CAS: 83834-10-0; 3,7-Dibromodibenzo[b,D]Thiophene

• 英文名称3,7-Dibromodibenzo[b,D]Thiophene
• 中文名称3,7-二溴二苯并[b,d]噻吩
• IUPAC名称3,7-dibromodibenzo[b,d]thiophene
• 其它别名3,7-Dibromodibenzo[b,D]Thiophene; Kmnbvodpwifuss-Uhfffaoysa-N; 3,7-Dibromodibenzothiophene; 3,7-Dibromo-Dibenzothiophene; 5,11-Dibromo-8-Thiatricyclo[7.4.0.0(2),
• CAS编号83834-10-0
• MFCD编号:MFCD01027447
• 分子式:C12H6Br2S
• 分子量:342.05
• 产品CID: 1826662
• 产品分类有机原料 → 杂环化合物

• 相似结构搜索
• InChIKey: KMNBVODPWIFUSS-UHFFFAOYSA-N
• InChI=1S/C12H6Br2S/c13-7-1-3-9-10-4-2-8(14)6-12(10)15-11(9)5-7/h1-6H…
• 计算化学: 氢键受体数1.0氢键供体数0.0可旋转键数0.0

物理性质

• 熔点176°C
• 沸点436.5±25.0 °C(预测)
• 闪点217.8±23.2 °C
• 密度1.905±0.06 g/cm3(预测)
• PSA:28.24
• LogP:5.7
• 外观形态白色至淡黄色粉末至晶体
• 储存条件置于阴暗处,密封, 常温干燥保存
• 产品应用该化合物用于合成含氮化合物,电子部件和电子设备材料.

MSDS等安全信息

• 警示词Warning
• 危险描述H302-H315-H319-H335-
• 防范说明P261-P305+P351+P338-
• 安全声明H303May be harmful if swallowed+H313Skin contact may be harmful+H333Inhalation may be harmful to the body

上下游产品

合成工艺路线路线简述

• 合成目标产物 3,7-Dibromodibenzo[b,D]Thiophene 主要起始原料 3,7-Dibromodibenzothiophene Dioxide
• 2242833-32-3 = 83834-10-0
  反应条件:1.1 Catalysts: Palladium Chloride Solvents: Dimethyl Sulfoxide; 15 H,140 °C
  标题:Edge-Decorated Polycyclic Aromatic Hydrocarbons By An Oxidative Coupling Approach
  作者:Gilmartin,Philip; Et Al
  参考文献:Chemistry - A European Journal 日期:2023 卷标:29(10)]
  
  132-65-0 = 83834-10-0
  反应条件:1.1 Reagents: Hydrogen Peroxide Solvents: Acetic Acid; 4 H,Reflux2.1 Reagents: N-Bromosuccinimide,Sulfuric Acid Solvents: Acetic Acid; 2 H,0 °C; 12 H,Rt2.2 Reagents: Water3.1 Reagents: Lithium Aluminum Hydride Solvents: Tetrahydrofuran; Rt; Rt -> Reflux; 3 H,Reflux; Reflux -> 0 °C3.2 Reagents: Water; 0 °C3.3 Reagents: Hydrochloric Acid Solvents: Water; Ph 3
  标题:Colour Tunability By Optically Induced Electron Transfer In Diarylamine-Dibenzothiophene Derivatives
  作者:Ruighi,Francesco; Et Al
  参考文献:Dyes And Pigments 日期:2023 卷标:219]
  
  197961-37-8 = 83834-10-0
  反应条件:1.1 Reagents: Hydrochloric Acid Solvents: Water; Rt -> 0 °C1.2 Reagents: Potassium Thiocyanate,Sodium Nitrite,Iron Chloride (Fecl3) Solvents: Water; 0 °C; Overnight,0 °C -> Rt1.3 Reagents: Water; Rt1.4 Reagents: Disodium Sulfide Solvents: Ethanol,Water; Overnight,Reflux; Cooled1.5 Reagents: Hydrochloric Acid Solvents: Water; Ph 22.1 Catalysts: Palladium Chloride Solvents: Dimethyl Sulfoxide; 12 H,140 °C
  标题:Cyclization Of 2-Biphenylthiols To Dibenzothiophenes Under Pdcl2/dmso Catalysis
  作者:Zhang,Tao; Et Al
  参考文献:Organic Letters 日期:2018 卷标:20(17) 页码:5439-5443]
  
