CAS: 2645-22-9; 4,4-Dipyridyl Disulfide

该化合物是一种含有硫磺的七环化合物,其特点是连接两个丙-4-yl组的脱硫桥.这种结构具有独特的回活动性,使其在有机合成,协调化学和材料科学中具有价值.脱硫联结提供了氧化作用特性,有利于在动态共价化学和催化中应用.它的双丙烯基糖可以增强离子体能力,促进催化或超分子系统的金属协调.该化合物的稳定性和明确界定的几何性使其适合于构建分子框架或功能材料.它在交叉组合反应和作为建筑块的作用中的多样性进一步强调了其在先进化学研究中的实用性.

结构式图片

相似化合物

24367-50-8 4556-23-4 1982380-63-1

欧盟法规

ECHA物质C&L通报REACH预注册

上下游产品

CAS号4556-23-4 4-巯基吡啶 | CAS号5421-92-1 4-吡啶基吡啶氯盐酸盐 | CAS号626-61-9 4-氯吡啶 | CAS号349489-99-2 nitroso(pyridin... | CAS号4556-23-4 4-巯基吡啶 | CAS号26157-58-4 2-acetamidoethy... | CAS号1892-29-1 2-羟乙基二硫化物 | CAS号5402-20-0 吡啶-4-磺酸 | CAS号65938-88-7 吡啶-4-磺酰胺 | CAS号134479-04-2 吡啶-4-磺酰氯 | CAS号501422-69-1 4-Pyridinesulfe...

合成工艺路线路线简述

    4-氯吡啶置于sodium Hydroxide,乙醇,水,碘,Potassium Hydrosulfide,Potassium Iodide体系中,化学反应生成4,4'-联吡啶二硫醚
    参考文献:Koenigs; Kinne,Chemische Berichte,1921,Vol. 54,P. 1359
    标题:Koenigs; Kinne,Chemische Berichte,1921,Vol. 54,P. 1359

    海关参考信息

    专利信息


    专利号:US-9885035-B2
    优先权日:2002-10-30
    标 题 :Method for the synthesis of a bifunctional complex
    发明人:FRANCH THOMAS; GOULIAEV ALEX HAAHR
    权利人:NUEVOLUTION AS
    摘要:Disclosed is a method for obtaining a bifunctional complex comprising a display molecule part and a coding part, wherein a nascent bifunctional complex comprising a chemical reaction site and a priming site for enzymatic addition of a tag is reacted at the chemical reaction site with one or more reactants, and provided with respective tag(s) identifying the reactant(s) at the priming site is using one or more enzymes.

    专利号:US-9574189-B2
    优先权日:2005-12-01
    标题:Enzymatic encoding methods for efficient synthesis of large libraries
    发明人:FRANCH THOMAS; LUNDORF MIKKEL DYBRO; JACOBSEN SØREN NYBOE; OLSEN EVA KAMPMANN; ANDERSEN ANNE LEE; HOLTMANN ANETTE; HANSEN ANDERS HOLM; SØRENSEN ANDERS MALLING; GOLDBECH ANNE; DE LEON DAEN; KALDOR DITTE KIEVSMOSE; SLØK FRANK ABILDGAARD; HUSEMOEN GITTE NYSTRUP; DOLBERG JOHANNES; Jensen Kim Birkebæ; PEDERSEN LENE; NØRREGAARD-MADSEN MADS; GODSKESEN MICHAEL ANDERS; GLAD SANNE SCHRØDER; NEVE SØREN; THISTED THOMAS; KRONBORG TINE TITILOLA AKINLEMINU; SAMS CHRISTIAN KLARNER; FELDING JAKOB; FRESKGÃ…RD PER-OLA; GOULIAEV ALEX HAAHR; PEDERSEN HENRIK
    权利人:FRANCH THOMAS; LUNDORF MIKKEL DYBRO; JACOBSEN SØREN NYBOE; OLSEN EVA KAMPMANN; ANDERSEN ANNE LEE; HOLTMANN ANETTE; HANSEN ANDERS HOLM; SØRENSEN ANDERS MALLING; GOLDBECH ANNE; DE LEON DAEN; KALDOR DITTE KIEVSMOSE; SLØK FRANK ABILDGAARD; HUSEMOEN GITTE NYSTRUP; DOLBERG JOHANNES; Jensen Kim Birkebæ; PEDERSEN LENE; NØRREGAARD-MADSEN MADS; GODSKESEN MICHAEL ANDERS; GLAD SANNE SCHRØDER; NEVE SØREN; THISTED THOMAS; KRONBORG TINE TITILOLA AKINLEMINU; SAMS CHRISTIAN KLARNER; FELDING JAKOB; FRESKGÃ…RD PER-OLA; GOULIAEV ALEX HAAHR; PEDERSEN HENRIK; NUEVOLUTION AS
    摘要:Disclosed is a method for obtaining a bifunctional complex comprising a molecule linked to a single stranded identifier oligonucleotide, wherein a nascent bifunctional complex comprising a chemical reaction site and a priming site for enzymatic addition of a tag is a) reacted at the chemical reaction site with one or more reactants, and b) reacted enzymatically at the priming site with one or more tag(s) identifying the reactant(s).

