CAS: 37609-25-9; 5-Cyclohexadecen-1-One

该化合物是有机化合物,其特点是循环结构和不饱和.它有一个环己二乙烷环,由16个碳原子组成,五号位置为双环,五号位置为双环,第一位置为一氯酮功能组.该化合物一般没有色素,可粉黄液无色,呈现出一种特殊的气味.其分子结构有助于其再活性,特别是由于存在双重结合而产生的反应.Ketone组还使其易受核肺炎攻击,影响其化学行为.5-Cyclohexadecen-one在有机溶剂中溶解,这使其在有机合成中有用,并有可能形成香味或香味剂.此外,其独特结构可能会产生具体的生物活动,从而引起对医药化学和材料科学的兴趣.与许多有机化合物一样,在处理时应采取安全防范措施,因为它可能构成健康风险或环境危害.

结构式图片

相似化合物

1121-66-0 35720-58-2 542-46-1

欧盟法规

REACH注册ECHA物质C&L通报REACH预注册

合成工艺路线路线简述

    2-氯环十二酮 在 Sodium Tetrahydroborate,Mercury(II) Trifluoroacetate体系中,反应 0.3H,获得 (E)-5-Cyclohexadecen-1-One
    参考文献:易位辅助氧化三氟乙酸汞的化学计量和定量催化
    标题:易位辅助氧化三氟乙酸汞的化学计量和定量催化
    摘要:在室温下,将1,5-己二烯-3-醇叔化成35-90%的δ-乙烯酮,在两种条件下收率:用一摩尔当量的三氟乙酸汞处理,然后使中间的α-水银脱汞酮与硼氢化钠;用0.2摩尔当量的三氟乙酸锂或三氟甲磺酸锂处理.反应是高度立体选择性的,酮的e异构体占产物的80-95%.在第二条件下观察到最高的选择性.
    Doi:10.1016/0040-4020(84)85011-5

    海关参考信息

    专利信息


    专利号:US-2025091984-A1
    优先权日:2022-04-07
    标题:Fragrance and flavor materials
    发明人:DICKERSON THALIA S; TURESKI ROBERT; BLANDINO MAUREEN
    权利人:TAKASAGO PERFUMERY CO LTD
    摘要:The present disclosure is directed to the synthesis and application of novel compounds having unique and desired flavor and/or fragrance characteristics. The compounds of the present disclosure can be employed alone or incorporated as fragrance or flavor compounds in fragrance or flavor compositions. The present disclosure is also directed to consumer products comprising such fragrance or flavor compounds and/or fragrance or flavor compositions.

    专利号:US-12114681-B2
    优先权日:2018-06-04
    标题:Fragrance and flavor materials
    发明人:BLANDINO MAUREEN; TANUMA KENJI
    权利人:TAKASAGO PERFUMERY CO LTD
    摘要:The synthesis and application of compounds having unique and desired flavor and/or fragrance characteristics are provided herein. The compounds herein can be employed alone or incorporated as fragrance or flavor ingredients in fragrance or flavor compositions. The application is also directed to consumer products comprising such derivatives and/or fragrance or flavor compositions.

    专利号:US-2021198229-A1
    优先权日:2018-03-08
    标 题 :Fragrance and flavor materials from 1-(2-hydroxy-4-methylcyclohexyl)-ethanone
    发明人:DICKERSON THALIA S; LOMBARDO LOUIS J; LANKIN MICHAEL E
    权利人:TAKASAGO PERFUMERY CO LTD
    摘要:The present disclosure is directed to 1-(2-hydroxy-4-methycyclohexyl)-ethanone derivatives having unique and desired flavor and/or fragrance characteristics, as well as the synthesis and application of the derivatives. The compounds of the present disclosure can be employed alone or incorporated as fragrance or flavor ingredients to modify or enhance already existing fragrance compositions, solvents, media, and the like.

    专利号:US-2020407301-A1
    优先权日:2018-03-08
    标 题:Fragrance and flavor materials derived from 1-(4-methylcyclohex-1-en-1-yl)ethan-1-one
    发明人:BLANDINO MAUREEN; LANKIN MICHAEL E; LOMBARDO LOUIS J
    权利人:TAKASAGO PERFUMERY CO LTD
    摘要:The present disclosure is directed to 1-(4-methyl cyclohex-1-en-1-yl)ethan-1-one derivatives having unique and desired flavor and/or fragrance characteristics, as well as the synthesis and application of the derivatives. The compounds of the present disclosure can be employed alone or incorporated as fragrance or flavor ingredients to modify or enhance already existing fragrance compositions, solvents, media, and the like.

    专利号:US-11236288-B2
    优先权日:2018-06-04
    标题:Fragrance materials
    发明人:BLANDINO MAUREEN; LANKIN MICHAEL E
    权利人:TAKASAGO PERFUMERY CO LTD
    摘要:The synthesis and application of a compound having unique and desired fragrance characteristics is provided herein. The compound of the present disclosure can be employed alone or incorporated as a fragrance component in fragrance compositions. The application is also directed to consumer products comprising such compound and/or fragrance compositions.

    专利号:US-6759557-B2
    优先权日:2001-06-08
    标题 :Melanin production inhibitors and skincare products containing such inhibitors
    发明人:MATSUDA HIROYUKI; KUMAMOTO HIROYASU; TAMAI EIKO; YAGI MISAO; YAMAMOTO KENICHI; HAGIWARA TOSHIMITSU; WATANABE SHINYA
    权利人:TAKASAGO PERFUMERY CO LTD
    摘要:A melanin synthesis inhibitor composition containing at least one macrocyclic compound represented by Formula (1) n wherein X is a group selected among the groups consisting of Câ•?O; CH—OH and Oâ•?C—CHOH; R being a chain hydrocarbon having 13 to 24 carbon atoms, R forms a ring with X and may be saturated or contain 1 to 3 unsaturated bonds and may be substituted by a lower alkyl group of 1 to 3 carbon atoms.
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    合成参考文献


    摘要:Scott, P. J. H., Science of Synthesis Knowledge Updates, (2013) 4, 290.
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