CAS: 10519-87-6; Dimethyldivinylsilane

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CAS号75-01-4 乙烯基氯 | CAS号75-78-5 二甲基二氯硅烷 | CAS号1066-35-9 二甲基一氯硅烷 | CAS号3536-96-7 乙烯基氯化镁 | CAS号1826-67-1 乙烯基溴化镁 | CAS号1112-56-7 四乙烯基锡 | CAS号593-60-2 溴乙烯 | CAS号1719-58-0 二甲基乙烯基氯硅烷 | CAS号75-78-5 二甲基二氯硅烷 | CAS号51664-50-7 bis(2-bromoethy...

乙烯基氯化镁,二氯二甲基硅烷 以 乙醚 用作溶剂,化学反应 5.0H,以86%的收率获得二乙烯基二甲基硅烷
参考文献:Sila-α-Galbanone 和类似物:白松香加味剂 α-Galbanone 含硅衍生物的合成和嗅觉表征
标题:Sila-α-Galbanone 和类似物:白松香加味剂 α-Galbanone 含硅衍生物的合成和嗅觉表征
摘要:硅化合物 1B-3B 分别是白松香气味剂 α-Galbanone (1A),α-Spirogalbanone (2A) 和 Nor-α-Galbanone (3A) 的 Sila 类似物.Sila-α-Galbanone (1B),Sila-α-Spirogalbanone (2B) 和 Sila-Nor-α-Galbanone (3B) 以异构纯形式在多步合成中合成,从 Me2Sicl2,(Ch2=ch)2Sicl2 开始,和 Me2(Ch2=ch)Sicl.乙烯基硅烷的加氢甲酰化,然后是闭环醛醇缩合或闭环烯烃复分解,是这些合成中的关键步骤.研究了 C/si 对 1A/1B,2A/2B 和 3A/3B 的嗅觉特性.所有化合物都具有菠萝方面的绿色水果白松香型气味,因此在嗅觉上是相关的.然而,发现 Sila 类似物 1B-3B 比相应的母体碳化合物 1A-3A 弱.这种效应对于 C/si 对
Doi:10.1002/ejic.201402597

专利信息

专利号:US-9233989-B2
优先权日:2011-10-11
标题:Sila analogs of oxazolidinone derivatives and synthesis thereof
发明人：REDDY DUMBALA SRINIVASA; BALAMKUNDU SEETHARAM SINGH; RAMESH REMYA
权利人:COUNCIL SCIENT IND RES
摘要:The invention discloses silaanalogs of oxazolidinone compounds, to pharmaceutical compositions and to the synthesis of the oxazolidinone derivatives of formula I. The invention further relates to methods of treating a subject suffering with gram positive pathogens including those resistant to methicillin and vancomycin using the compound(s) or modulation of coagulation properties of blood-clotting cascade or compositions of the oxazolidinone derivatives of the invention.

专利号:US-9085692-B1
优先权日:2014-02-25
标题 :Synthesis of oligomeric divinyldialkylsilane containing compositions
发明人：LASKOSKI MATTHEW; KELLER TEDDY M; SAAB ANDREW
权利人:LASKOSKI MATTHEW; KELLER TEDDY M; SAAB ANDREW; US GOVERNMENT
摘要:A method of: providing a solution of: a dichloroaromatic compound having an electron-withdrawing group bound to each aromatic ring containing one of the chloride groups; an excess of a dihydroxyaromatic compound; a base; and a solvent; heating the solution to a temperature at which the dichloroaromatic compound and the dihydroxyaromatic compound react to form an aromatic ether oligomer; and reacting the aromatic ether oligomer with a chlorodialkylvinylsilane to form one or more vinyl-terminated compounds having the formula below. The aromatic ether oligomer is a dihydroxy-terminated compound or a dimetallic salt thereof. Water formed during the heating is concurrently distilled from the solution. Each R is an alkyl group, Ar 1 is a residue from the dichloroaromatic compound, Ar 2 is a residue from the dihydroxyaromatic compound, and n is a non-negative integer.

专利号:CN-1384123-A
优先权日:2001-03-26
标 题 :Synthesis of polymer and film of the polymer

专利号:US-11767388-B1
优先权日:2019-09-18
标 题 :Silicon-functionalized rubber
发明人：ENSIGN SETH CODY; VIELHABER MARGARET FLOOK; JOHNGRASS JENA LYNN; MA LIQING
权利人:GOODYEAR TIRE & RUBBER
摘要:The compatibility between silica fillers and synthetic rubbers which are synthesized utilizing lanthanide-based catalyst systems, such as neodymium catalyst systems can be improved by terminating the polymerization with a vinyl silane terminating agent. In doing so the vinyl silane is allowed to react with the polymer chain ends of the neodymium rubber to functionalize the chain ends of the polymer chains with silicon containing groups. This results in the rubber having better characteristics for utilization in tire rubber formulations, such a tire tread formulations, that exhibit improved wear characteristics and lower rolling resistance. The process for the synthesis of such functionalized polydiene rubber comprises (1) polymerizing a diene monomer in the presence of a lanthanide-based catalyst system, and (2) terminating the polymerization with a vinyl silane terminator. The functionalized polydiene rubber composition made by this method is comprised of a polydiene rubber which is functionalized at its chain ends with a silicon containing group.

专利号:US-10424794-B2
优先权日:2014-07-02
标题:Ionic complex, electrolyte for nonaqueous electrolyte battery, nonaqueous electrolyte battery and ionic complex synthesis method
发明人：TAKAHASHI MIKIHIRO; MORINAKA TAKAYOSHI; SHINMEN MASUTAKA; YAMAMOTO KENTA; KAWABATA WATARU; KUBO MAKOTO; FUJIMOTO MASATAKA; MATSUZAKI HIROKI; TSUJIOKA SHOICHI
权利人:CENTRAL GLASS CO LTD
摘要:To provide a material suitable for a nonaqueous electrolyte battery having high-temperature durability. An ionic complex of the present invention is represented by any of the following formulae (1) to (3). For example, in the formula (1), A is a metal ion, a proton, or an onium ion; M is any of groups 13 to 15 elements. R 1 represents a C 1 to C 10 hydrocarbon group which may have a ring, a heteroatom, or a halogen atom, or —N(R 2 )—. R 2 at this time represents hydrogen atom, alkali metal atom, a C 1 to C 10 hydrocarbon group which may have a ring, a heteroatom, or a halogen atom. R 2 can also have a branched chain or a ring structure when the number of carbon atoms is 3 or more. Y is carbon atom or sulfur atom. a, o, n, p, q, and r are each predetermined integers.

专利号:US-6787601-B2
优先权日:2001-03-26
标题 :Polymer synthesis
发明人：LAMOLA ANGELO A; BLANKENSHIP ROBERT M
权利人:SHIPLEY CO LLC
摘要:Disclosed is a method of preparing emulsion polymers and a method of preparing porous dielectric materials using the emulsion polymers.