    专利号:EP-0051234-B1
    优先权日:1980-10-31
    标题:A process for the production of a 2-azetidinone derivative
    摘要:A new and efficient process of producing a 2-azetidinone derivative is provided, which comprises cyclizing a beta -amino acid by treating with triphenylphosphine and a heterocyclic disulfide in the presence of an alkylnitrile. The 2-azetidinone derivatives produced are useful as starting compound for synthesis of beta -lactam group antibiotics such as thienamycin and nocardicin.

    专利号:US-11225655-B2
    优先权日:2010-04-16
    标题:Bi-functional complexes and methods for making and using such complexes
    发明人:GOULIAEV ALEX HAAHR; FRANCH THOMAS; GODSKESEN MICHAEL ANDERS; JENSEN KIM BIRKEBAEK
    权利人:GOULIAEV ALEX HAAHR; FRANCH THOMAS; GODSKESEN MICHAEL ANDERS; JENSEN KIM BIRKEBAEK; NUEVOLUTION AS
    摘要:The present invention is directed to a method for the synthesis of a bi-functional complex comprising a molecule part and an identifier oligonucleotide part identifying the molecule part. A part of the synthesis method according to the present invention is preferably conducted in one or more organic solvents when a nascent bi-functional complex comprising an optionally protected tag or oligonucleotide identifier is linked to a solid support, and another part of the synthesis method is preferably conducted under conditions suitable for enzymatic addition of an oligonucleotide tag to a nascent bi-functional complex in solution.

    专利号:US-12018097-B2
    优先权日:2017-06-09
    标题 :Non-chromatographic purification of macrocyclic peptides by a resin catch and release
    发明人:CREECH GARDNER S; KHEIRABADI MAHBOUBEH; EASTGATE MARTIN D; NIRSCHL DAVID S; CARTER PERCY H
    权利人:BRISTOL MYERS SQUIBB CO
    摘要:The disclosure is directed to the synthesis and improved methods for purifying macrocyclic peptides produced by solid phase peptide synthesis. The synthesized peptide is capped with an alkyne-functionalized or azide-functionalized compound of formula (I):prior to cleavage of the peptide from the solid phase support.

