CAS: 13194-68-8; 4-Iodo-2-Methylaniline

相似化合物

666746-27-6 52415-00-6 4102-53-8

上下游产品

CAS号95-53-4 邻甲苯胺 | CAS号52415-00-6 4-碘-2-甲基-1-硝基苯 | CAS号120-66-1 乙酰邻甲苯胺 | CAS号611-05-2 3-甲基-4-硝基苯胺 | CAS号100377-05-7 2-iodo-5,5-dime... | CAS号60-29-7 乙醚 | CAS号7732-18-5 水 | CAS号7553-56-2 碘 | CAS号7664-93-9 硫酸 | CAS号860526-66-5 (4-amino-3-meth... | CAS号55919-82-9 5-碘-1H-吲唑 | CAS号227015-67-0 (4-iodo-2-methy... | CAS号212628-46-1 5-bromo-3,4-dif... | CAS号78881-21-7 4-氨基-3-甲基苯腈 | CAS号63019-98-7 2H,4h,5h,6h,7h,... | CAS号5326-47-6 2-氨基-5-碘苯甲酸 | CAS号31656-92-5 2-Methylphenyl azide | CAS号202865-85-8 2-溴-5-碘甲苯 | CAS号117324-09-1 N1-(4-碘-2-甲基苯基)乙酰胺 | CAS号75838-38-9 1,4-二碘-2-甲基苯

邻甲苯胺置于n-碘代丁二酰亚胺体系中,用 二甲基亚砜 用作溶剂,化学反应 72.0H,反应生成4-碘-2-甲基苯胺
参考文献:N-碘代琥珀酰亚胺在苯胺碘化的区域化学中的显着变化:1,2-二氯-3,4-二碘苯的合成
标题:N-碘代琥珀酰亚胺在苯胺碘化的区域化学中的显着变化:1,2-二氯-3,4-二碘苯的合成
摘要:通过nis在极性溶剂(例如dmso)中直接对苯胺进行碘化,可得到对碘化的产品,其区域选择性高达> 99%.在acoh存在下改用极性较小的溶剂(例如苯)会使该结果转向邻位异构体的急剧增加或优先生成,区域选择性也高达> 99%.该发现被用于合成1,2-二氯-3,4-二碘苯. 芳香胺-亲电取代-卤化-区域选择性-溶剂效应
Doi:10.1055/s-0031-1290118

专利信息

专利号:US-5998595-A
优先权日:1996-11-05
标题:Azidohalogenobenzyl derivatives, sugar compounds and protection of hydroxy groups
发明人：KUSUMOTO SHOICHI; FUKASE KOICHI
权利人:WAKO PURE CHEM IND LTD
摘要:Azidohalogenobenzyl derivatives of the formula (I) ##STR1## wherein A is a halogen atom, B is a halogen atom or a hydrogen atom, and X is a group reactive with a hydroxy group, methods of protecting hydroxy group(s) using said derivatives, and sugar compounds wherein a hydrogen atom of at least one hydroxy group is substituted by an azidohalogenobenzyl group. According to the present invention, there are provided novel derivatives capable of introducing a group into a compound having hydroxy group(s), which group is useful as a stable hydroxy-protecting group even in solid phase synthesis for the purpose of the extension of sugar chain under continuous acidic conditions and of being removed under mild conditions; sugar compounds protected by using said derivatives; and methods of protecting hydroxy group(s) using said derivatives.

专利号:US-10442886-B2
优先权日:2014-11-18
标题 :Mechanochromic luminescent material, mechanochromic resin obtained by crosslinking mechanochromic luminescent material, method for producing mechanochromic luminescent material, and method for producing mechanochromic
发明人：YABU HIROSHI; SAITO YUTA; SAITO SHOHEI; YAMAGUCHI SHIGEHIRO; NOBUSUE Shunpei
权利人:JAPAN SCIENCE & TECH AGENCY
摘要:Provided is a mechanochromic resin by which a stress applied to a material can be visualized in real time, and a mechanochromic luminescent material that is used in the synthesis of the mechanochromic resin. Stress can be visualized in real time by means of a mechanochromic luminescent material represented by formula (1) or formula (2) and a mechanochromic resin obtained by crosslinking the mechanochromic luminescent material. [Chemical formula 1] (In the formula, Y 1 and Y 2 each denote a substituent group that inhibits aggregation of the mechanochromic luminescent material represented by formula (1), and Y 1 and Y 2 may be same as or different from each other. Z 1 and Z 2 each denote a polymerizable group, and may be same as or different from each other.) [Chemical formula 2] (In the formula, Y 1 and Y 2 each denote a substituent group that inhibits aggregation of the mechanochromic luminescent material represented by formula (2), and Y 1 and Y 2 may be same as or different from each other. Z 1 and Z 2 each denote a polymerizable group, and may be same as or different from each other).

专利号:CN-116444382-A
优先权日:2022-01-07
标题:Synthesis method of 4-iodo-2-methylaniline