108-93-0 = 84-61-7 反应条件:1.1 Solvents: Cyclohexane; 4 H,200 °C 标题:Synthesis,Characterization And Catalytic Properties Of Sapo-11,-31 And -41 Molecular Sieves 作者:Venkatathri,N.; Srivastava,R. 参考文献:Indian Journal Of Chemistry 日期:2004 卷标:(5) 页码:1039-1043]
108-93-0 = 84-61-7 反应条件:1.1 Catalysts: 1H-Imidazolium,3-[4-[(Diphenylphosphino)Oxy]Butyl]-1-Methyl-,Chloride (1:1); 6 H,100 °C 标题:Efficient Synthesis Of Symmetrical Phthalate And Maleate Diesters Using Phosphinite Ionic Liquids 作者:Valizadeh,H.; Khalili,E. 参考文献:Journal Of The Iranian Chemical Society 日期:2012 卷标:9(4) 页码:529-534]
131-11-3 + 108-93-0 = 84-61-7 反应条件:1.1 Catalysts: Sodium Methoxide; 6 H,145 °C 标题:Research On Dicyclohexyl Phthalate Synthesis By Transesterification 作者:Zheng,Xingrong 参考文献:Guangdong Huagong 日期:2011 卷标:38(7) 页码:53-54]
苯酐,环己醇置于1-(4-Diphenylphosphinitebutyl)-3-Methylimidazolium Chloride体系中,用 Neat (No Solvent) 作为反应溶剂,化学反应 6.0H,以80%的收率获得产物邻苯二甲酸二环己酯 参考文献:Efficient Synthesis Of Symmetrical Phthalate And Maleate Diesters Using Phosphinite Ionic Liquids 标题:Efficient Synthesis Of Symmetrical Phthalate And Maleate Diesters Using Phosphinite Ionic Liquids 摘要:使用磷酸盐离子液体作为催化剂和反应介质合成了对称的二烷基邻苯二甲酸酯和马来酸酯.研究结果表明,磷酸盐离子液体在没有使用任何酸或碱催化剂的情况下,表现出更好的催化和重复使用性能.在最佳条件下,使用1-甲基-3-(4-磷酸盐丁基)咪唑氯化物作为催化剂,邻苯二甲酸酐和马来酸酐转化为相应的初级和次级醇的二酯,产率在72%到85%之间.这种方法无法制备三级醇和酚的二酯.在这些条件下,一种广泛使用的增塑剂,二辛基邻苯二甲酸酯,获得了非常好的产率.离子液体经过简单的产品分离后可以重复使用三次,无需任何处置. DOI:10.1007/s13738-011-0065-0
专利号:US-11780952-B2 优先权日:2016-08-08 标题:Process for the synthesis of silylated polyurethanes and silylated polyurethane composition 发明人:LAFERTE OLIVIER 权利人:BOSTIK SA 摘要:The present invention provides a process for the synthesis of silylated polyurethanes, comprising three sequential steps, a step (i) of preparing NCO-terminated polyurethane, a step (ii) of partial grafting of the NCO functions with silane functions and a step (iii) of total grafting of the residual NCO functions with functions that react with the NCO functions by means of polyfunctional compounds. The present invention also provides a silylated polyurethane composition that can be obtained by means of the process according to the invention, an adhesive composition comprising said silylated polyurethane composition and a self-adhesive item obtained from the adhesive composition according to the invention.
专利号:US-7749300-B2 优先权日:2008-06-05 标题 :Photochemical synthesis of bimetallic core-shell nanoparticles 发明人:CHRETIEN MICHELLE N; WU YILIANG; CHOPRA NAVEEN 权利人:XEROX CORP 摘要:A method of forming bimetallic core-shell metal nanoparticles including a core of a first metal material and a shell of a second metal material, the method including photochemically producing metallic nanoparticle cores of the first metal material, and forming a shell of the second metal material around the cores. The shell can be formed by adding shell-forming precursor materials to a solution or suspension of the cores and photochemically forming the shells around the cores, or by separately photochemically producing metallic nanoparticles of the second metal material and mixing the metallic nanoparticles of the second metal material and the metallic nanoparticle cores to cause the metallic nanoparticles of the second metal material to form a shell around the metallic nanoparticle cores.
