专利号:US-9796653-B2 优先权日:2015-12-21 标题 :Methods of preparing α,β-unsaturated or α-halo ketones and aldehydes 发明人:BAXENDALE IAN R; SHARLEY JAMES S; Miranda Amadeo Fernández; PÉREZ ANA MARIA COLLADO 权利人:INT FLAVORS & FRAGRANCES INC 摘要:Copper(II) bromide mediated oxidation of acylated enol and use of the reaction in the synthesis of α,β-unsaturated or α-bromo ketones or aldehydes are disclosed. The method provides an efficient and practical process for manufacturing dehydrohedione (DHH) and many other versatile α,β-unsaturated or α-bromo ketones or aldehydes in large scales to avoid using precious metal compounds.
专利号:WO-0019994-A9 优先权日:1998-10-02 标题 :Estrogen receptor ligands 发明人:KATZENELLENBOGEN JOHN A; KATZENELLENBOGEN BENITA S; FINK BRIAN E; STAUFFER SHAUN R; MORTENSEN DEBORAH S; SATTIGERI VISWAJANANI JITENDRA; HUANG YING 权利人:UNIV ILLINOIS 摘要:This invention provides non-steroidal estrogen receptor ligands having a modular structure that is amenable to solid phase synthesis and the application of combinatorial synthetic methods to prepare these estrogen receptor ligands. ER ligands of this invention consist of a core scaffold that is a carbocyclic or heterocyclic-5-member ring that has two double bonds or a 6-member aromatic ring. A plurality of selected substituents are bonded to the ring substantially independently of other substituents. The modular structure of these compounds allows for synthesis of a very large numer of substituent structural variations, substituent combinations and substituent positioning on the core. The structural variants of the ER ligands of this invention exhibit a spectrum of selective affinities for ERα and ERβ and a spectrum of agonist/antagonist properties.
专利号:US-5405926-A 优先权日:1993-10-12 标 题:Polymer compositions and products made therefrom having nonlinear optical properties; methods for their synthesis, and for the production of the products 发明人:BRITTAIN WILLIAM J; KULIG JOSEPH J; MOORE COLLIN G 权利人:UNIV AKRON 摘要:This invention provides novel polyethers and polycarbonates which exhibit nonlinear optical response, and which have utility as a transparent optical component in optical light switch and high modulator devices. n These polyethers and polycarbonates are the polymerization product of one or more monomers having the formula ##STR1## in which Z is a conjugated heterocyclic substituent having a NO 2 or a CN group. Further, the invention relates to a method of making the polycarbonate by a ring opening polymerization in the presence of an electric field. In a separate embodiment, the invention relates to non-linear optical devices made with these polymers.
专利号:CN-105348064-A 优先权日:2015-12-08 标题 :A new method for the synthesis of α-diketones
专利号:DD-247899-A1 优先权日:1984-03-09 标题:PROCESS FOR SYNTHESIS OF 5,6-DISUBSTITUTED 1,2,4-TRIAZINES
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合成参考文献
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