CAS: 2136-79-0; Chlorthal

该化合物是磷酸的一种氯化衍生物,其特点是在标准条件下其纯度和稳定性很高;该化合物由于其强固的芳香结构和活性碳化物组,在合成专门聚合物,农用化学品和染料方面起着关键中间作用;其四氯化脊椎可增强抗降解性,使之适合需要热稳定性和化学稳定性的应用;该产品通常作为细晶状粉供应,其批量至批量质量一致,确保工业工艺的可靠性能;建议适当处理和储存以保持其完整性,如同大多数卤化芳香酸一样.

结构式图片

欧盟法规

ECHA物质C&L通报

上下游产品

tetrachloroterephthaloyl dichloride terephthalic acid 2,3,5,6-tetrachloro-4-methyl-benzoic acid sulfuric acidDacthal [cobalt(II)(tetrachloroterephthalate)(dimethylformamide)2(ethanol)2

合成工艺路线路线简述

    四氯对苯二甲腈置于硫酸,水,溶剂黄146体系中,化学反应 72.0H,以91.2%的收率获得氯酞酸
    参考文献:Supramolecular Interactions In The Adduct Of Di-Triethylammonium,Tetrachlorobenzene-1,4-Dicarboxylate And Tetrachlorobenzene-1,4-Dicarboxylic Acid
    标题:Supramolecular Interactions In The Adduct Of Di-Triethylammonium,Tetrachlorobenzene-1,4-Dicarboxylate And Tetrachlorobenzene-1,4-Dicarboxylic Acid
    摘要:二-三乙基铵,四氯苯-1,4-二甲酸和四氯苯-1,4-二甲酸的加合物,即{2(C2H5)3Nh+c8Cl4O 4 2-H2C8Cl4O4},结晶为三linic,P-1,晶胞尺寸为 A = 8.5080(5) å,B = 8.9789(6) å,C = 12.5212(8) å,α = 93.301(1)°,β = 109.107(1)°,γ = 103.565(1)°,V = 869.2(1) å3 和 Z = 2.C8Cl4O 4 2-和 H2C8Cl4O4 分子通过沿 C 轴的 O-H-O 连接,沿 B 轴的 C-Cl-O=c 连接和沿 A 轴的 C-Cl-Cl-C 连接形成晶体结构的三维框架.(C2H5)3Nh+阳离子通过 N-H--O,C-H--O 和 C-H-π 等各种分子间相互作用驻留在三维框架的空腔中.在标题化合物中,四氯苯-1,4-二羧酸盐和四氯苯-1,4-二羧酸通过氢键和卤素键形成三维框架,三乙基铵通过超分子相互作用驻留在框架的空隙中.
    Doi:10.1007/s10870-008-9380-4

    海关参考信息

    专利信息


    专利号:WO-2024256370-A1
    优先权日:2023-06-13
    标 题 :Synthesis of glufosinate using an amidase-based process
    发明人:ZIMMERMANN GUNTHER; POTT MORITZ STEFAN
    权利人:BASF SE
    摘要:The present invention relates to a method of preparing glufosinate, comprising the steps of hydrolysing an N-carbamoyl glufosinate amide with an Amidase enzyme to form an N- carbamoyl amino acid compound followed by cleaving off the carbamoyl moiety of said N- carbamoyl amino acid compound.

    专利号:US-2021386068-A1
    优先权日:2018-11-07
    标题 :Compositions comprising pyridine carboxylate herbicides and very long chain fatty acid (vlcfa) synthesis inhibitor herbicides
    发明人:KISTER JEREMY; SATCHIVI NORBERT M
    权利人:CORTEVA AGRISCIENCE LLC
    摘要:Disclosed herein are compositions comprising (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a VLCFA synthesis inhibitor herbicide. Also disclosed herein are methods of controlling undesirable vegetation, comprising applying to vegetation or an area adjacent the vegetation or applying in soil or water to control the emergence or growth of vegetation (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof, and (b) a VLCFA synthesis inhibitor herbicide.

    专利号:US-2021352899-A1
    优先权日:2018-11-07
    标题 :Compositions comprising pyridine carboxylate herbicides and fatty acid and lipid synthesis inhibitor herbicides
    发明人:KISTER JEREMY; SATCHIVI NORBERT M
    权利人:CORTEVA AGRISCIENCE LLC
    摘要:Disclosed herein are compositions comprising (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a fatty acid and lipid synthesis inhibitor (FA/LSI) herbicide, an agriculturally acceptable salt or ester thereof, or mixtures thereof. Also disclosed herein are methods of controlling undesirable vegetation, comprising applying to vegetation or an area adjacent the vegetation or applying in soil or water to control the emergence or growth of vegetation (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a fatty acid and lipid synthesis inhibitor (FA/LSI) herbicide, an agriculturally acceptable salt or ester thereof, or mixtures thereof.

