CAS: 884336-44-1; 2-(9,9'-Spirobi[fluoren]-2-yl)-4,4,5,5-Tetramethyl-1,3,2-Dioxaborolane

该化合物是一种有机有机体化合物,其特点是其独特的螺旋结构,由附于螺旋-二氟乙烯框架的碳酸碱组成,该化合物通常具有与和芳香系统有关的特性,包括有机电子学的潜在应用,如开发有机发光二极管和有机光伏(OPVs)等; 丁酸功能的存在允许多功能性再活动,特别是在铃木的组合反应中,使其在合成有机化学中具有价值.此外,酸酯组加强了其在有机溶剂中的稳定性和溶性.该化合物的分子结构有助于其电子特性,可针对材料科学中的具体应用进行调整.

英文名称2-(9,9'-Spirobi[fluoren]-2-yl)-4,4,5,5-Tetramethyl-1,3,2-Dioxaborolane
中文名称9,9'-螺双[9H-芴]-2-基硼酸频哪醇酯
IUPAC名称2-(9,9'-spirobi[fluoren]-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
其它别名(9,9'-Spirobi[fluoren]-7-yl)Boronic Acid Pinacol Ester; 7-(4,4,5,5-Tetramethyl-1,3,2-Dioxaborolan-2-yl)-9,9'-Spirobi[fluorene]
CAS编号884336-44-1
MFCD编号:MFCD29472553
分子式:C31H27BO2
分子量:442.37
产品CID: 1894884
产品分类医药中间体 → 有机发光二极管材料中间体

相似结构搜索
InChIKey: VZMLUIPYIYNRGP-UHFFFAOYSA-N
InChI=1S/C31H27BO2/c1-29(2)30(3,4)34-32(33-29)20-17-18-24-23-13-7-10-16-27(23)31(28(24)19-20)25-14-8-5-11-21(25)22-12-6-9-15-26(22)31/h5-19H…
计算化学: 氢键受体数2.0氢键供体数0.0可旋转键数1.0

MSDS等安全信息

GHS符号GHS07
警示词Warning
危险描述H315-H319-H335
防范说明P261-P305+P351+P338

合成工艺路线路线简述

171408-76-7 + 61676-62-8 = 884336-44-1
反应条件:1.1 Reagents: Butyllithium Solvents: Tetrahydrofuran,Hexane; 30 Min,-78 °C1.2 -78 °C -> Rt; 2 H,Rt1.3 Reagents: Water; Rt
标题:Synthesis And Electrophosphorescent Properties Of Iridium Complexes Based On 2-Fluorenylquinoline Derivatives
作者:Lee,Kum Hee; Et Al
参考文献:Thin Solid Films 日期:2010 卷标:518(14) 页码:3972-3977]

236389-20-1 = 884336-44-1
反应条件:1.1 Solvents: Acetic Acid; 0 - 5 °C1.2 Reagents: Hydrochloric Acid Solvents: Water2.1 Solvents: Tetrahydrofuran; Rt -> -78 °C2.2 Reagents: Butyllithium; 30 Min,-78 °C2.3 -78 °C
标题:Synthesis And Electroluminescence Properties Of Novel Deep Blue Emitting 6,12-Dihydro-Diindeno[1,2-B;1',2'-E]Pyrazine Derivatives
作者:Park,Young-Il; Et Al
参考文献:Chemical Communications (Cambridge 日期:2008 卷标:(18) 页码:2143-2145]

171408-76-7 + 73183-34-3 = 884336-44-1
反应条件:1.1 Reagents: Potassium Acetate Catalysts: Palladium Diacetate Solvents: Dimethylformamide; 6 H,80 °C
标题:Syntheses And Characterizations Of High Refractive Index And Low Birefringence Polyimides Containing Spirobifluorene In The Side Chain
作者:Wen,Pushan; Et Al
参考文献:Polymer 日期:2017 卷标:117 页码:76-83]

171408-76-7 + 61676-62-8 = 884336-44-1
反应条件:1.1 Reagents: Butyllithium Solvents: Tetrahydrofuran,Hexane; -78 °C; 1 H,-78 °C1.2 -78 °C; -78 °C -> Rt; Overnight,Rt
标题:The Dibenzothiophene-S,S-Dioxide And Spirobifluorene Based Small Molecules Promote Low Roll-Off And Blue Organic Light-Emitting Diodes
作者:Hu,Liwen; Et Al
参考文献:Journal Of Photochemistry And Photobiology 日期:2019 卷标:382]

1133-80-8 = 884336-44-1
反应条件:1.1 Reagents: Tetrabutylammonium Hydroxide Solvents: Methanol,Pyridine2.1 Solvents: Tetrahydrofuran; Rt -> -78 °C2.2 Reagents: Tert-Butyllithium; 1 H,-78 °C2.3 Solvents: Tetrahydrofuran3.1 Solvents: Acetic Acid; 0 - 5 °C3.2 Reagents: Hydrochloric Acid Solvents: Water4.1 Solvents: Tetrahydrofuran; Rt -> -78 °C4.2 Reagents: Butyllithium; 30 Min,-78 °C4.3 -78 °C
标题:Synthesis And Electroluminescence Properties Of Novel Deep Blue Emitting 6,12-Dihydro-Diindeno[1,2-B;1',2'-E]Pyrazine Derivatives
作者:Park,Young-Il; Et Al
参考文献:Chemical Communications (Cambridge 日期:2008 卷标:(18) 页码:2143-2145