Bismuth (Iii) Nitrate Pentahydrate,Potassium Chloride置于乙二醇,Sodium Hydroxide体系中,用 水 作为反应溶剂,化学反应 2.0H,反应生成 氯氧化铋 参考文献:紫外线照射下biocl对三氯乙烯的光催化降解. 标题:紫外线照射下biocl对三氯乙烯的光催化降解. 摘要:在这项研究中,Biocl样品是在不同ph值下合成的,并通过xrd,Sem,Uv-Vis Drs,Bet,光电化学测量和pl进行表征.通过三氯乙烯(tce)在紫外线照射下的分解来评估所制备样品的光催化性能.研究了溶液ph值和常见的无机阴离子等参数对tce去除的影响.结果表明,Biocl-0.6表现出比biocl-6.0更好的光催化性能,因为它具有更高的光诱导载体迁移能力.在biocl-0.6上,Tce的光催化降解遵循伪一级动力学,并且在酸性溶液中似乎比在碱性溶液中更有效.tce在120分钟内几乎完全脱氯.3-> So 4 2-> No 3-,而氯-表现出双重的效果.此外,Biocl-0.6在三个循环的重复测试后显示出优异的可重用性. DOI:10.1002/aoc.4354
专利信息
专利号:US-8709304-B2 优先权日:2009-12-14 标题 :Hydrothermal synthesis of nanocubes of sillenite type compounds for photovoltaic applications and solar energy conversion of carbon dioxide to fuels 发明人:SUBRAMANIAN VAIDYANATHAN; MURUGESAN SANKARAN 权利人:SUBRAMANIAN VAIDYANATHAN; MURUGESAN SANKARAN; UNIV NEVADA 摘要:The present invention relates to formation of nanocubes of sillenite type compounds, such as bismuth titanate, i.e., Bi 12 TiO 20 , nanocubes, via a hydrothermal synthesis process, with the resulting compound(s) having multifunctional properties such as being useful in solar energy conversion, environmental remediation, and/or energy storage, for example. In one embodiment, a hydrothermal method is disclosed that transforms nanoparticles of TiO 2 to bismuth titanate, i.e., Bi 12 TiO 20 , nanocubes, optionally loaded with palladium nanoparticles. The method includes reacting titanium dioxide nanotubes with a bismuth salt in an acidic bath at a temperature sufficient and for a time sufficient to form bismuth titanate crystals, which are subsequently annealed to form bismuth titanate nanocubes. After annealing, the bismuth titanate nanocubes may be optionally loaded with nano-sized metal particles, e.g., nanosized palladium particles.
专利号:US-2023111600-A1 优先权日:2019-12-17 标题 :Polymeric fatty acid compounds for the treatment of fibrous amino acid-based substrates, especially hair 发明人:WAGNER ROLAND; STREICHER KATHARINA; ROHMANN LAURA; WENSKE CHRISTIAN; HAVELI SHRUTISAGAR DATTATRAYA 权利人:MOMENTIVE PERFORMANCE MAT GMBH 摘要:The present invention is directed at mono-, di- or polyquaternary ammonium compounds of the formula (I) wherein x is 1 to 50, and F can be the same or different and is represented by the general formula (II) wherein at least one of the optionally substituted and optionally functional-group-containing hydrocarbon radicals R 1 , R 2 , R 3 , R 4 or R 5 contains at least one estolide moiety comprising two or more ester or amide moieties. The invention also relates to a process for the synthesis of such compounds, the use of the compounds in cosmetic formulations for skin and hair care, cosmetic compositions for the treatment of fibers, and compositions containing one or more of the compounds for the treatment of hair.
专利号:US-11612556-B2 优先权日:2014-12-16 标 题:Peptidic compounds, compositions comprising them and uses of said compounds, in particular cosmetic uses 发明人:PESCHARD OLIVIER; DOUCET ANNE; LEROUX RICHARD; MONDON PHILIPPE 权利人:SEDERMA SA 摘要:The peptidic compound comprises at least an aminoacid which is lysine, ornithine, diaminopropionic acid or diaminobutyric acid or a derivative of these aminoacids, on which a carboxylic acid is grafted via a peptidic bound on the nitrogen of the lateral chain, said carboxylic acid comprising a (poly)cycle or (poly)heterocycle. Preferably, the grafted carboxylic acid is an aminoacid or a derivative, in particular selected from, a proline, a hydroxyproline or pyroglutamic acid.The peptidic compound can stimulate the synthesis of the main molecules constituting the extracellular matrix of the skin, especially collagen 1 and 4 and elastin. It can be used for topical cosmetic treatment such as a global anti-aging treatment, or for specific activities, including anti-wrinkles, moisturizing, to improve the mechanical properties of the skin, firmness/tone/elasticity/flexibility, to increase density and volume of the skin, improve skin radiance, for a restructuring effect and/or to fight stretch marks.