    专利号:TW-I655905-B
    优先权日:2012-07-24
    标题 :Contains 4-amino-3-chloro-5-fluoro-6-(4-chloro-2-fluoro-3-methoxyphenyl)pyridine-2-carboxylic acid or a derivative thereof and very long chain fatty acid (VLCFA) Synthesis of herbicidal compositions with fatty acid/fat synthesis inhibiting herbicides

    专利号:US-9644469-B2
    优先权日:2012-07-24
    标题 :Herbicidal compositions comprising 4-amino-3-chloro-5-fluoro-6-(4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid or a derivative thereof and VLCFA and lipid synthesis inhibiting herbicides
    发明人:YERKES CARLA N; MANN RICHARD K; SHIRAISHI IKUO; YANAGIYAMA SHINGO; SATCHIVI NORBERT M
    权利人:DOW AGROSCIENCES LLC
    摘要:A synergistic herbicidal composition containing (a) a compound of formula (I): n nor an agriculturally acceptable salt or ester thereof and (b) VLCFA and fatty acid/lipid synthesis inhibiting herbicides, including but not limited to, acetochlor, alachlor, anilofos, benfuresate, cafenstrole, dimethenamid-P, fentrazamide, indanofan, flufenacet, mefenacet, s-metolachlor, molinate, pethoxamid, pretilachlor, prosulfocarb, pyroxasulfone, thenylchlor and thiobencarb, or a salt or ester thereof, provide synergistic weed control of undesirable vegetation in direct-seeded, water-seeded and transplanted rice, cereals, wheat, barley, oats, rye, sorghum, corn or maize, sugarcane, sunflower, oilseed rape, canola, sugar beet, soybean, cotton, pineapple, pastures, grasslands, rangelands, fallowland, turf, tree and vine orchards, aquatics, plantation crops, vegetables, industrial vegetation management (IVM) or rights-of-way (ROW).

    专利号:US-9999223-B2
    优先权日:2008-05-21
    标 题 :Herbicidal composition comprising glyphosate, glufosinate or their salts
    发明人:SIEVERNICH BERND; MOBERG WILLIAM KARL; SIMON ANJA; WALTER HELMUT; EVANS RICHARD R
    权利人:BASF SE
    摘要:The present invention relates to a herbicidal composition which comprises:n a) at least one herbicide A selected from glyphosate, glufosinate and their salts, and b) a herbicide B which is 3-[5-(difluoromethoxy)-1-methyl-3-(trifluoromethyl)pyrazol-4-ylmethylsulfonyl]-4,5-dihydro-5,5-dimethyl-1,2-oxazole [common name: pyroxasulfone]. nn The present invention relates in particular to a herbicidal composition comprising:n a) at least one herbicide A selected from glyphosate, glufosinate and their salts, b) a herbicide B which is 3-[5-(difluoromethoxy)-1-methyl-3-(trifluoromethyl)pyrazol-4-ylmethylsulfonyl]-4,5-dihydro-5,5-dimethyl-1,2-oxazole [common name: pyroxasulfone], and c) at least one further herbicide C, which is selected from the herbicide groups C.1 to C.8:n C.1 herbicides of the group of acetolactate synthase inhibitors (ALS inhibitors), C.2 herbicides of the group of protoporphyrinogen oxidase inhibitors (PPO inhibitors), C.3 herbicides of the group of auxines, C.4 herbicides of the group of 4-hydroxyphenyl-pyruvate-dioxygenase inhibitors (HPPD inhibitors), C.5 herbicides of the group of phytoene desaturase inhibitors (PDS inhibitors), C.6 herbicides of the group of photosystem II inhibitors (PSII inhibitors), C.7 herbicides of the group of microtubulin inhibitors, and C.8 herbicides of the group of inhibitors of the synthesis of very long chain fatty acids (VLCFA inhibitors).
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    合成参考文献


    参考文献:10.1107/s1600536810045794
    摘要:Zheng C, Zhang P, Zhang P, Li S. catena-Poly[[[aquatris(pyridine-κN)nickel(II)]-μ-2,3,5,6-tetrachlorobenzene-1,4-dicarboxylato-κ2O1:O4] pyridine monosolvate]. Acta Crystallogr E Struct Rep Online. 2010 Nov 20;66(12):m1618. doi: 10.1107/s1600536810045794.
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