CAS: 814-94-8; Tin(Ii) Oxalate

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专利信息

专利号:WO-2020253244-A1
优先权日:2019-06-20
标 题 :Process for catalytic synthesis of lactide
发明人：JIANG WEI; ZHANG YANKAI; SUN PING; LI AIMIN; ZHANG QUANXING
权利人:NANJING UNIVERSITY OF TECHNOLOGY; NANJING QUANKAI RES INSTITUTE OF BIOMATERIALS CO LTD
摘要:The present invention provides a process for the catalytic synthesis of lactide, comprising: mixing a lactic acid oligomer with a composite catalyst; and synthesizing lactide under a heating condition, and collecting the product using a vacuum distillation mode. The used composite catalyst is composed of a zinc or tin compound and an alkali metal compound. Compared with the prior art, the advantages of the present invention are that: the used composite catalyst features a high production rate with a small use amount, a low reaction temperature (150-220°C), and a short reaction time (2-5 h), has a single pass yield that may reach 95% or more, reduces energy consumption compared with the prior art, and facilitates industrial implementations.

专利号:US-2005187374-A1
优先权日:2004-02-20
标 题:Polyester synthesis with enhanced titanium catalyst composition
发明人：CHEN BIN; DOWLING CONOR M; SESHADRI SRI R
摘要:A catalyst composition for preparing polyesters comprises a titanium compound and one or more catalyst enhancers. The titanium compound may be either a titanyl compound of the formula X m TiOY o or a titanium salt of the formula X m TiY o , where each X is independently selected from the group consisting of H, Li, Na, K, Rb, Cs, Be, Mg, Ca, Sr, Ba and ammonium; m=0, 1 or 2; Y is a ligand of the formula C a H b O c , wherein a=1 to 30, b=0 to 60, and c=1 to 10; and o=2, 3, or 4. The catalyst enhancer may be selected from either or both of two classes: 1) compounds selected from the group consisting of oxalate and C1-C26 carboxylate salts of Li, Na, K, Rb, Cs, Be, Ca, Mg, Sr, and Ba; and 2) compounds selected from the group consisting of soluble compounds of Al, Co, Zn, and Sn.

专利号:US-2001051110-A1
优先权日:1998-06-09
标题 :Apparatus for in-situ preparation and analysis of mixed metal oxide catalysts
发明人：BORADE RAMESH; POOJARY DAMODARA; ZHOU XIAO PING
摘要:The present invention discloses an apparatus and method for rapid synthesis and analysis of members of a combinatorial library. The apparatus includes a plurality of vessels for containing individual library members and a fluid handling system that apportions a test fluid about equally between each of the vessels. This allows for simultaneous screening of library members by detecting changes in test fluid following contact with individual library members. Fluid flow through each of the vessels is controlled using passive flow restrictors or active flow controllers to ensure that each library member contacts approximately the same amount of test fluid per unit time. The disclosed apparatus and method is especially useful for making inorganic oxide mixtures and for screening the mixtures based on their ability to catalyze the conversion of fluid reactants.

专利号:CN-107961783-B
优先权日:2017-11-22
标题:Catalysts for the synthesis of light olefins

专利号:US-9000234-B2
优先权日:2011-12-22
标题:Calcination of modified support to prepare hydrogenation catalysts
发明人：WEINER HEIKO; ZHOU ZHENHUA; JOHNSTON VICTOR J
权利人:WEINER HEIKO; ZHOU ZHENHUA; JOHNSTON VICTOR J; CELANESE INT CORP
摘要:The present invention relates to a catalyst having an amorphous support and one or more active metals. The amorphous support may comprise a support material and an amorphous support modifier, which adjusts the acidity of the support material. In preparing the amorphous catalyst, post-synthesis treatment, i.e. calcination, may be used to adjust the catalyst performance while converting acetic acid to ethanol.

专利号:US-10654781-B2
优先权日:2015-11-12
标 题:Method of catalytic conversion of carbohydrates to low-carbon diols by using alloy catalysts
发明人：SUN RUIYAN; ZHENG MINGYUAN; ZHANG TAO; PANG JIFENG; JIANG YU; WANG AIQIN; WANG XIAODONG
权利人:DALIAN INST CHEM & PHYSICS CAS
摘要:This invention provides a method for catalytic conversion of carbohydrates to low-carbon diols using alloy catalysts. In the process, carbohydrates as the feedstock are subjected to one-step catalytic conversion to realize the highly efficient and selective production of ethylene glycol etc. under hydrothermal conditions, with an alloy catalyst composed of tin, and a transition metal such as iron, cobalt, nickel, rhodium, ruthenium, palladium, iridium, platinum and copper, or a mixture thereof. The reaction is carried out in water at a temperature range of 120-300° C., with a hydrogen pressure range of 1-13 MPa. Compared with the present petroleum based synthesis technology of ethylene glycol, the method in this invention possesses advantages of using renewable feedstock, high atom economy and environmental friendly. Besides, compared with other technologies using biomass as feedstock to produce ethylene glycol, the alloy catalyst in this invention possesses the advantages of few leaching amount, good hydrothermal stability and easy to recycle.