CAS: 32992-96-4; Bis(Ethylcyclopentadienyl)Ruthenium(Ii)

该化合物是一个协调化合物,其特点是为中金属原子,该化合物的特点是独特的结构,包括一个乙基替代品环球环球离心,与环球中心协调;多个五氟基化合物的存在表明,该化合物具有复杂的离子环境,能够影响其再活性和稳定性;露天复合物的催化特性众所周知,特别是在有机合成和氢化反应中.在周围的的具体安排可以影响电子特性和阻力,使该化合物在各种化学应用中可能有用.此外,该化合物可能具有有趣的物理特性,例如有机溶剂中的溶性以及不同的光谱特性,这些特性可以使用NMR和IR光谱学等技术加以研究.

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chloro(ethylcyclopentadienyl)bis(triphenylphosphine)ruthenium(II) 1,1'-diethylferr°Cene ruthenium(III)chloride ruthenium trichlorideruthenium

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    专利信息


    专利号:US-7012150-B2
    优先权日:2002-08-05
    标题:Method of manufacturing bis(cyclopentadienly)ruthenium and bis(cyclopentadienyl)ruthenium manufactured by the same
    发明人:SAGAE TAKEYUKI
    权利人:TANAKA PRECIOUS METAL IND
    摘要:The present invention provides a method of manufacturing a bis(cyclopentadienyl)ruthenium, comprising the step of synthesizing a bis(cyclopentadienyl)ruthenium by causing cyclopentadiene, ruthenium chloride and zinc powder to react in an alcohol solvent, wherein the synthesis of the bis(cyclopentadienyl)ruthenium comprises the step of mixing the cyclopentadiene and zinc powder in the alcohol solvent and thereafter adding ruthenium chloride portionwise while holding the temperature of the reaction system at from −70° C. to 20° C. A highly pure product can be obtained through purification of subliming bis(cyclopentadienyl)ruthenium having been synthesized in the synthesis step in an atmosphere under reduced pressure.

    专利号:US-6521772-B1
    优先权日:2001-09-27
    标 题 :Synthesis of substituted ruthenocene complexes
    发明人:LIENHARD MICHAEL ALEXANDER; HOOVER CYNTHIA A; ATWOOD JIM D; HOTH DAVID C
    权利人:PRAXAIR TECHNOLOGY INC; RES FOUNDATION SUNY
    摘要:This invention is directed to a method for producing an alkyl-substituted metallocene complex comprising the steps of mixing a metallocene with a solvent to form a metallocene-solvent mixture; mixing the metallocene-solvent mixture with an effective amount of a metallation reagent to produce a metallated-metallocene; and mixing said metallated-metallocene with an electrophilic alkyl-reagent to form an alkyl-substituted metallocene complex.

    专利号:US-10384201-B2
    优先权日:2016-02-17
    标题:Direct synthesis method of nanostructured catalyst particles on various supports and catalyst structure produced by the same
    发明人:JEONG NAMJO; KIM CHAN-SOO; JWA EUN-JIN; CHOI JI YEON; NAM JOO-YOUN; PARK SOON-CHUL; JANG MOON-SEOK; SEO YONG SEOK; HWANG KYO SIK; KIM HAN KI; HAN JI HYUNG; KIM TAE YOUNG; YOON YOUNG GI
    权利人:KOREA INST ENERGY RES
    摘要:Disclosed is a direct synthesis method of nanostructured catalyst particles on surfaces of various supports. In the disclosed synthesis method of a catalyst structure having a plurality of nanostructured catalyst particles dispersed in a support by a one-step process using a high-temperature high-pressure closed reactor, the one-step process includes supplying the support and a catalyst source into the high-temperature high-pressure closed reactor; supplying an atmosphere forming gas of the reactor into the reactor; perfectly sealing the high-temperature high-pressure closed reactor and heating the reactor to produce the catalyst structure in the reactor under self-generated pressure and synthesis temperature conditions, the catalyst structure including the plurality of nanostructured catalyst particles dispersed in the support; removing internal gases of the reactor to allow the reactor to be in a high-temperature, atmospheric pressure state and supplying an inert gas into the reactor to remove unreacted materials and byproducts remaining in the reactor; and cooling the reactor to room temperature while supplying the inert gas to synthesize the catalyst structure.

    专利号:US-2003026921-A1
    优先权日:2000-07-06
    标 题 :Low temperature synthesis of semiconductor fiber

    专利号:US-12043893-B2
    优先权日:2017-08-24
    标题:Manufacturing processes to synthesize, functionalize, surface treat and/or encapsulate powders, and applications thereof
    发明人:KING DAVID; DAMERON ARRELAINE; TREVEY JAMES; LICHTY PAUL; ARGO ANDREW; BOURGOIS KYLE; RAGONESI JAMES; INGHAM KYLE; JACKSON DAVID; TRACY RYON; NGUYEN NGHI; LYON ADAM; VILLAGOMEZ JOSE; CURRY GARRETT
    权利人:FORGE NANO INC
    摘要:A system, apparatus and method are provided for processing articles. The system includes subsystems for synthesizing, pre-treating, conducting a vapor phase coating process and post-treating articles in the form of powders and solid or porous workpieces. The apparatus permits vapor phase synthesis, treatment and deposition processes to be performed with high efficiency and at high overall throughput. The methods include converting solids, liquids or gases into gaseous and solid streams that can be separated or exchanged with or without treatment and/or coating steps, and produce optimized composite articles for specific applications.

    专利号:EP-3207991-B1
    优先权日:2016-02-17
    标 题:Direct synthesis method of a catalyst structure having nanostructured catalyst particles dispersed in a support
    发明人:JEONG NAMJO; KIM CHAN-SOO; JWA EUN-JIN; CHOI JI YEON; NAM JOO-YOUN; PARK SOON-CHUL; JANG MOON-SEOK; SEO YONG SEOK; HWANG KYO SIK; KIM HAN KI; HAN JI HYUNG; KIM TAE YOUNG; YOON YOUNG GI
    权利人:KOREA INST ENERGY RES
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    合成参考文献


    参考文献:10.1007/978-0-387-76534-1_5
    摘要:Hosali S, Smith G, Smith L, Vitkavage S, Arkalgud S. Through-Silicon Via Fabrication, Backgrind, and Handle Wafer Technologies. 2008. In: Wafer Level 3-D ICs Process Technology. : Springer US; 2008.
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