专利号:US-6924385-B2 优先权日:2002-11-18 标 题:Method for synthesis of aliphatic isocyanates from aromatic isocyanates 发明人:LETTMANN CHRISTIAN; KOHLSTRUK STEPHAN; STOCHNIOL GUIDO; SPYROU EMMANOUIL 权利人:DEGUSSA 摘要:The invention relates to a method for synthesis of aliphatic isocyanates from aromatic isocyanates in substantially 3 stages. In particular, the invention relates to a method for synthesis of bis{4-isocyanatocyclohexyl}methane (H 12 MDI) from bis{4-isocyanatophenyl}methane (MDI). More especially, the invention relates to a method for synthesis of H 12 MDI with a trans-trans isomer content of <30%, preferably of <20%, particularly preferably of 5 to 15%.
专利号:US-4732945-A 优先权日:1986-10-15 标题 :Synthesis by reacting oxirane resin with carboxyl compounds 发明人:DAMMANN LAURENCE G 权利人:ASHLAND OIL INC 摘要:Disclosed is a new partial capping synthesis wherein resinous mixtures containing controlled amounts of phenolic hydroxyl and/or mercapto functionality, and aliphatic hydroxyl functionality are synthesized. Such synthesis comprises providing one or more resins which in total contain aliphatic primary and/or secondary hydroxyl functionality and oxirane functionality. A single resin or blend of resins may provide the requisite functionality. The one or more resins then are reacted with a carboxyl-functional capping agent bearing phenolic hydroxyl functionality and/or mercapto functionality. This reaction is conducted under reaction conditions and for a time such that the carboxyl functionality of the capping agent selectively reacts with the oxirane functionality of the one or more resins to produce a resinous product containing aliphatic hydroxyl functionality and containing phenolic hydroxyl functionality and/or mercapto functionality.
专利号:US-4826617-A 优先权日:1986-10-15 标题:Selective resin synthesis and dual functional resins made thereby 发明人:DAMMANN LAURENCE G 权利人:ASHLAND OIL INC 摘要:Disclosed is a new partial capping synthesis wherein resinous mixtures containing controlled amounts of phenolic hydroxyl and/or mercapto functionality, and aliphatic hydroxyl functionality are synthesized. Such synthesis comprises providing one or more resins which in total contain aliphatic primary and/or secondary hydroxyl functionality and oxirane functionality. A single resin or blend of resins may provide the requisite functionality. The one or more resins then are reacted with a carboxyl-functional capping agent bearing phenolic hydroxyl functionality and/or mercapto functionality. This reaction is conducted under reaction conditions and for a time such that the carboxyl functionality of the capping agent selectively reacts with the oxirane functionality of the one or more resins to produce a resinous product containing aliphatic hydroxyl functionality and containing phenolic hydroxyl functionality and/or mercapto functionality.
专利号:US-2004097752-A1 优先权日:2002-11-18 标 题:Method for synthesis of aliphatic isocyanates from aromatic isocyanates
专利号:US-7416765-B2 优先权日:2004-10-04 标 题 :Polymerizable liquid crystalline composition and liquid crystal film made from the composition 发明人:SEKI TAKASHI; NAKAMURA TOORU; MAZAKI HITOSHI 权利人:NIPPON OIL CORP 摘要:A polymerizable liquid crystalline composition comprises a side chain liquid crystalline polymer obtained by radical-copolymerizing a (meth)acrylic compound has an optically active site and a (meth)acrylic compound having an oxetanyl group, and a cation generator and thus have no functional group the synthesis of which is difficult, such as an epoxy group. The use of the polymerizable liquid crystalline composition provides a cholesteric liquid crystal film which is excellent in a capability of retaining the orientation after being aligned and fixed in a liquid crystal orientation and in mechanical strength without the necessity of a complicated operation such as photo irradiation under an inert gas atmosphere.
专利号:US-4818796-A 优先权日:1987-05-13 标 题:Polymers prepared by polymerizing alpha, beta-ethylenically unsaturated acids and epoxy compounds 发明人:DAS SURYYA K; PORTER JR SAMUEL; TYGER WAYNE H 权利人:PPG INDUSTRIES INC 摘要:Hydroxyl-containing polymers prepared by reaction of a polymerizable alpha, beta-ethylenically unsaturated carboxylic acid and an epoxy compound containing greater than 5 carbon atoms are disclosed. The polymer is prepared by free radical organic solution polymerization techniques. Synthesis of the polymers by this technique assures multiple hydroxyl functionality in all polymer chains thereby providing good cure response. The polymers are useful as binders in high solids coating compositions. When used with appropriate curing agents, the resultant coatings have good hardness, high gloss and distinctness of image, have good solvent and humidity resistance and are very resistant to acid etching. n Preferred reactants are: n (a) an alpha, beta ethylenically unsaturated carboxylic acid and n (b) a glycidyl ester of the formula ##STR1## where R=a tertiary aliphatic hydrocarbon group of 4 to 26 carbon atoms.
参考文献:10.1007/978-3-032-05220-9_19 摘要:Chowdhury S, Oluwajire O, Grace L. Bio-Based Epoxy Natural Fiber Composites for Marine Energy Harvesting. 2026. In: Proceedings of the American Society for Composites Annual Technical Conferences.