CAS: 1120-25-8; (Z)-Methyl Hexadec-9-Enoate

该化合物是源自棕榈油酸的脂肪酸甲基酯,通常用作脂类分析的参考标准,并作为有机合成的中间体. 化合物的主要优点包括高纯度,稳定性和特性,使其适合色谱学,生物化学和工业研究的应用. 它不饱和的结构允许合成途径进一步发挥作用. 甲基棕榈油还用于脂类代谢研究,并因其有利的燃烧特性而作为生物柴油配方的组成部分. 酯的一贯质量确保分析和实验环境中的可靠性能.

结构式图片

相似化合物

373-49-9 1937-62-8 112-62-9

欧盟法规

ECHA物质C&L通报REACH预注册

上下游产品

methyl ester of azelaic acid aldehyde triphenylheptylphosphonium bromide methanol cis-9-hexadecenoic acid9,10-dihydroxy-hexadecanoic acid threo-9,10-Dihydroxy-hexadecansaeure(+/-)-threo-9,10-Dihydroxy-hexadecansaeure palmitoleyl alcohol azelaic acid

合成工艺路线路线简述

    10,11-Dibromo-Undecanoic Acid置于pd-Baso4 喹啉,氢氧化钾,氢气,对甲苯磺酸,臭氧,Sodium Amide,Peg 400体系中,用 正己烷,二氯甲烷 用作溶剂,化学反应 13.5H,反应生成棕榈油酸甲酯
    参考文献:Narasimhan,S.; Mohan,H.,Indian Journal Of Chemistry-Section B Organic And Medicinal Chemistry,1995,Vol. 34,# 11,P. 950-953
    标题:Narasimhan,S.; Mohan,H.,Indian Journal Of Chemistry-Section B Organic And Medicinal Chemistry,1995,Vol. 34,# 11,P. 950-953

    海关参考信息

    专利信息


    专利号:US-10787688-B2
    优先权日:2012-05-11
    标 题:Multi-stage synthesis method with synthesis gas
    发明人:HAAS THOMAS; WITTMANN EVA MARIA
    权利人:EVONIK OPERATIONS GMBH
    摘要:The invention provides a process for the preparation of hydrocarbons substituted with at least one group containing at least one oxygen atom, comprising the process stepsn A) reaction of a carbon source comprising at least one selected from CO 2 and CO to give acetate and/or ethanol with a first microorganism, B) separating off of the acetate from the first microorganism, C) reaction of the acetate to give a hydrocarbon substituted with at least one group containing at least one oxygen atom with a second microorganism and optionally D) purification of the hydrocarbon substituted with at least one group containing at least one oxygen atom.

    专利号:US-2005214275-A1
    优先权日:2004-01-02
    标题:Sequential ordered fatty acid alpha oxidation and delta9 desaturation are major determinants of lipid storage and utilization in adipocytes
    发明人:GROSS RICHARD W
    权利人:GROSS RICHARD W
    摘要:A method for intentionally modulating by externally directing the amount of fat in a living mammal having adipocyte cells which comprises administering a compound thereto having reactive selectivity to the metabolic regulatory system of the cells of the animal to increase the fatty acid α oxidation of the lipid content in the differentiating adipocyte thereby reducing the amount of equivalents available for ATP synthesis.

    专利号:CN-104910009-A
    优先权日:2015-06-25
    标题 :A kind of method of ionic liquid catalyzed synthesis of pletil alcohol ester

    专利号:US-2015065682-A1
    优先权日:2013-08-30
    标 题 :Aliphatic polyesters and copolyesters derived from natural oils and their related physical properties
    发明人:NARINE SURESH; BOUZIDI LAZIZ; LI SHAOJUN; JOSE JESMY; POURFALLAH GHAZALEH
    权利人:ELEVANCE RENEWABLE SCIENCES
    摘要:The synthesis of certain medium and long chain ω-hydroxy esters and certain ω-hydroxy fatty acids is disclosed. Such ω-hydroxy esters and ω-hydroxy fatty acids are derived from natural oils, and their corresponding polymers were obtained by melt polycondensation. Additionally, the present effort investigates the effects of structural and molecular parameters on the thermal and mechanical properties of ω-hydroxy ester based polymers. Additionally, the present effort investigates the co-polymerization of ω-hydroxy ester based polymers.

