CAS: 4363-93-3; Quinoline-4-Carbaldehyde

相似化合物

486-74-8 6281-32-9 2973-27-5

上下游产品

CAS号491-35-0 4-甲基喹啉 | CAS号5450-80-6 4-(2H-pyridin-1... | CAS号5632-16-6 4-(溴甲基)喹啉 | CAS号87-51-4 吲哚-3-乙酸 | CAS号1912-33-0 吲哚-3-乙酸甲酯 | CAS号2591-98-2 吲哚-3-乙醛 | CAS号110-88-3 三聚甲醛 | CAS号91-22-5 喹啉 | CAS号123-91-1 1,4-二氧六环 | CAS号7446-08-4 二氧化硒 | CAS号60814-30-4 1-(喹啉-4-基)乙-1-酮 | CAS号5632-13-3 4-氨基甲基喹啉盐酸盐 | CAS号486-74-8 4-喹啉羧酸 | CAS号6281-32-9 4-喹啉甲醇 | CAS号491-35-0 4-甲基喹啉 | CAS号57056-95-8 1-formyl-4-meth... | CAS号79180-50-0 4-methylquinoli... | CAS号1822-57-7 4-(氯甲基)喹啉盐酸盐 | CAS号91-22-5 喹啉 | CAS号728033-96-3 3-[(4-喹啉甲基)氨基]-...

吲哚-3-乙醛置于二甲基硫,氧气体系中,化学反应生成 4-喹啉甲醛
参考文献:单线态氧通过n-1-C-2裂变将吲哚转化为喹啉,作为仿生合成奎宁生物碱的模型实验
标题:单线态氧通过n-1-C-2裂变将吲哚转化为喹啉,作为仿生合成奎宁生物碱的模型实验
摘要:吲哚-3-乙醛(的光充氧28-30),然后用二甲硫处理,然后稀醋酸,得到4-Acylquinolines(13,31和32),分别.
DOI:10.1016/s0040-4020(01)96581-0

专利信息

专利号:US-2022356139-A1
优先权日:2019-09-03
标 题:Synthesis of deuterated aldehydes
发明人：WANG WEI
权利人:ARIZONA BOARD OF REGENTS ON BEHALF OF ATHE UNIV OF ARIZONA
摘要:Described are methods for preparing a deuterated aldehyde using N-heterocyclic carbene catalysts in a solvent comprising D 2 O. The methods may be used to convert a wide variety of aldehydes (e.g., aryl, alkyl, or alkenyl aldehydes) to C-1 deuterated aldehydes under mild reaction conditions without functionality manipulation.

专利号:US-5175302-A
优先权日:1987-07-13
标 题 :Nucleophilic fluoroalkylation of aldehydes
发明人：STAHLY G PATRICK
权利人:ETHYL CORP
摘要:Aryl difluoromethyl sulfone adds to aldehydes under phase transfer conditions to give novel substituted alcohols of the general formula n n RCH(OH)CF.sub.2 SO.sub.2 Ar (I) n n wherein R is an aryl, cycloaliphatic, sec- or tert-aliphatic, or heterocyclic group and Ar is an aryl group. The substituted alcohols of formula I are of particular utility as intermediates in the synthesis of a variety of useful end products. For example, the products of formula I may be utilized in desulfonylation reactions, oxidation reactions and fluorination reactions.

专利号:US-4837327-A
优先权日:1987-07-13
标 题 :Process for nucleophilic fluoroalkylation of aldehydes
发明人：STAHLY G PATRICK
权利人:ETHYL CORP
摘要:Aryl difluoromethyl sulfone adds to alkehydes under phase transfer conditions to give novel substituted alcohols of the general formula n n RCH(OH)CF.sub.2 SO.sub.2 Ar (I) n n wherein R is an aryl, cycloaliphatic, sec- or tert-aliphatic, or heterocyclic group and Ar is an aryl group. The substituted alcohols of formula I are of particular utility as intermediates in the synthesis of a variety of useful end products. For example, the products of formula I may be utilized in desulfonylation reactions, oxidation reactions and fluorination reactions.

专利号:US-4999429-A
优先权日:1989-01-09
标 题 :Process for the preparation of α,α,β-1-trifluoro-1-olefinic derivatives
发明人：STAHLY G PATRICK
权利人:ETHYL CORP
摘要:Aryl difluoromethyl sulfone adds to aldehydes under phase transfer conditions to give novel substituted alcohols of the general formula n n RCH(OH)CF.sub.2 SO.sub.2 Ar (I) n n wherein R is an aryl, cycloaliphatic, sec- or tert-aliphatic, or heterocyclic group and Ar is an aryl group. The substituted alcohols of formula I are of particular utility as intermediates in the synthesis of a variety of useful end products. For example, the products of formula I may be utilized in desulfonylation reactions, oxidation reactions and fluorination reactions.

专利号:US-7960553-B1
优先权日:2006-10-02
标 题 :Reagent for synthesis of para-methoxbenzyl (PMB) ethers and associated methods
发明人：DUDLEY GREGORY B
权利人:UNIV FLORIDA STATE RES FOUND
摘要:A newly synthesized compound designated lepidine ether 2-(4-Methoxybenzyloxy)-4-methylquinoline reacts with methyl triflate in the presence of alcohols to generate a neutral organic salt that transfers the para-methoxybenzyl (PMB) protecting group onto alcohols in high yield and under mild conditions.

专利号:US-11161823-B2
优先权日:2019-03-11
标 题 :Anticancer 1,3-dioxane-4,6-dione derivatives and method of combinatorial synthesis thereof
发明人：ISLAM IMADUL; AL-KAYSI RABIH O; BOUDJELAL MOHAMED; ALI RIZWAN; NEHDI ATEF; ALGHANEM BANDAR
权利人:NAT GUARD HEALTH AFFAIRS; KING SAUD BIN ABDULAZIZ UNIV FOR HEALTH SCIENCES; KING ABDULLAH INTERNATIONAL MEDICAL RES CENTER; KING ABDULLAH INETRNATIONAL MEDICAL RES CENTER
摘要:Compounds, methods of synthesis, and methods of cancer treatment by arylidene-1,3-dioxane-4,6-diones. A Meldrum's acid-based chemistry and hybrid solid-liquid method. The method includes protection of ketone and aldehyde components and simultaneous immobilization on the solid phase, introduction of substituents, grafts and derivatives compatible with the protection, detachment and restoration of active carbonyl reactivity, reaction of ketone library with malonate, reacting of the products with the aldehyde library in liquid phase and separation of the products by preparative HPLC.