专利号:US-2010278715-A1 优先权日:2009-04-29 标 题:Systems, Devices, and/or Methods Regarding Specific Precursors or Tube Control Agent for the Synthesis of Carbon Nanofiber and Nanotube 发明人:KHE NGUYEN 权利人:TH LLC 摘要:Certain exemplary embodiments can comprise, via a tube control agent (TCA) and a metallic catalyst, producing a carbon nanotube. At least some carbon used to form the carbon nanotube can be obtained from a plant, a cellulose product, and/or a cellulosic product. At least some of the carbon can be converted into powder.
专利号:US-7789935-B2 优先权日:2008-05-23 标 题:Photochemical synthesis of metallic nanoparticles for ink applications 发明人:CHRETIEN MICHELLE N; CHOPRA NAVEEN; HEUFT MATTHEW; KAZMAIER PETER M 权利人:XEROX CORP 摘要:A method of forming an ink, including photochemically producing stabilized metallic nanoparticles and formulating the nanoparticles into an ink.
专利号:WO-2024151591-A1 优先权日:2023-01-10 标 题 :Microwave-assisted synthesis of polyacrylic beads and the use thereof 发明人:TEHRANI ROUZBEH AFSARMANESH; ALIMOHAMMADI FARBOD 权利人:UNIV TEMPLE 摘要:A novel method of synthesizing polyacrylic beads, comprising the steps of suspending a monomer and a cross-linking agent in a solution, heating the solution in a microwave reactor, cooling the solution, and collecting the polyacrylic beads. The polyacrylic beads can be used in to remove solutes from various solutions, including blood, porcine blood, dialysate, serum, contaminated water, wastewater, and combinations thereof.
专利号:EP-1654330-B1 优先权日:2003-07-23 标题:Utilization of water-dilutable condensation resin as water-dilutable dispersing agent for pigment concentrates 发明人:HOBISCH GERALD; MORRE PETER 权利人:CYTEC SURFACE SPECIALTIES AT 摘要:The invention relates to the utilization of water-dilutable condensation resin AB as dispersing agent for pigments, wherein the condensation resins have an acid value ranging from 20 mg/g to 180 mg/g and are obtained by condensation of component A containing acid groups with an acid value ranging from 30 mg/g to 240 mg/g, which are selected from amongst the group consisting of copolymers of olefinically unsaturated monomers and by dimerization or oligomerization of compounds obtained from unsaturated aliphatic carboxylic acids and polyesters B containing hydroxyl groups with a hydroxyl value ranging from 20 mg/g to 300 mg/g and a number-average molar mass Mn ranging from 500 g/mol to 5000 g/mol. The mass proportion of components A in the reaction mixture for the synthesis of the condensation resin AB amounts to 30% to 90% and that of component B amounts to 70% to 10%, with the proviso that the sum of the mass proportions of both components always amounts to 100%.
1: Aydoğan Ahbab M, Barlas N. Influence of in utero di-n-hexyl phthalate and dicyclohexyl phthalate on fetal testicular development in rats. Toxicol Lett. 2015 Mar 4;233(2):125-37. doi: 10.1016/j.toxlet.2015.01.015. Epub 2015 Jan 28. doi: 10.1016/j.fct.2012.09.010. Epub 2012 Sep 25. doi: 10.1177/0960327113494903. Epub 2013 Jul 8. pii: E533. doi: 10.3390/ijerph13060533. 5: Li X, Chen X, Hu G, Li L, Su H, Wang Y, Chen D, Zhu Q, Li C, Li J, Wang M, Lian Q, Ge RS. Effects of in Utero Exposure to Dicyclohexyl Phthalate on Rat Fetal Leydig Cells. Int J Environ Res Public Health. 2016 Feb 23;13(3). pii: E246. doi: 10.3390/ijerph13030246. 6: Svingen T. Comments on Li et al. Effects of in Utero Exposure to Dicyclohexyl Phthalate on Rat Fetal Leydig Cells. Int. J. Environ. Res. Public Health 2016, 13, 246. Int J Environ Res Public Health. 2016 May 25;13(6). pii: E532. doi: 10.3390/ijerph13060532.
合成参考文献
摘要:BIBRA Toxicology International p5 (1994) 摘要: 摘要: 摘要:USEPA/Pollution Prevention and Toxics; 2012 Chemical Data Reporting Database. 1,2-Benzenedicarboxylic acid, 1,2-dicyclohexyl ester (84-61-7). Available from, as of February 27, 2015: 摘要:EPA/Office of Pollution Prevention and Toxics; High Production Volume (HPV) Challenge Program. 1,2-Benzenedicarboxylic acid, dicyclohexyl ester (84-61-7). Available from, as of February 26, 2015: https://www.epa.gov/hpv/pubs/general/opptsrch.htm