    专利号:US-2014186905-A1
    优先权日:2011-08-15
    标题 :Biotechnological synthesis process of organic compounds with the aid of an alkl gene product
    发明人:SCHAFFER STEFFEN; GIELEN JASMIN; DECKER NICOLE; KIRCHNER NICOLE; HAAS THOMAS; POETTER MARKUS; HAEGER HARALD
    权利人:SCHAFFER STEFFEN; GIELEN JASMIN; DECKER NICOLE; KIRCHNER NICOLE; HAAS THOMAS; POETTER MARKUS; HAEGER HARALD; EVONIK DEGUSSA GMBH
    摘要:Subject matter of the invention is a biotechnological process for the production of organic compounds with the aid of at least one alkL gene product.

    专利号:CN-109879905-B
    优先权日:2019-02-18
    标 题 :Preparation method of naphthyl sulfonic group modified SBA-15 and application of naphthyl sulfonic group modified SBA-15 in synthesis of phospholipid rich in unsaturated fatty acid structure
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    主要参考文献

    [参考文献]: Eleftheria Diakogiannaki, Et Al. Mechanisms Involved In The Cytotoxic And Cytoprotective Actions Of Saturated Versus Monounsaturated Long-Chain Fatty Acids In Pancreatic Beta-Cells. J Endocrinol. 2007 Aug;194(2):283-91.
    [参考文献]: C Rentel, Et Al. Coupling Of Capillary Electrochromatography To Coordination Ion Spray Mass Spectrometry, A Novel Detection Method. Electrophoresis. 1999 Sep;20(12):2329-36.
    [参考文献]: Oier Aizpurua-Olaizola, Et Al. Optimization Of Supercritical Fluid Consecutive Extractions Of Fatty Acids And Polyphenols From Vitis Vinifera Grape Wastes. J Food Sci. 2015 Jan;80(1):E101-7.
    [参考文献]: P W Wertz, Et Al. Metabolism Of Topically Applied Fatty Acid Methyl Esters In Balb/c Mouse Epidermis. J Dermatol Sci. 1990 Jan;1(1):33-7.
    [参考文献]: Xian-Guo Zou, Et Al. Lipozyme Rm Im-Catalyzed Acidolysis Of Cinnamomum Camphora Seed Oil With Oleic Acid To Produce Human Milk Fat Substitutes Enriched In Medium-Chain Fatty Acids. J Agric Food Chem. 2014 Oct 29;62(43):10594-603.

    合成参考文献


    摘要:S109 | PARCEDC | List of 7074 potential endocrine disrupting compounds (EDCs) by PARC T4.2 | DOI:10.5281/zenodo.10944198
    参考文献:10.1007/bf02522980
    摘要:Smith DR, Knabe DA, Cross HR, Smith SB. A diet containing myristoleic plus palmitoleic acids elevates plasma cholesterol in young growing swine. Lipids. 1996 Aug;31(8):849–58. doi: 10.1007/bf02522980.
    参考文献:10.1007/s11745-008-3174-5
    摘要:Cvacka J, Kofronová E, Vasícková S, Stránský K, Jiros P, Hovorka O, Kindl J, Valterová I. Unusual fatty acids in the fat body of the early nesting bumblebee, Bombus pratorum. Lipids. 2008 May;43(5):441–50. doi: 10.1007/s11745-008-3174-5.
    参考文献:10.1186/s13068-015-0345-5
    摘要:Jena U, McCurdy AT, Warren A, Summers H, Ledbetter RN, Hoekman SK, Seefeldt LC, Quinn JC. Oleaginous yeast platform for producing biofuels via co-solvent hydrothermal liquefaction. Biotechnology for Biofuels and Bioproducts. 2015 Oct 13;8(1):167. doi: 10.1186/s13068-015-0345-5.
    参考文献:10.1007/s11745-003-1176-8
    摘要:Tsevegsuren N, Aitzetmuller K, Vosmann K. Isomers of hexadecenoic and hexadecadienoic acids in Androsace septentrionalis (Primulaceae) seed oil. Lipids. 2003 Nov;38(11):1173–8. doi: 10.1007/s11745-003-1176-8.
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