  53167-81-0 = 83834-10-0
  反应条件:1.1 Reagents: Hydrogen Catalysts: Palladium Solvents: Ethanol1.2 Reagents: Hydrochloric Acid Solvents: Ethanol2.1 Reagents: Hydrochloric Acid Solvents: Water2.2 Reagents: Sodium Nitrite Solvents: Water2.3 Reagents: Copper Bromide (Cubr),Hydrogen Bromide2.4 Solvents: Water
  标题:Synthesis And Anti-Pneumocystis Carinii Pneumonia Activity Of Novel Dicationic Dibenzothiophenes And Orally Active Prodrugs
  作者:Patrick,Donald A.; Et Al
  参考文献:European Journal Of Medicinal Chemistry 日期:1999 卷标:34 页码:575-583]
  
  92-86-4 = 83834-10-0
  反应条件:1.1 -2.1 Reagents: Lithium Aluminum Hydride Solvents: Diethyl Ether
  标题:Anodic Oxidation Of Sulfur-Bridged Hexamethoxybiphenyl Compounds: Isolation Of A Stable Mixed-Valence Salt Of 2,3,4,6,7,8-Hexamethoxydibenzo[bc,Fg][1,4]Dithiapentalene
  作者:Cariou,Michel; Et Al
  参考文献:New Journal Of Chemistry 日期:1996 卷标:20(10) 页码:1031-1039]
  
  83834-12-2 = 83834-10-0
  反应条件:1.1 Reagents: Lithium Aluminum Hydride Solvents: Diethyl Ether; Reflux; 6 H,Reflux1.2 Reagents: Water; Heated1.3 Reagents: Hydrochloric Acid Solvents: Water; Acidified
  标题:Dipolar Stabilization Of Emissive Singlet Charge Transfer Excited States In Polyfluorene Copolymers
  作者:Dias,Fernando B.; Et Al
  参考文献:Journal Of Physical Chemistry B 日期:2008 卷标:112(21) 页码:6557-6566]
  
  2242833-32-3 = 83834-10-0
  反应条件:1.1 Catalysts: Palladium Chloride Solvents: Dimethyl Sulfoxide; 12 H,140 °C
  标题:Cyclization Of 2-Biphenylthiols To Dibenzothiophenes Under Pdcl2/dmso Catalysis
  作者:Zhang,Tao; Et Al
  参考文献:Organic Letters 日期:2018 卷标:20(17) 页码:5439-5443]
  
  251982-99-7 = 83834-10-0
  反应条件:1.1 Reagents: Hydrochloric Acid Solvents: Water1.2 Reagents: Sodium Nitrite Solvents: Water1.3 Reagents: Copper Bromide (Cubr),Hydrogen Bromide1.4 Solvents: Water
  标题:Synthesis And Anti-Pneumocystis Carinii Pneumonia Activity Of Novel Dicationic Dibenzothiophenes And Orally Active Prodrugs
  作者:Patrick,Donald A.; Et Al
  参考文献:European Journal Of Medicinal Chemistry 日期:1999 卷标:34 页码:575-583]
  
  132-65-0 = 83834-10-0
  反应条件:1.1 Reagents: Bromine Catalysts: Iron Chloride (Fecl3) Solvents: Chloroform; 0 °C; 0 °C -> Rt; Overnight,Rt
  标题:Synthesis And Nonlinear Optical Properties Of A New A-π-A Two-Photon Compound Utilizing Dibenzothiophene As Center
  作者:Zhang,Xian; Et Al
  参考文献:Chinese Journal Of Chemistry 日期:2007 卷标:25(12) 页码:1883-1886]
  
