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CAS号15267-95-5 氯甲基三乙氧基硅烷

氯甲基三乙氧基硅烷,苯胺 反应 19.0H,以14%的收率获得产物苯胺甲基三乙氧基硅烷
参考文献:来自烷基取代的烯烃的线性加氢氨基烷基化产物.
标题:来自烷基取代的烯烃的线性加氢氨基烷基化产物.
摘要:烷基取代的烯烃向线性氢氨基烷基化产物的区域选择性转化代表了非常理想的合成转化.特别是n的这种转换甲胺衍生物具有极大的科学意义,因为它们可以直接获得具有直链烷基链的重要胺.在本文中,我们提出了一种新的单锅法,其中包括使用α-甲硅烷基化的胺底物进行的初始烯烃加氢烷基化反应和随后的原去烷基化反应,该反应可从简单的烷基取代的烯烃中以较高的选择性提供线性的加氢氨基烷基化产物.为此,已经开发出了新型的钛催化剂,它们能够激活更具挑战性的α-硅烷化胺底物的α-Ch键.另外,描述了新催化剂的配体结构与所获得的区域选择性之间的直接关系.
DOI:10.1002/chem.202003223

专利信息

专利号:US-9617396-B2
优先权日:2012-02-22
标 题:Method for in-situ synthesis of silicon nanoparticles
发明人：SCHUBERT CHLOÉ; PONCELET OLIVIER
权利人:COMMISSARIAT ENERGIE ATOMIQUE
摘要:The invention relates to a method for in-situ synthesis of silicon nanoparticles in a thermosetting polymeric matrix, the thermosetting and thermoset matrices obtained in this way and a material including same. The method includes the following steps: a) forming an aqueous-phase/organic-phase inverse emulsion, wherein the aqueous phase includes at least a basic catalyst and the organic phase includes at least a non-cross-linked (co)polymer precursor chosen from an aliphatic, cycloaliphatic or aromatic epoxy resin precursor, a polyester-imide precursor, an unsaturated/epoxy polyester (co)polymer precursor, a polyether/epoxy (co)polymer precursor and a polyurethane precursor; b) introducing, into the inverse emulsion formed in step a), at least one silicon precursor forming a complete network whereof the rate of hydrolysis is greater than the cross-linking speed of the (co)polymer and c) stirring the mixture obtained in step b) and heating to a temperature between 20° C. and 70° C.

专利号:US-10486970-B2
优先权日:2016-01-14
标题 :Method for preparation of graft modified ammonium polyphosphate with ultra-low hydroplaning and resistance to hydrolysis and application thereof
发明人：HE YANLING; ZHANG XIUQIN
权利人:ZHONGSHAN COMPLORD NEW MAT CO LTD
摘要:A method for preparation of graft modified ammonium polyphosphate with ultra-low hydroplaning and resistance to hydrolysis belongs to the field of the preparation of flame retardant. Ammonia water is used as hydrolytic agent of amino silane. In the early stage of synthesis of ammonium polyphosphate with phosphorus pentoxide, diammonium hydrogen phosphate and melamine as raw materials, hydrolyzed amino silane ammonia mixture is added, and continues warming reaction, when the temperature drops to a certain temperature, melamine is added to maintain high temperature reaction for a certain period of time, then cools to obtain graft modified ammonium polyphosphate with ultra-low hydroplaning and resistance to hydrolysis. The present disclosure grafts ammonium polyphosphate with two kinds of amino grafting in stages, and the modified ammonium polyphosphate products after grafted basically have no hydroplaning when meets water. Because of addition of excessive melamine in late stage, the excessive melamine is not only used for graft modified ammonium polyphosphate, but also used for reacting with acidic ammonium polyphosphate whose polymerization is incomplete, making it form polyphosphate melamine, eliminate the formation of water-soluble small molecules, and reduce water solubility of the products to a greater extent.

专利号:US-10875879-B2
优先权日:2017-09-12
标题:Compositions, synthesis, and uses of hydrolyzable silane modified cashew nut shell liquid derivatives
发明人：NATESH ANBAZHAGAN; STONIS TIMOTHY; TAMBE CHETAN; CAMPANER PIETRO
权利人:CARDOLITE CORP
摘要:The present disclosure provides cashew nut shell liquid derivatives based organosilicon products and methods and uses of preparing the same.

专利号:US-2015031794-A1
优先权日:2012-02-22
标题 :Method For In-Situ Synthesis Of Silicon Nanoparticles

专利号:EP-2817361-B1
优先权日:2012-02-22
标题:Process for in-situ synthesis of silica nanoparticules

专利号:EP-2817361-A1
优先权日:2012-02-22
标题:Method for in-situ synthesis of silicon nanoparticles