CAS: 488-48-2; 2,3,5,6-Tetrabromocyclohexa-2,5-Diene-1,4-Dione

该化合物是结构结构,包括一个芳香环上附着的溴原子,有助于其独特的化学特性;Bromanil经常用于各种用途,包括作为除草剂和其他化合物合成;其活性受溴的存在影响,这种溴可以参与电益替代反应;该化合物在标准条件下通常稳定,但在接触强氧化剂或极端环境条件时可能会退化;Bromanil在有机溶剂中的溶解性使其在各种化学工艺中有用,尽管其环境影响和潜在毒性需要谨慎处理和管制;与许多溴化化合物一样,人们对其在环境中的持久性和潜在生物蓄积性表示关切,这是其应用和处置中的重要考虑因素.

结构式图片

相似化合物

19643-45-9 1633-14-3 3958-82-5

欧盟法规

ECHA物质C&L通报REACH预注册

上下游产品

2,6-dibromo-4-nitrophenol 4-nitro-phenol 4-Fluorophenol Pentabromophenol2,5-bis-aziridin-1-yl-3,6-dibromo-[1,4]benzoquinone 1,2-dimesityl-propenone 2,3,5,6-tetrabromohydroquinone 2-bromo-1,3,4,5,6-pentaphenyl-cyclohexa-2,5-diene-1,4-diol

合成工艺路线路线简述

    对硝基苯酚置于溴,硝酸体系中,化学反应生成 四溴对苯醌
    参考文献:Halogenation. Xxii. The Action Of Bromine And Nitric Acid On Organic Compounds. Preparation Of Nitrosyl Tribromide And The Formation Of Tetrabromoquinone
    标题:Halogenation. Xxii. The Action Of Bromine And Nitric Acid On Organic Compounds. Preparation Of Nitrosyl Tribromide And The Formation Of Tetrabromoquinone
    摘要:
    DOI:10.1021/ja01655A025

    海关参考信息

    专利信息


    专利号:US-4895954-A
    优先权日:1986-07-26
    标题 :Precursors for synthesis of triphendioxazine dyestuffs
    发明人:SCHWAIGER GUENTHER; SPRINGER HARTMUT; HELMLING WALTER
    权利人:HOECHST AG
    摘要:Water-soluble triphendioxazine compounds which have fiber-reactive properties as dyestuffs, which afford deep and fast dyeings on fiber materials, such as wool and, in particular, cellulose, and which correspond to the formula (1) ##STR1## in which: n is the number 0 or 1; n Y is the vinyl group or an ethyl group containing, in β-position, a substituent which can be eliminated by means of an alkali; n Q 1 and Q 2 both represent a benzotriazole radical which can also be additionally substituted in the benzene nucleus by alkyl having 1 to 4 carbon atoms, alkoxy having 1 to 4 carbon atoms, halogen, carboxy or sulfo; n B is --O--, --S--, --NH-- or --N(R')-- wherein R' is optionally substituted alkyl having 1 to 6 carbon atoms; n W 1 and W 2 both represent a divalent, optionally substituted aliphatic, cycloaliphatic, aliphatic-cycloaliphatic, araliphatic or aromatic-carbocyclic radical, it being possible for the aliphatic radicals to be interrupted by hetero groups --O--, --S--, --SO 2 --, --CO--, 1,4-piperidino, --NH-- and/or --N(R o )-- in which R o is optionally substituted alkyl having 1 to 6 carbon atoms or alkanoyl having 2 to 5 carbon atoms, and/or for aliphatic and aryl radicals to be attached to one another through such a hetero group; n R is hydrogen, alkyl having 1 to 6 carbon atoms, alkoxy having 1 to 6 carbon atoms, halogen, carboxyl or sulfo; n E is hydrogen, sulfo, carboxyl, a group --SO 2 --Y as defined above or an optionally substituted sulfonamide group; and n X 1 and X 2 are both hydrogen or halogen, cycloalkyl, alkoxy, aryloxy, aryl or another substituent; n and at least one carboxy, sulfo or sulfato group is present in the molecule (1), n and pre-products of those triphendioxazine compounds, of the general formula ##STR2## in which K is an amino or nitro group, Y' is β-hydroxyethyl or defined as for Y, W has one of the meanings of W 1 , and E' is hydrogen, sulfo, carboxy or a group of the formula --SO 2 --Y' defined above, or an optionally substituted sulfonamide group, and R, B and R* have the above meanings.

