CAS: 4165-57-5; 1-Bromo-2,3,4,5,6-Pentadeuteriobenzene

上下游产品

CAS号1076-43-3 氘代苯 | CAS号71-43-2 苯 | CAS号108-86-1 溴苯 | CAS号7732-18-5 水 | CAS号37055-51-9 二苯胺-d10 | CAS号43019-90-5 苯甲酰氯-D5 | CAS号4165-61-1 苯胺-2,3,4,5,6-d5 | CAS号5161-29-5 苯乙烯-D5 | CAS号25837-46-1 苯乙炔-D5 | CAS号2694-78-2 二苯甲酮-2,3,4,5,6-d5 | CAS号24762-44-5 三苯基膦-d15 | CAS号28077-64-7 1-(苯基-D5)-乙酮 | CAS号1079-02-3 苯甲酸-2,3,4,5,6-d5 | CAS号1211-35-4 2-(4-氯苯基)-1H-吲哚

氘代苯置于sodium Bromate,硫酸体系中,用 水 作为反应溶剂,化学反应 12.0H,以70%的收率获得产物氘代溴苯
参考文献:定向邻位使用的cp *的rh(c-H硼化催化iii)-Nhc络合物†
标题:定向邻位使用的cp *的rh(c-H硼化催化iii)-Nhc络合物†
摘要:Cp * Rh(nhc)配合物与庞大的手性双齿nhc-羧酸盐配体有效地合成和充分表征,包括固态结构.这些空前的铑(iii)配合物在温和条件下在吡啶定向的芳烃邻位c-H硼酸酯化反应中显示出很高的选择性.
DOI:10.1039/c8Cc03144D

专利信息

专利号:US-9309165-B2
优先权日:2012-12-19
标 题 :6-chloro-3-(phenyl-d5)-inden-1-one and use thereof
发明人：JACOBSEN MIKKEL FOG; BRANDES SEBASTIAN
权利人:LUNDBECK & CO AS H
摘要:The present invention discloses the compound 6-chloro-3-(phenyl-d 5 )-inden-1-one (I) and routes of synthesis to obtain (I). In a further aspect the present invention discloses the use of (I) for the synthesis of (S)-6-chloro-3-(phenyl-d 5 )-indan-1-one.

专利号:US-12440831-B2
优先权日:2019-11-11
标 题:Longer-lived ruthenium olefin metathesis catalysts supported by hemi-labile carbene ligands
发明人：SCHRODI YANN; CENA NICOLAS; YOON JOSEPH
权利人:The California State University—Northridge; THE TRUSTEES OF THE CALIFORNIA STATE UNIV
摘要:Contemplated subject matter disclosed herein relates generally to organometallic olefin metathesis catalysts, and more particularly to longer-lived olefin metathesis catalysts supported by hemi-labile carbene ligands that bear an arm with one or more donor ligands, as well as the use of such catalysts in metathesis reactions of olefins and olefin compounds. The contemplated subject matter has utility in the fields of catalysis, organic synthesis, polymer chemistry, and industrial and fine chemicals chemistry. This contemplated subject matter serves to reduce the cost of olefin metathesis (OM) processes including in olefin metathesis polymerizations, conversion of vegetable oils into chemicals, and processes in the petrochemical industry. This contemplated subject matter reduces the cost of OM processes by providing OM catalysts that are longer-lived and lead to higher turnover numbers, hence requiring less catalyst to convert a given amount of substrate(s). Considering that the OM catalyst is the most expensive part of some OM processes, longer-lived OM catalysts have the benefit of reducing the overall cost of the OM processes.

专利号:US-9334275-B2
优先权日:2011-12-19
标题:Processes for preparing indoles
发明人：YOSHIKAI NAOHIKO; WEI YE
权利人:UNIV NANYANG TECH
摘要:Methods for the synthesis of an indole in provided. Methods comprise oxidizing a N-aryl imine in the presence of a palladium-based catalyst, an oxidant, and a solvent.

专利号:US-2012220595-A1
优先权日:2009-11-12
标题:Deuterated Tyrosine Kinase Inhibitors
发明人：EPSTEIN DAVID M; JIN MEIZHONG; MULVIHILL MARK J
权利人:EPSTEIN DAVID M; JIN MEIZHONG; MULVIHILL MARK J; OSI PHARMACEUTICALS LLC
摘要:Compounds of Formula I, as shown below and defined herein: enriched in deuterium, and pharmaceutically acceptable salts thereof, synthesis, intermediates, formulations, and methods of disease treatment therewith, including cancers mediated at least in part by IGF-1R and/or IR.

专利号:CN-105199423-A
优先权日:2015-08-25
标题 :A kind of synthesis method of stable isotope labeling prohibited pigment

专利号:US-7135544-B2
优先权日:1997-04-11
标 题:Living olefin polymerization processes
发明人：SCHROCK RICHARD R; BAUMAN ROBERT
权利人:MASSACHUSETTS INST TECHNOLOGY
摘要:Processes for the living polymerization of olefin monomers with terminal carbon-carbon double bonds are disclosed. The processes employ initiators that include a metal atom and a ligand having two group 15 atoms and a group 16 atom or three group 15 atoms. The ligand is bonded to the metal atom through two anionic or covalent bonds and a dative bond. The initiators are particularly stable under reaction conditions in the absence of olefin monomer. The processes provide polymers having low polydispersities, especially block copolymers having low polydispersities. It is an additional advantage of these processes that, during block copolymer synthesis, a relatively small amount of homopolymer is formed.