CAS: 1711-07-5; 3-Fluorobenzoylchloride

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间氟苯甲酸置于n,N-二甲基甲酰胺,草酰氯体系中,用 二氯甲烷 用作溶剂,化学反应 12.08H,以100%的收率获得间氟苯甲酰氯
参考文献:用于定向 C(Sp2)-h 和 C(Sp3)-h 硼酸化不同类型底物的显着高效铱催化剂
标题:用于定向 C(Sp2)-h 和 C(Sp3)-h 硼酸化不同类型底物的显着高效铱催化剂
摘要:在这里,我们描述了一类新的 C-H 硼化催化剂的发现及其在芳族,杂芳族和脂肪族系统的区域选择性 C-H 硼化中的应用.新催化剂具有 Ir-C(噻吩基) 或 Ir-C(呋喃基) 阴离子配体,而不是标准 C-H 硼化条件中使用的二胺型中性螯合配体.据报道,这些新发现的催化剂的使用对不同种类的芳烃底物显示出优异的反应性和邻位选择性,并具有高分离产率.此外,该催化剂被证明对大量脂肪族底物的选择性 C(Sp 3)-h 键硼化.杂环分子利用 C-H 键固有的高反应性选择性地硼化.已经使用相同的催化剂描述了许多后期 C-H 功能化.此外,我们表明其中一种催化剂甚至可以在露天用于 C(Sp 2 )-H 和 C(Sp 3 )-H 硼酸化,从而使该方法更加通用.初期机理研究表明,活性催化中间体是 Ir(Bis)Boryl 络合物,连接的配体作为双齿配体.总的来说,这项研究强调了新型 C-H 硼酸化催化剂的发现,这些催化剂应该在
Doi:10.1021/jacs.0C13415

专利信息

专利号:US-11981648-B2
优先权日:2019-06-13
标题:Method for the synthesis of 3-R-1,4,2-dioxazol-5-ones
发明人：HALL DAVID S; DAHN JEFFERY RAYMOND; HYNES TOREN
权利人:TESLA INC; PANASONIC HOLDINGS CORP
摘要:Provided are methods of preparing 3-R-1,4,2-dioxazol-5-one compounds using convenient and efficient methods. Also provided are 3-R-1,4,2-dioxazol-5-one compounds produced using the methods described.

专利号:WO-2024126692-A1
优先权日:2022-12-15
标题 :Peracid promoters in the iridium-catalyzed hydrosilylation synthesis of haloalkylorganosilanes
发明人：SCHOLZ HENRIK; KROKE EDWIN; KRAUSHAAR KONSTANTIN; GLATZER HOLGER JÃœRGEN; LEWIS KENRICK MARTIN; WAGNER ROLAND
权利人:MOMENTIVE PERFORMANCE MAT GMBH
摘要:The present invention is directed at a process for producing a compound of Formula (I): (R1)y(R2O)3-ySiCH2CHR3CR4R5X comprising reacting (a) an olefinic halide; (b) an alkoxysilane; (c) a catalytically effective amount of iridium-containing catalyst; and (d) a reaction-promoting effective amount of a peroxycarboxylic acid to produce the product of Formula (I).

专利号:US-2024287008-A1
优先权日:2019-06-13
标题 :Method for the synthesis of 3-r-1,4,2-dioxazol-5-ones

专利号:EP-4634196-A1
优先权日:2022-12-15
标题 :Peracid promoters in the iridium-catalyzed hydrosilylation synthesis of haloalkylorganosilanes

专利号:US-2023029852-A1
优先权日:2019-06-13
标 题:Method for the synthesis of 3-r-1,4,2-dioxazol-5-ones

专利号:US-8524740-B2
优先权日:2010-07-15
标 题 :Synthesis and anticancer activity of aryl and heteroaryl-quinolin derivatives
发明人：KUO SHENG-CHU; LEE KUO-HSIUNG; HUANG LI-JIAU; CHOU LI-CHEN; WU TIAN-SHUNG; WAY TZONG-DER; CHUNG JING-GUNG; YANG JAI-SING; HUANG CHI-HUNG; TSAI MENG-TUNG
权利人:KUO SHENG-CHU; LEE KUO-HSIUNG; HUANG LI-JIAU; CHOU LI-CHEN; WU TIAN-SHUNG; WAY TZONG-DER; CHUNG JING-GUNG; YANG JAI-SING; HUANG CHI-HUNG; TSAI MENG-TUNG; TAIRX INC
摘要:A compound of Formula I is disclosed as follows: n n n n n n n n n n n n or a pharmaceutically acceptable salt, prodrug, solvate, or metabolite thereof, wherein n R is hydrogen, P(â•?O)(OH) 2 , P(â•?O)(O(C 1 -C 18 )alkylene(C 6 -C 20 )aryl) 2 , P(â•?O)(OH)(OM), P(â•?O)(OM) 2 , Pâ•?O(O 2 M), S(â•?O)(OH) 2 , S(â•?O)(O(C 1 -C 18 )alkylene(C 6 -C 20 )aryl) 2 , S(â•?O)(OH)(OM), S(â•?O)(OM) 2 ; n M is a monovalent or divalent metal ion, or alkylammonium ion; n W is (C 6 -C 20 )aryl, (C 6 -C 20 )heteroaryl, (C 1 -C 18 )alkyl(C 6 -C 20 )aryl, (C 1 -C 18 )alkyl(C 6 -C 20 )heteroaryl, hydroxy(C 6 -C 20 )aryl, hydroxy(C 6 -C 20 )heteroaryl, (C 1 -C 18 )alkoxy(C 6 -C 20 )aryl, (C 1 -C 18 )alkoxy(C 6 -C 20 )heteroaryl, (C 1 -C 18 )alkylenedioxy(C 6 -C 20 )aryl, (C 1 -C 18 )alkylenedioxy(C 6 -C 20 )heteroaryl, halo(C 6 -C 20 )aryl, halo(C 6 -C 20 )heteroaryl, (C 1 -C 18 )alkylamino(C 6 -C 20 )aryl, (C 1 -C 18 )alkylamino(C 6 -C 20 )heteroaryl, (C 1 -C 18 )cycloalkylamino(C 6 -C 20 )aryl, or (C 1 -C 18 )cycloalkylamino(C 6 -C 20 )heteroaryl, and their OR 8 substutes; n R 5 is (C 1 -C 18 alkoxy, hydrogen, hydroxyl, O—(C 1 -C 18 )alkyl(C 6 -C 20 )aryl, halo or OR 8 , or R 5 and R 6 are (C 1 -C 18 )dioxy provided that R 7 is hydrogen; n R 6 is hydroxyl, O—(C 1 -C 18 )alkyl(C 6 -C 20 )aryl, halo or OR 8 , (C 1 -C 18 )alkoxy, (C 1 -C 18 )alkylamino, or (C 1 -C 18 )cycloalkylamino, or R 6 and R 7 are (C 1 -C 18 )dioxy provided that R 5 is hydrogen; n R 7 is hydrogen, halo or OR 8 , hydroxyl, or O—(C 1 -C 18 )alkyl(C 6 -C 20 )aryl; and n R 8 is P(â•?O)(OH) 2 , P(â•?O)(O(C 1 -C 18 )alkyl(C 6 -C 20 )aryl) 2 , Pâ•?O)(OH)(OM), or P(â•?O)(OM) 2 , Pâ•?O(O 2 M).