances in Organoboron Chemistry towards Organic Synthesis, (2019) 1, 32.
    摘要:Weast, R.C. and M.J. Astle. CRC Handbook of Data on Organic Compounds. Volumes I and II. Boca Raton, FL: CRC Press Inc. 1985., p. V1 503
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