  1016-05-3 = 83834-10-0
  反应条件:1.1 Reagents: N-Bromosuccinimide,Sulfuric Acid Solvents: Acetic Acid; 2 H,0 °C; 12 H,Rt1.2 Reagents: Water2.1 Reagents: Lithium Aluminum Hydride Solvents: Tetrahydrofuran; Rt; Rt -> Reflux; 3 H,Reflux; Reflux -> 0 °C2.2 Reagents: Water; 0 °C2.3 Reagents: Hydrochloric Acid Solvents: Water; Ph 3
  标题:Colour Tunability By Optically Induced Electron Transfer In Diarylamine-Dibenzothiophene Derivatives
  作者:Ruighi,Francesco; Et Al
  参考文献:Dyes And Pigments 日期:2023 卷标:219]
  
  197961-37-8 = 83834-10-0
  反应条件:1.1 Reagents: Sodium Nitrite,Hydrochloric Acid Solvents: Water; Rt -> 0 °C; 10 Min,0 °C; 1 H,0 °C1.2 Reagents: Potassium Thiocyanate,Iron Chloride (Fecl3) Solvents: Water; 10 Min,0 °C; 1 H,0 °C; 16 H,0 °C -> Rt1.3 Reagents: Disodium Sulfide Solvents: Ethanol,Water; 24 H,Reflux; Reflux -> Rt1.4 Reagents: Hydrochloric Acid Solvents: Water; Ph 2,Rt2.1 Catalysts: Palladium Chloride Solvents: Dimethyl Sulfoxide; 15 H,140 °C
  标题:Edge-Decorated Polycyclic Aromatic Hydrocarbons By An Oxidative Coupling Approach
  作者:Gilmartin,Philip; Et Al
  参考文献:Chemistry - A European Journal 日期:2023 卷标:29(10)]
  
  439797-69-0 = 83834-10-0
  反应条件:1.1 Reagents: Stannous Chloride Solvents: Ethanol; 17 H,Reflux; Reflux -> Rt1.2 Reagents: Sodium Hydroxide Solvents: Water; Ph 10,0 °C2.1 Reagents: Sodium Nitrite,Hydrochloric Acid Solvents: Water; Rt -> 0 °C; 10 Min,0 °C; 1 H,0 °C2.2 Reagents: Potassium Thiocyanate,Iron Chloride (Fecl3) Solvents: Water; 10 Min,0 °C; 1 H,0 °C; 16 H,0 °C -> Rt2.3 Reagents: Disodium Sulfide Solvents: Ethanol,Water; 24 H,Reflux; Reflux -> Rt2.4 Reagents: Hydrochloric Acid Solvents: Water; Ph 2,Rt3.1 Catalysts: Palladium Chloride Solvents: Dimethyl Sulfoxide; 15 H,140 °C
  标题:Edge-Decorated Polycyclic Aromatic Hydrocarbons By An Oxidative Coupling Approach
  作者:Gilmartin,Philip; Et Al
  参考文献:Chemistry - A European Journal 日期:2023 卷标:29(10)]
  
  439797-69-0 = 83834-10-0
  反应条件:1.1 Reagents: Acetic Acid,Zinc Solvents: Tetrahydrofuran; 16 H,Rt2.1 Reagents: Hydrochloric Acid Solvents: Water; Rt -> 0 °C2.2 Reagents: Potassium Thiocyanate,Sodium Nitrite,Iron Chloride (Fecl3) Solvents: Water; 0 °C; Overnight,0 °C -> Rt2.3 Reagents: Water; Rt2.4 Reagents: Disodium Sulfide Solvents: Ethanol,Water; Overnight,Reflux; Cooled2.5 Reagents: Hydrochloric Acid Solvents: Water; Ph 23.1 Catalysts: Palladium Chloride Solvents: Dimethyl Sulfoxide; 12 H,140 °C
  标题:Cyclization Of 2-Biphenylthiols To Dibenzothiophenes Under Pdcl2/dmso Catalysis
  作者:Zhang,Tao; Et Al
  参考文献:Organic Letters 日期:2018 卷标:20(17) 页码:5439-5443

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