3,5-Heptanedione Enol 反应生成 3,5-庚烷二酮 参考文献:Effect Of Substituents On The Keto-Enol Equilibrium Of Alkyl-Substituted β-Diketones 标题:Effect Of Substituents On The Keto-Enol Equilibrium Of Alkyl-Substituted β-Diketones 摘要: DOI:10.1246/bcsj.46.632
专利号:WO-2019199375-A1 优先权日:2018-04-10 标 题 :Synthesis of boron complexes with oxygen-containing multidentate ligands 发明人:LU GANG 权利人:DOW SILICONES CORP 摘要:A method for preparing a boron complex is provided. The method comprises contacting and allowing to react at a temperature from 0 to 100°C: (a) an alkoxyborane of formula (I) wherein R1 and R2 independently are hydrogen, C1-C30 hydrocarbyl or C5-C30 heterocyclic; and R3 is C1-C30 hydrocarbyl; and (b) either (i) an α-diketo compound having from 4 to 30 carbon atoms, or (ii) a β-diketo compound having from 5 to 50 carbon atoms. A method for addition reaction polymerization using the boron complex obtained by said method is also provided.
专利号:US-9815860-B2 优先权日:2007-01-12 标题 :Process for preparing cationic rhodium complexes 发明人:NEDDEN HANS GUENTER 权利人:NEDDEN HANS GUENTER; JOHNSON MATTHEY PLC 摘要:A process for the synthesis of a cationic rhodium complex comprises the steps of:n (a) forming a mixture of a rhodium-diolefin-1,3-diketonate compound and a phosphorus ligand in a ketone solvent, (b) mixing an acid with the mixture to form a solution of the cationic rhodium complex, (c) evaporating at least a portion of the solvent from the solution, (d) optionally, treating the resulting complex with an ether, and (e) treating the resulting complex with an alcohol. nn The complex may be recovered and used as a catalyst, for example in hydrogenation reactions.
专利号:WO-0240493-A1 优先权日:2000-11-20 标题 :Asymmetric metal complexes based on a transition metal useful for enantioselective reduction of ketone derivatives by hydride transfer 发明人:LE GUYADER FREDERIC; MANFRE FRANCO; BIENEWALD FRANCK 权利人:RHODIA CHIMIE SA; LE GUYADER FREDERIC; MANFRE FRANCO; BIENEWALD FRANCK 摘要:The invention concerns asymmetric metal complexes based on a transition metal and comprising as ligand of said metal at least an optically active form of a compound of general formula (I). The invention also concerns the preparation and the use of said complexes in asymmetric organic synthesis and in particular for enantioselective reduction of ketone derivatives by hydride transfer.
专利号:CN-107876092-A 优先权日:2017-11-24 标 题 :High Stability Titanium Catalyst for the Synthesis of Benzyl Carbonate and Diphenyl Carbonate by Transesterification
专利号:DE-102005036880-A1 优先权日:2005-08-02 标题:Stereoselective synthesis of chiral diols
专利号:CN-108947900-A 优先权日:2018-08-06 标题 :A light-induced metal-free catalyzed carboarylation tandem reaction for the synthesis of heterocyclic compounds
参考标题:Synthesis Of Multifunctionalized 2-Carbonylpyrrole By Rhodium-Catalyzed Transannulation Of 1-Sulfonyl-1,2,3-Triazole With β-Diketone 作者:Wanli Cheng,Yanhua Tang,Ze-Feng Xu,Chuan-Ying Li |发布日期:2016.12.2 摘要:A Facile Rhodium-Catalyzed Transannulation Of 1-Sulfonyl-1,2,3-Triazoles With β-Diketones Was Realized, And A Series Of Multisubstituted 2-Carbonylpyrroles Were Synthesized Efficiently (Up To 94% Yield). The Protocol Features Several Advantages, Such As Readily Available Materials, Mild Reaction Conditions, A Concise Operating Procedure, A Broad Reaction Scope, And Excellent Regioselectivity When Benzoylacetone
合成参考文献
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