CAS: 405-99-2; 1-Fluoro-4-Vinylbenzene

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CAS号2065-66-9 甲基三苯基碘化 | CAS号459-57-4 对氟苯甲醛 | CAS号18511-62-1 (±)-4-氟苯乙烯环氧化物 | CAS号54509-73-8 ethene | CAS号352-34-1 4-氟碘苯 | CAS号766-98-3 4-氟苯乙炔 | CAS号3020-28-8 碘甲基-三苯基-碘化磷 | CAS号1779-49-3 甲基三苯基溴化膦 | CAS号332-42-3 1-氟-4-(2-溴乙基)苯 | CAS号403-29-2 2-溴-4'-氟苯乙酮 | CAS号403-41-8 1-(4-氟苯基)乙醇 | CAS号7589-27-7 对氟苯乙醇 | CAS号51787-96-3 5-(4-氟苯基)-4,5-二... | CAS号403-40-7 4-氟-α-甲基苄胺 | CAS号1583-88-6 4-氟苯乙胺 | CAS号459-47-2 1-乙基-4-氟苯 | CAS号459-57-4 对氟苯甲醛 | CAS号50-00-0 甲醛 | CAS号403-42-9 对氟苯乙酮

4-氟溴乙基苯置于氢氧化钾体系中,化学反应生成 4-氟苯乙烯
参考文献:含有核氯和氟的加压胺.
标题:含有核氯和氟的加压胺.
摘要:
DOI:10.1021/ja01209A038

专利信息

专利号:WO-2022155981-A1
优先权日:2021-01-25
标题 :USE OF N-HETEROCYCLIC CARBENE-BASED COMPOUNDED NICKEL (II) COMPLEX IN SYNTHESIS OF α-BENZYL BENZOFURAN COMPOUND
发明人：SUN HONGMEI; SHUI YU; JIN WENHUI
权利人:UNIV SOOCHOW
摘要:Disclosed is the use of an N-heterocyclic carbene-based compounded nickel (II) complex in the synthesis of an α-benzyl benzofuran compound. In the present invention, an air-stable compounded nickel (II) complex Ni[P(OEt) 3 ]{[R`NC(CH 3 )C(CH 3 )NR`]C}Br 2 is used as a catalyst, wherein R` is 2,4,6-trimethylphenyl, and the α-benzyl benzofuran compound is synthesized by means of a hydrogen heteroarylation reaction of an aryl ethylene compound and a benzofuran compound in the presence of an organic base. The operability and substrate applicability of the catalyst are obviously better than those of the prior art, and meanwhile, the nickel catalyst has a higher practical application value due to the air stability and easiness of synthesis thereof.

专利号:US-10487099-B2
优先权日:2017-06-30
标 题:Synthesis of hypervalent iodine reagents with dioxygen
发明人：POWERS DAVID CHARLES; MAITY ASIM; HYUN SUNG-MIN
权利人:TEXAS A & M UNIV SYS
摘要:Methods of synthesis of hypervalent iodine reagents and methods for oxidation of organic compounds are disclosed.

专利号:US-9834570-B2
优先权日:2013-06-03
标 题 :One step process for regioselective synthesis of α-acyloxy carbonyls
发明人：SUDALAI ARUMUGAM; REDDI RAMBABU; MALEKAR PUSHPA
权利人:COUNCIL SCIENT IND RES
摘要:A regioselective N-Heterocyclic Carbene (NHC) catalyzed one step process for high yield synthesis of α-acyloxy carbonyl compounds is disclosed.

专利号:US-6710208-B2
优先权日:1996-12-19
标题 :Process for the solid phase synthesis of aldehyde, ketone, oxime, amine, hydroxamic acid and α,β-unsaturated carboxylic acid and aldehyde compounds
发明人：SALVINO JOSEPH M; MORTON GEORGE C; MASON HELEN J; LABAUDINIERE RICHARD F
权利人:AVENTIS PHARMA INC
摘要:This invention is directed to a process for the solid phase synthesis of aldehyde, ketone, oxime, amine, hydroxamic acid and α,β-unsaturated carboxylic acid and aldehyde compounds and to polymeric hydroxylamine resin compounds useful therefor.

专利号:US-2004132610-A1
优先权日:2003-01-03
标题:Transition metal complexes in the controlled synthesis of polyolefins substituted with functional groups
发明人：TAGGE CHRISTOPHER D; WILSON ROBERT B
摘要:A method is provided for the polymerization of olefins substituted with a functional group using a transition metal catalyst that, by virtue of one or more stabilizing groups incorporated within the catalyst structure, “fixesâ€? the stereoconfiguration of each olefinic monomer relative to the transition metal complex during each successive reaction in the polymerization process. The invention substantially reduces the likelihood of olefin rearrangement at the active site of the catalyst during polymerization. In one particular embodiment, the functional group is a polar, electron-donating group and the stabilizing group is a Lewis acid substituent; examples of polymers that can be prepared with such a system include poly(vinyl acetate), poly(vinyl alcohol), and poly(vinyl ethers). Novel complexes and catalyst systems useful in the polymerization method are also provided.

专利号:US-9949970-B2
优先权日:2010-09-14
标题 :Synthesis of new benzothiazole derivatives as potential anti-tubercular agents
发明人：KAMAL AHMED; SHETTI RAJESH VCRNC; SWAPNA PONNAMPALLI; AZEEZA SHAIK; REDDY A MALLA; KHAN INSHAD ALI; ABDULLAH SHEIKH TASDUQ; SHARMA SANDEEP; KALIA NITIN PAL
权利人:COUNCIL SCIENT IND RES
摘要:Disclosed are compounds of general formula A useful as potential anti-tubercular agents. The general formula A is