[3-(Benzyloxy)-1,1-Dimethylpropoxy]Diphenyl-{[(E)-3-Phenyl-2-Propenyl]Oxy}Silane置于四丁基氟化铵体系中,用 四氢呋喃 作为反应溶剂,化学反应生成 二苯基二氟硅烷
参考文献:Synthesis And Applications Of Tert-Alkoxysiloxane Linkers In Solid-Phase Chemistry
标题:Synthesis And Applications Of Tert-Alkoxysiloxane Linkers In Solid-Phase Chemistry
摘要:Straightforward Syntheses Of Two Tert-Alkoxysilyl Chloride Functionalised Resins 3 And 31 That Allow Facile Attachment Of 1 Degrees,2 Degrees,3 Degrees Alcohols And Phenols To The Solid-Phase Have Been Achieved. Resin 3 Displayed Useful Loading Levels (0.7 Mmol/g),And It Was Stable To Storage In Activated Form. Siloxanes From Reaction Of 3 With Alcohols And Phenols Were Compatible With A Variety Of Reaction Conditions Commonly Used In Solid-Phase Synthesis. (C) 2006 Published By Elsevier Ltd.
DOI:10.1016/j.Tet.2006.10.052