CAS: 5558-04-3; 1-Cyclopropyl-1-Phenylethanol

上下游产品

methyl magnesium iodide cyclopropyl phenyl ketone Cyclopropyl methyl ketone methyllithium α-cyclopropylstyrene 4-phenyl-pent-3-en-1-ol 3,3,3-Trifluoro-2-trifluoromethyl-propionic acid (Z)-4-phenyl-pent-3-enyl ester (3)1-Acetoxy-4-phenyl-penten-(3)

1-Cyclopropyl-1-Phenylethanol置于potassium Hydrogensulfate,Lithium Aluminium Tetrahydride,过氧化氢异丙苯,氧气体系中,用 甲苯 作为反应溶剂,化学反应生成 1-环丙基-1-苯基乙醇
参考文献:Reaktivität Und Selektivität Bei Der Oxidation Von Styrolderivaten. V. Untersuchungen Zur Oxidation Vonα-Substituierten Styrolen
标题:Reaktivität Und Selektivität Bei Der Oxidation Von Styrolderivaten. V. Untersuchungen Zur Oxidation Vonα-Substituierten Styrolen
摘要:The Liquid Phase Oxidation Of Alpha-Phenyl-1A,Alpha-Trimethylsilyloxy Ib,Alpha-Cyclopropyl-1C,Alpha-Trifluoromethyl-1D Styrene,And Styrene Le With Oxygen In Chlorobenzene And Cumene Solution In The Temperature Range 55-125 Degrees C Was Investigated. The Product Yields Were Determined Gaschromatographically. The Epoxide Selectivity Increases Up To 90 Degrees C With Increasing Temperature. The Epoxides Of La And Ic Rearrange At Higher Temperatures,Therefore Their Yield Decreases. The Relative Chain Propagation Constants (K(P)C=c) Were Determined By Competitive Oxidations Of Cumene.
DOI:10.1002/(Sici)1521-3897(199901)341:1<52::Aid-Prac52>3.0.Co;2-D

专利信息

专利号:WO-2015103505-A2
优先权日:2014-01-03
标 题:Direct stereospecific synthesis of unprotected aziridines from olefins