CAS: 33629-47-9; Butralin

该化合物是一种化学化合物,被归类为除草剂,主要用于农业,以控制作物中各种杂草; Butralin 属于二硝基除草剂类别,它通过抑制植物中的细胞分裂,有效防止杂草生长;该化合物通常在杂草出现之前适用于土壤,允许其作为先发性除草剂; Butralin 的特征是水溶性相对较低,这助长了其在土壤中的持久性和一段时间内的效力;必须谨慎地处理 butralin,因为如果不按照安全准则使用,它可能会对人类健康和环境造成危险;此外,其使用需要各地区的监管批准,这反映了对潜在生态影响的担忧;

结构式图片

欧盟法规

《欧盟PIC法规》REACH注册ECHA物质"欧盟管控危险化学品"ECHA物质OtherC&L通报REACH预注册

上下游产品

CAS号75-21-8 环氧乙烷 | CAS号4097-49-8 4-叔丁基-2,6-二硝基苯酚 | CAS号33966-50-6 丁胺 | CAS号98-59-9 对甲苯磺酰氯(PTSC) | CAS号2213-81-2 2-氯-5-叔丁基-1,3-二硝基苯 | CAS号77055-30-2 4-叔丁基-2,6-二硝基苯甲醚

合成工艺路线路线简述

  • 合成目标产物 Butralin 主要起始原料 Ethylene Oxide And 4-Tert-Butyl-2,6-Dinitrophenol
  • (文献来源)合成步骤主要原料 Ethylene Oxide 和 4-Tert-Butyl-2,6-Dinitrophenol
4-叔丁基苯酚置于sodium Hydroxide,硝酸体系中,用 甲醇,水,溶剂黄146 作为反应溶剂,化学反应生成 仲丁灵
参考文献:4-Tert-Butyl-N-Sec-Butyl-2,6-Dinitroaniline
标题:4-Tert-Butyl-N-Sec-Butyl-2,6-Dinitroaniline
摘要:小说4-叔丁基-N-丙基-2,6-二硝基苯胺及其光学活性对映体可用作除草剂,杀鱼剂,水生杂草控制剂和菟丝子控制剂.

海关参考信息

专利信息


专利号:WO-2024256370-A1
优先权日:2023-06-13
标 题 :Synthesis of glufosinate using an amidase-based process
发明人:ZIMMERMANN GUNTHER; POTT MORITZ STEFAN
权利人:BASF SE
摘要:The present invention relates to a method of preparing glufosinate, comprising the steps of hydrolysing an N-carbamoyl glufosinate amide with an Amidase enzyme to form an N- carbamoyl amino acid compound followed by cleaving off the carbamoyl moiety of said N- carbamoyl amino acid compound.

专利号:US-2025120400-A1
优先权日:2021-12-10
标题:Synthesis of glufosinate using a hydantoinase-based process
发明人:DITRICH KLAUS; BREUER MICHAEL; POTT MORITZ STEFAN; ZIMMERMANN GUNTHER; SEEMAYER STEFAN
权利人:BASF SE
摘要:The present invention relates to a method of manufacturing glufosinate, comprising the steps of hydrolysing a hydantoin with a Hydantoinase enzyme to form a N-carbamoyl amino acid compound followed by cleaving off the carbamoyl moiety of said N-carbamoyl amino acid compound.

专利号:US-11919928-B2
优先权日:2016-03-16
标题 :Method for producing dihydrotentoxin
发明人:KUBO TAKASHI; MACHIDA MASAYUKI; FUJIOKA TOMONORI; YAMAGUCHI Shigenari; KAWAI KIYOSHI
权利人:KUMIAI CHEMICAL INDUSTRY CO
摘要:An object of the present invention is to identify an enzyme having activity of synthesizing dihydrotentoxin that is a tentoxin precursor and an enzyme having activity of synthesizing tentoxin using dihydrotentoxin as a substrate. The present invention concerns a tentoxin synthesis-related gene encoding a protein comprising the amino acid sequence of SEQ ID NO: 16 and having activity of nonribosomal peptide synthesis of dihydrotentoxin and a tentoxin synthesis-related gene encoding a protein comprising the amino acid sequence of SEQ ID NO: 18 and having activity of converting dihydrotentoxin to tentoxin.