专利号:US-2022288005-A1 优先权日:2019-07-26 标题:Synthesis of pro-resolving analogs and compositions therefor 发明人:VAN DYKE THOMAS E; SERHAN CHARLES N 权利人:NOCENDRA INC 摘要:This disclosure relates to methods of synthesizing certain lipoxin analogs (e.g., lipoxin mimetics, etc.) and pharmaceutical compositions comprising these pro-resolving compounds. Methods of administering the lipoxin mimetics (e.g., lipoxin A4 mimetics, lipoxin B4 mimetics, etc.) to patients in need thereof are also provided.
专利号:US-9561493-B2 优先权日:2010-05-11 标题 :Synthesis of pyrochlore nanostructures and uses thereof 发明人:SUBRAMANIAN VAIDYANATHAN; MURUGESAN SANKARAN 权利人:SUBRAMANIAN VAIDYANATHAN; MURUGESAN SANKARAN; UNIV NEVADA RENO 摘要:A template-free reverse micelle (RM) based method is used to synthesize pyrochlore nanostructures having photocatalytic activity. In one embodiment, the method includes separately mixing together a first acid stabilized aqueous solution including pyrochlore precursor A and a second acid stabilized aqueous solution including pyrochlore precursor B with an organic solution including a surfactant to form an oil-in-water emulsion. Next, equimolar solutions of the first and second acid stabilized oil-in-water emulsions are mixed together. Then, the mixture of the first and second acid stabilized oil-in-water emulsion is treated with a base to produce a precipitate including pyrochlore precursors A and B. After which, the precipitate is dried to remove volatiles. The precipitate is then calcined in the presence of oxygen to form a pyrochlore nanostructure, such as a bismuth titanate (Bi 2 Ti 2 O 7 ) pyrochlore nanorod. The method of synthesizing the pyrochlore nanorod is template-free.
专利号:WO-2006097348-A1 优先权日:2005-03-15 标 题:Use of agents such as nonpolymeric nitric oxide donors for making the lips full again and/or colouring the lips 发明人:CALS-GRIERSON MARIE-MADELEINE 权利人:OREAL; CALS-GRIERSON MARIE-MADELEINE 摘要:The invention relates in particular to the cosmetic use (i) of at least one agent for promoting the production of NO in and/or on the lips, chosen from nitric oxide NO donors or precursors; nonpolymeric NO releasers; and NO synthase synthesis and/or activity stimulators; or (ii) of other agents for promoting microcirculation in the skin, chosen from potassium channel openers; calcium channel blockers; phosphodiesterase inhibitors; flavonoids; vasodilator peptides that are not NO donors; temperature modulators; agents for promoting the stimulation and/or maintenance of angiogenesis; agents for promoting the stimulation of endothelial cell proliferation; agents for promoting endothelial cell migration; and mixtures thereof, in a makeup and/or care composition for the lips, as an agent for naturally making the lips full again and/or naturally coloring the lips. It also relates to specific care and/or makeup compositions for the lips containing said agent, and also to a cosmetic process aimed at making the lips naturally full and/or colored, using said compositions .
[参考文献]: Bhawna Sarwan, Et Al. Mineralization And Toxicity Reduction Of Textile Dye Neutral Red In Aqueous Phase Using Biocl Photocatalysis. J Photochem Photobiol B. 2012 Nov 5:116:48-55. [参考文献]: Dong-Hong Wang, Et Al. Nanosheet-Constructed Porous Biocl With Dominant {001} Facets For Superior Photosensitized Degradation. Nanoscale. 2012 Dec 21;4(24):7780-5. [参考文献]: Mohammed A Gondal, Et Al. Biocl-Assisted Photodegradation Of Rhodamine B Under White Light And Monochromatic Green Pulsed Laser Irradiation. J Environ Sci Health A Tox Hazard Subst Environ Eng. 2012;47(8):1192-200. [参考文献]: R L Ward, Et Al. In Vitro Activities Of Bismuth Salts Against Rotaviruses And Other Enteric Viruses. Antimicrob Agents Chemother. 1985 Mar;27(3):306-8. [参考文献]: S R Akhundov, Et Al. [参考文献]: Gig Tr Prof Zabol. 1986 Jun:(6):16-21.
合成参考文献
摘要:S13 | EUCOSMETICS | Combined Inventory of Ingredients Employed in Cosmetic Products (2000) and Revised Inventory (2006) | DOI:10.5281/zenodo.2624118 参考文献:10.1007/bf00202053 摘要:Gump DW, Nadeau OW, Hendricks GM, Meyer DH. Evidence that bismuth salts reduce invasion of epithelial cells by enteroinvasive bacteria. Medical Microbiology and Immunology. 1992 Jul;181(3):131–43. doi: 10.1007/bf00202053.