    专利号:US-2019136227-A1
    优先权日:2002-10-30
    标题:Method for the synthesis of a bifunctional complex
    广州博氧化工有限公司
    ⚠️ 未注册 · 未认证企业
    ⚠️ 该商家尚未完成注册及企业认证,请用户仔细辨别,谨慎交易。
    数据来源于公开网络搜索,平台未作核实,请自行辨别。
    🏢敬请 企业认领
    🏬开设公司展台
    📢获取免费会员权益
    🎖️点亮专属注册企业标签
    📇展现公司完整信息 样本查看立即注册认领 →
    网址: http://www.gzbychem.com
    企业联系电话:0769-88852786👤
    📞广州博氧化工有限公司 ⚠️参考联系方式
    联系人:刘艳芬
    电话:0769-88852786
    手机:18929546850
    传真:0769-88852786
    邮箱:gzbyhg2012@163.com
    通信地址: 东莞市望牛墩朱平沙科技五路1号
    邮编: 523208
    🆔 联系时候可告知是从"百琢研"平台获取的信息.
    ⚠️ 声明: 该企业未认证、未认领,请自行辨别信息的真实性和可靠性。咨询或交易时请注意风险评估与信息核实,百琢研不参与任何交易。企业认领注册入口→

    地址:东莞市望牛墩朱平沙科技五路1号
    ⚠️ 未注册 · 未认证企业
    注册入口 备注: 📌 数据来源说明:本展台内容基于各搜索引擎等公开数据整理,仅作展示用途。请用户自行辨别
    ✉️ 若企业需抹除展台内容或有异议, 请通过页面底部联系方式告知我们,我们会尽快处理。
    第 1 / 1 页
    现货

    供应商参考报价(招募中)

    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    主要参考文献

    参考标题:Synthesis Of Sulfonimidamides From Sulfenamides Via An Alkoxy‐amino‐λ 6 ‐sulfanenitrile Intermediate
    作者:Edward L. Briggs,Arianna Tota,Marco Colella,Leonardo Degennaro,Renzo Luisi,James A. Bull |发布日期:2019.10
    摘要:Few Operationally Simple Methods For Their Preparation. Here, The Synthesis Of Nh-Sulfonimidamides Is Achieved Directly From Sulfenamides, Themselves Readily Formed In One Step From Amines And Disulfides. A Highly Chemoselective And One-Pot Nh And O Transfer Is Developed, Mediated By Phio In Iproh, Using Ammonium Carbamate As The Nh Source, And In The Presence Of 1 Equivalent Of Acetic Acid. A Wide

    合成参考文献


    摘要:Kordnezhadian, R.; De Borggraeve, W. M.; Ismalaj, E., Science of Synthesis: Modern Strategies in Organofluorine Chemistry , (2024) 1, 11.
    参考文献:10.1007/s00294-008-0184-z
    摘要:López-Mirabal HR, Winther JR, Kielland-Brandt MC. Oxidant resistance in a yeast mutant deficient in the Sit4 phosphatase. Curr Genet. 2008 May;53(5):275–86. doi: 10.1007/s00294-008-0184-z.
    参考文献:10.1007/s00438-008-0339-0
    摘要:López-Mirabal HR, Winther JR, Thorsen M, Kielland-Brandt MC. Mutations in the RAM network confer resistance to the thiol oxidant 4,4′-dipyridyl disulfide. Molecular Genetics and Genomics. 2008 Mar 21;279(6):629–42. doi: 10.1007/s00438-008-0339-0.
    参考文献:10.1007/s00775-008-0365-8
    摘要:Paes de Sousa PM, Pauleta SR, Rodrigues D, Simões Gonçalves ML, Pettigrew GW, Moura I, Moura JJG, Correia dos Santos MM. Benefits of membrane electrodes in the electrochemistry of metalloproteins: mediated catalysis of Paracoccus pantotrophus cytochrome c peroxidase by horse cytochrome c: a case study. JBIC Journal of Biological Inorganic Chemistry. 2008 Mar 26;13(5):779–87. doi: 10.1007/s00775-008-0365-8.
    参考文献:10.1107/s1600536810021331
    摘要:Zhang J, Xu W. catena-Poly[[[(2-phenylacetato-κO)zinc(II)]bis[μ-4,4′-(disulfanediyl)dipyridine-κ2N:N′]] monohydrate]. Acta Crystallogr E Struct Rep Online. 2010 Jun 16;66(7):m788–9. doi: 10.1107/s1600536810021331.
    📝 需求与反馈
    尽可能描述清楚需求与问题信息
    ×

    通知