专利号:US-2021386068-A1
优先权日:2018-11-07
标题 :Compositions comprising pyridine carboxylate herbicides and very long chain fatty acid (vlcfa) synthesis inhibitor herbicides
发明人:KISTER JEREMY; SATCHIVI NORBERT M
权利人:CORTEVA AGRISCIENCE LLC
摘要:Disclosed herein are compositions comprising (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a VLCFA synthesis inhibitor herbicide. Also disclosed herein are methods of controlling undesirable vegetation, comprising applying to vegetation or an area adjacent the vegetation or applying in soil or water to control the emergence or growth of vegetation (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof, and (b) a VLCFA synthesis inhibitor herbicide.

专利号:US-2021352899-A1
优先权日:2018-11-07
标题 :Compositions comprising pyridine carboxylate herbicides and fatty acid and lipid synthesis inhibitor herbicides
发明人:KISTER JEREMY; SATCHIVI NORBERT M
权利人:CORTEVA AGRISCIENCE LLC
摘要:Disclosed herein are compositions comprising (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a fatty acid and lipid synthesis inhibitor (FA/LSI) herbicide, an agriculturally acceptable salt or ester thereof, or mixtures thereof. Also disclosed herein are methods of controlling undesirable vegetation, comprising applying to vegetation or an area adjacent the vegetation or applying in soil or water to control the emergence or growth of vegetation (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a fatty acid and lipid synthesis inhibitor (FA/LSI) herbicide, an agriculturally acceptable salt or ester thereof, or mixtures thereof.

专利号:ES-2717283-T3
优先权日:2012-07-24
标 题:Herbicidal compositions comprising 4-amino-3-chloro-5-fluoro-6- (4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid or a derivative thereof and herbicides inhibitors of VLCFA synthesis and synthesis of fatty acids / lipids
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主要参考文献


1: Xu X, Guo X, Song S, Wu A, Xu C, Kuang H, Liu L. Gold-based strip sensor for the rapid and sensitive detection of butralin in tomatoes and peppers. Food Addit Contam Part A Chem Anal Control Expo Risk Assess. 2022 Jul;39(7):1255-1264. doi: 10.1080/19440049.2022.2063391. Epub 2022 Apr 19.
343:128419. doi: 10.1016/j.foodchem.2020.128419. Epub 2020 Oct 19. 192(1):62. doi: 10.1007/s10661-019-8013-z. 16(3):1024. doi: 10.3390/ma16031024.
5: Li C, Liu R, Li L, Li W, He Y, Yuan L. Dissipation behavior and risk assessment of butralin in soybean and soil under field conditions. Environ Monit Assess. 2017 Aug 29;189(9):476. doi: 10.1007/s10661-017-6185-y.

合成参考文献


摘要:U.S. Environmental Protection Agency/Office of Prevention, Pesticides, and Toxic Substances. Reigart, J.R., Roberts, J.R. Recognition and Management of Pesticide Poisonings. 5th ed. 1999. EPA Document No. EPA 735-R-98-003, and available in electronic format at:
摘要:USEPA/Office of Pesticide Programs; Reregistration Eligibility Decision Document - Butrlain. EPA738-R-97-09 May 1998. Available from, as of October 17, 2005:
摘要:Franke C et al; Chemosphere 29: 1501-14 (1994)
摘要:
参考文献:10.1128/aac.01150-09
摘要:Ma C, Tran J, Gu F, Ochoa R, Li C, Sept D, Werbovetz K, Morrissette N. Dinitroaniline activity in Toxoplasma gondii expressing wild-type or mutant alpha-tubulin. Antimicrob Agents Chemother. 2010 Apr;54(4):1453–60.
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