CAS: 696-62-8; 4-Iodoanisole

上下游产品

CAS号5720-07-0 4-甲氧基苯硼酸 | CAS号104-94-9 对甲氧基苯胺 | CAS号100-66-3 苯甲醚 | CAS号623-12-1 4-氯苯甲醚 | CAS号104-92-7 对溴苯甲醚 | CAS号540-38-5 4-碘苯酚 | CAS号4637-24-5 N,N-二甲基甲酰胺二甲基缩醛 | CAS号36651-93-1 (4-methoxypheny... | CAS号103056-99-1 (4-METHOXYPHENY... | CAS号111887-18-4 4-(4-methoxyphe... | CAS号106052-22-6 1-di(propan-2-y... | CAS号107770-12-7 3-(4-methoxyphe... | CAS号123074-43-1 3,3-bis(4-metho... | CAS号105903-05-7 3-(4-methoxyphe... | CAS号108478-59-7 4-甲氧基-2-甲基-[1,1... | CAS号109125-09-9 1-hept-1-en-2-y... | CAS号108062-25-5 3-(4-methoxyphe...

Triethyl(4-Methoxyphenyl)Germane置于n-碘代丁二酰亚胺体系中,用 N,N-二甲基甲酰胺 作为反应溶剂,化学反应 4.0H,以84%的收率获得产物4-碘苯甲醚
参考文献:Aryl Germanes 的正交稳定性和反应性可实现快速和选择性(多)卤化.
标题:Aryl Germanes 的正交稳定性和反应性可实现快速和选择性(多)卤化.
摘要:虽然卤化在合成和放射成像中至关重要,但目前可用的曲目主要是为了在每个分子中引入一个卤素.该报告使选择性引入几种不同的卤素变得容易.这里展示了无毒的芳基锗烷在苛刻的氟化条件下(允许选择性氟化)在苛刻的氟化条件下的优越稳定性,同时在亲电碘化和溴化中表现出优异的反应性和官能团耐受性,在快速和无添加剂的情况下胜过硅烷或硼酸酯条件.机械实验和计算研究表明协同的亲电子芳香取代是潜在的机制.
DOI:10.1002/anie.202008372

专利信息

专利号:US-2008086013-A1
优先权日:2006-06-15
标 题:Carbometallation of alkynes and improved synthesis of uniquinones
发明人：LIPSHUTZ BRUCE H
权利人:UNIV CALIFORNIA
摘要:Methods for the carbometallation of alkynes are presented. Those are useful for the synthesis of CoQ 10 and other ubiquinones as well as for the synthesis of ubiquinol analogs.

专利号:US-10889599-B2
优先权日:2018-02-27
标 题:1,1-diborylalkyl-1-metal compounds, preparation method thereof, and their applications toward synthesis of 1,1-diboronate ester compounds
发明人：CHO SEUNG HWAN; LEE YEOSAN
权利人:POSTECH ACAD IND FOUND
摘要:The present invention relates to a 1,1-diborylalkyl-1-metal compound including one metal group together with two identical boron groups at the sp3 carbon center, and its use. Specifically, the present invention relates to development of novel organic reactions, synthesis of functional molecules, and synthesis of new drugs by applying the novel 1,1-diboryl-1-metal substituted alkyl compounds to various molecular libraries which could not be synthesized by conventional methodologies.

专利号:US-2006167025-A1
优先权日:2004-12-22
标 题:Tricyclic amino alcohols, processes for synthesis of same and use of same as anti-inflammatory drugs
发明人：BERGER MARKUS; SCHMEES NORBERT; SCHAECKE HEIKE; BAURLE STEFAN; REHWINKEL HARTMUT; MENGEL ANNE; KROLIKIEWICZ KONRAD; GROSSBACH DANJA; VOIGTLAENDER DAVID
权利人:BERGER MARKUS; SCHMEES NORBERT; SCHAECKE HEIKE; BAURLE STEFAN; REHWINKEL HARTMUT; MENGEL ANNE; KROLIKIEWICZ KONRAD; GROSSBACH DANJA; VOIGTLAENDER DAVID
摘要:The invention relates to tricyclic amino alcohols of general formula (I) n nmethod for synthesis of same and use of same as anti-inflammatory agents.

专利号:US-10173993-B2
优先权日:2015-12-09
标题 :Process for the synthesis of sulfones and sulfonamides
发明人：VON WOLFF NIKLAS; CHAR JOËLLE; CANTAT THIBAULT
权利人:COMMISSARIAT ENERGIE ATOMIQUE
摘要:A one pot single step process is described for the synthesis of a compound, including a labeled compound, containing a sulfonyl functional group comprising the step of mixing together a silane, an SO 2 source, an electrophilic compound, an activating compound and optionally a metal catalyst. A process for producing tracers from a labeled sulfonyl containing compound prepared by the described process is also included.

专利号:US-10487099-B2
优先权日:2017-06-30
标 题:Synthesis of hypervalent iodine reagents with dioxygen
发明人：POWERS DAVID CHARLES; MAITY ASIM; HYUN SUNG-MIN
权利人:TEXAS A & M UNIV SYS
摘要:Methods of synthesis of hypervalent iodine reagents and methods for oxidation of organic compounds are disclosed.

专利号:US-6780810-B2
优先权日:2002-03-13
标题:Multifunctional catalyst useful in the synthesis of chiral vicinal diols and process for the preparation thereof, and process for the preparation of chiral vicinal diols using said multifunctional catalysts
发明人：CHOUDARY BOYAPATI MANORANJAN; CHOWDARI NAIDU SREENIVASA; MADHI SATEESH; KANTAM MANNEPALLI LAKSHMI
权利人:COUNCIL SCIENT IND RES
摘要:The present invention relates to a multifunctional reusable catalyst and to a process for the preparation thereof on a single matrix of the support to perform multicomponent reaction in a single pot. The multifunctional catalysts of the invention are useful for the synthesis of chiral vicinal diols by tandem and/or simultaneous reactions involving Heck coupling, N-oxidation and AD reaction of olefins in presence of cinchona alkaloid compounds both as an native one and immobilized one in the said matrix support. This invention also relates to a process for preparing vicinal diols by asymmetric dihydroxylation of olefins in presence of cinchona alkaloid compounds employing reusable multifunctional catalysts as heterogeneous catalysts in place of soluble osmium catalysts.