    专利号:US-2009093521-A1
    优先权日:2005-06-14
    标 题 :2, 5-Bis-Diamine [1,4] Benzoquinone-Derivatives
    发明人:BOLOGNESI MARIA LAURA; BANZI RITA; MINARINI ANNA; MELCHIORRE CARLO
    权利人:BOLOGNESI MARIA LAURA; BANZI RITA; MINARINI ANNA; MELCHIORRE CARLO
    摘要:Synthesis of 2,5-bis-diamine-[1,4]benzoquinonic derivatives having the general formula (I), products and intermediates of said synthesis; the synthesis involves the use of p-benzoquinones having the general formula (IX) and diamines having the general formula (XI).

    专利号:EP-3396028-B1
    优先权日:2014-02-24
    标 题 :Direct electrochemical synthesis of doped conductive polymers on metal alloys

    专利号:CN-86102496-B
    优先权日:1985-09-07
    标题:Synthesis of Tetrabromohydroquinone by Sectional Temperature Control

    专利号:WO-9743289-A1
    优先权日:1996-05-17
    标 题 :Large synthetic compounds based on electron donor and electron acceptor interactions
    发明人:IVERSON BRENT L; LOKEY R SCOTT
    权利人:UNIV TEXAS; IVERSON BRENT L; LOKEY R SCOTT
    摘要:Using predetermined electron donor-electron acceptor interactions, the present invention provides for the design, synthesis and use of compounds that are capable of interacting with, competing with and even mimicking biological macromolecules. The compounds may be related structurally and/or functionally to a wide variety of biologicals including proteins, nucleic acids, lipids, carbohydrates, steroids or other compounds. In one embodiment, alternating electron donor-acceptor molecules (AEDAMers) are employed to create compounds having higher order structures including helices and pleats. These compounds may be used in a myriad of different applications, which include roles as inert carriers, antigens, biologically inactive stabilizers, drugs and enzymes. Also contemplated are combinatorial processes for creating large libraries permitting rapid screening for desired structure and/or function.

    专利号:CN-105732488-B
    优先权日:2016-03-28
    标 题 :A kind of method of pyridine-2-formic acid decarboxylation synthesis 2-(2-chloroethoxy) ethoxypyridine ether compound
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    主要参考文献

    参考标题:One-Pot Synthesis Of Novel Antiproliferative 9-Aminoacridines
    作者:Gary Gellerman,Sagiv Waintraub,Amnon Albeck,Vladimir Gaisin |发布日期:2011.8
    摘要:Highly Efficient One-Pot Syntheses Of Antiproliferative 9-Aminoacridine (9-Aa) Derivatives Are Described. Simple Snar And Addition/elimination Reactions, Using Readily Accessible Starting Materials, Give A Fast Entry To Novel 9-(Pyridylamino)Acridines, 9-(Pyrimidinylamino)Acridines And Potential "Dual-Function" Bioreductive 9-(Acridinylamino)Quinone Intercalators. The Synthetic Routes Reported In This

    合成参考文献


    摘要:Summary Tables of Biological Tests, National Research Council Chemical-Biological Coordination Center., 5(144), 1953
    参考文献:10.1107/s0108768111015801
    摘要:García-Orduña P, Dahaoui S, Lecomte C. Intermolecular interactions and charge transfer in the 2:1 tetrathiafulvalene bromanil complex, (TTF)2-BA. Acta Crystallogr B Struct Sci. 2011 May 14;67(3):244–9. doi: 10.1107/s0108768111015801.
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