CAS: 99-08-1; 3-Nitrotoluene

上下游产品

CAS号625-95-6 3-甲碘苯 | CAS号17933-03-8 3-甲基苯硼酸 | CAS号3958-57-4 3-硝基苄溴 | CAS号108-88-3 甲苯 | CAS号13506-76-8 2-甲基-6-硝基苯甲酸 | CAS号3748-99-0 Benzenesulfonic... | CAS号645-00-1 1-碘-3-硝基苯 | CAS号333-27-7 三氟甲烷磺酸甲酯 | CAS号74-88-4 碘甲烷 | CAS号1975-51-5 2-甲基-4-硝基苯甲酸 | CAS号588-04-5 3,3'-二甲基偶氮苯 | CAS号108-44-1 3-甲基苯胺 | CAS号19618-06-5 3,3''-AZOXYTOLUENE | CAS号106011-93-2 bis(N,N-dimethy... | CAS号620-25-7 META-TOLYLHYDRO... | CAS号621-26-1 3,3'-dimethylhy... | CAS号70970-06-8 m-nitrobenzylid... | CAS号3958-57-4 3-硝基苄溴 | CAS号537-92-8 N-乙酰基-3-甲苯胺 | CAS号612-60-2 7-甲基喹啉

3-甲基苯胺置于双氧水,乙腈体系中,用 Aq. Buffer 作为反应溶剂,化学反应 1.0H,以88%的收率获得产物3-硝基甲苯
参考文献:取代的苯胺的有机催化氧化为乙氧基苯和硝基化合物:机理研究不包括二环氧乙烷中间体的参与
标题:取代的苯胺的有机催化氧化为乙氧基苯和硝基化合物:机理研究不包括二环氧乙烷中间体的参与
摘要:开发了有机催化和环境友好的方法来选择性氧化取代的苯胺.利用2,2,2-三氟苯乙酮介导的氧化过程,可以将取代的苯胺转化为a氧基苯,同时进行简单的处理...
DOI:10.1039/c6Gc03174A

专利信息

专利号:US-5512701-A
优先权日:1995-06-07
标题:Process for the synthesis of vinyl sulfenic acid derivatives
发明人：HOARD DAVID W; LUKE WAYNE D
权利人:LILLY CO ELI
摘要:The present invention is directed to a new process for the synthesis of vinyl sulfenic acid derivatives. These compounds are useful for the synthesis of benzo[b]thiophenes, in particular 2-aryl-benzo[b]thiophenes.

专利号:US-6372945-B1
优先权日:1995-06-07
标 题 :Process for the synthesis of vinyl sulfoxides
发明人：AIKINS JAMES A; MILLER RANDAL SCOT; ZHANG TONY Y
权利人:LILLY CO ELI
摘要:The present invention is directed to a new process for the synthesis of vinyl sulfoxides, in particular diarylvinyl sulfoxides

专利号:US-5606076-A
优先权日:1995-06-07
标 题 :Process for the synthesis of benzo[b]thiophenes
发明人：AIKINS JAMES A; ZHANG TONY Y
权利人:LILLY CO ELI
摘要:The present invention is directed to a process for the synthesis of 2-arylbenzo[b]thiophenes.

专利号:US-5569772-A
优先权日:1995-06-07
标 题:Process for the synthesis of benzo[b]thiophenes
发明人：HOARD DAVID W; LUKE WAYNE D
权利人:LILLY CO ELI
摘要:The present invention is directed to a new process for the synthesis of 2-aryl benzo[b]thiophenes, and to novel intermediates therefor.

专利号:US-5606075-A
优先权日:1995-06-07
标 题:Process for the synthesis of benzo[b]thiophenes
发明人：HOARD DAVID W; LUKE WAYNE D
权利人:LILLY CO ELI
摘要:The present invention is directed to new processes for the synthesis of 2-aryl benzo[b]thiophenes.

专利号:US-11745159-B2
优先权日:2017-10-20
标题:Heated nanowells for polynucleotide synthesis
发明人：MARSH EUGENE P; INDERMUHLE PIERRE F; PECK BILL JAMES
权利人:TWIST BIOSCIENCE CORP
摘要:Defined sequence RNA synthesis by 3′→5′ direction is now well established and currently in use for synthesis and development of vast variety of therapeutic grade RNA and Si RNA etc. A number of such synthetic RNA requires a modification or labeling of 3′-end of an oligonucleotide. The synthesis of 3′-end modified RNA requiring lipophilic, long chain ligands or chromophores, using 3′→5′ synthesis methodology is challenging, requires corresponding solid support and generally results in low coupling efficiency and lower purity of the final oligonucleotide in general because of large amount of truncated sequences containing desired hydrophobic modification. We have approached this problem by developing reverse RNA monomer phosphoramidites for RNA synthesis in 5′→3′-direction. They lead to very clean oligonucleotide synthesis allowing for introduction of various modifications at the 3′-end.