CAS: 22190-35-8; 6-Bromo-1,2,3,4-Tetrahydroquinoline

上下游产品

CAS号635-46-1 1,2,3,4-四氢喹啉 | CAS号3279-90-1 6-溴-1,2,3,4-四氢-2-喹啉酮 | CAS号76228-06-3 6-溴-2,3-二氢喹啉-4(1H)-酮 | CAS号185122-63-8 5-BROMO-1-INDAN... | CAS号767-92-0 反-十氢喹啉 | CAS号5382-49-0 1,2,3,4-四羟基-6-羧酸喹啉 | CAS号89-00-9 吡啶-2,3-二羧酸 | CAS号50741-36-1 1,2,3,4-四氢喹啉-6-甲腈

1,2,3,4-四氢喹啉置于n-溴代丁二酰亚胺(Nbs)体系中,用 乙腈 用作溶剂,化学反应 3.0H,反应生成6-溴-1,2,3,4-四氢喹啉
参考文献:铜催化水合二羧酸二叔丁酯的氧催化氧化成偶氮二甲酸二叔丁酯及其在温和条件下对1,2,3,4-四氢喹啉的脱氢作用
标题:铜催化水合二羧酸二叔丁酯的氧催化氧化成偶氮二甲酸二叔丁酯及其在温和条件下对1,2,3,4-四氢喹啉的脱氢作用
摘要:用均相的cui和偶氮二甲酸二叔丁酯开发了一种新型的共催化体系,用于在温和条件下对1,2,3,4-四氢喹啉进行好氧脱氢.发达共催化体系是由二-叔丁基偶氮二羧酸酯介导的二-1,2,3,4-四氢喹啉和好氧氧化再生的脱氢叔丁基偶氮二羧酸酯选自二叔使用分子氧作为丁基hydrazodicarboxylate终端氧化剂.发达的铜和偶氮二羧酸二叔丁酯助催化体系有效地合成了各种喹啉.
Doi:10.1021/acs.Orglett.6B03166

专利信息

专利号:CN-107162968-B
优先权日:2017-05-25
标 题 :A kind of method of visible light catalytic Tetrahydroquinolinesas oxidative dehydrogenation synthesis of quinoline class compound

专利号:CN-109485667-B
优先权日:2018-12-24
标 题 :Synthesis method of 2-aryl-tetrahydroquinoline-4-boron ester compound

专利号:US-2010280024-A1
优先权日:2007-10-15
标 题:Renin inhibitors
发明人：DESAI JIGAR; THOMBARE PRAVIN S; JAIN MUKUL R; PATEL PANKAJ RAMANBHAI
权利人:DESAI JIGAR; THOMBARE PRAVIN S; JAIN MUKUL R; PATEL PANKAJ RAMANBHAI
摘要:The present invention relates to renin inhibitors of formula (I), their pharmaceutically acceptable salts and pharmaceutical compositions containing them. The present invention also relates to a process of preparing compounds of general formula (I), their tautomeric forms, their pharmaceutically acceptable salts, pharmaceutical compositions containing them, and novel intermediates involved in their synthesis.