CAS: 130-23-4; 4-Amino-5-Hydroxynaphthalene-1,7-Disulfonic Acid

该化合物是一种有机化合物,其特点是氨基和羟基功能组的氯化萘结构,以及两个磺酸组.该化合物一般在室温下是固体,由于全氟辛烷磺酸组的存在,可溶于水中,从而增加其极度.H-酸主要用于染色工业,作为合成氮染料和其他色剂的中间体.其化学特性包括能够进行电子生物替代反应,使其在有机合成中成为多功能建筑块.此外,氨基和羟基组的存在可以使氢具有潜在的结合作用,影响其再活性和溶性.安全数据表明,应谨慎处理,因为它可能会在皮肤或眼睛接触时引起刺激.

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116-63-2 87-02-5 83-64-7

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CAS号90-20-0 H酸 | CAS号17894-99-4 1-萘胺-4,6,8-三磺酸 | CAS号6361-49-5 4-(benzoylamino...

合成工艺路线路线简述

    1-萘胺-4,6,8-三磺酸置于alkali Hydroxide体系中,化学反应生成1-氨基-8-萘酚-4,6-二磺酸
    参考文献:De80741
    标题:De80741

    海关参考信息

    专利信息


    专利号:WO-9108265-A1
    优先权日:1989-12-02
    标 题:Azo compounds and their use as dyes, 1-sulpho-6-carboxyl-amino naphthaline, its use as a diazo component and process for the production of these compounds
    发明人:SPRINGER HARTMUT; HUSSONG KURT
    权利人:HOECHST AG
    摘要:The description relates to azo compounds corresponding to formula (1) below, having fibre-reactive properties and making valuable dyes. They can dye hydroxy and/or carbonamide group-containing synthetic and natural materials, especially fibre materials, like wool and especially cellulose fibre materials in bright colours. Formula (1) in which: M is hydrogen or a salt-forming metal like an alkaline metal; K is a residue of general formulae (2A) or (2B) in which: E is the residue of an intermediate component common in disazo dyes which can act as a coupling and as a diazo component, e.g. the residue of a 1-(aminophenyl) or -amino-naphthyl) pyrazolon, aminonaphthol, anilin or 1-amino naphthalin compound; v is the figure zero or 1; K is the residue of a water-soluble coupling component, preferably from the naphthol, aminonaphthol, anilin, pyrazolon, hydroxypyridon and acetoacetyl arylide series, whereby this coupling component contains 1 or 2 fibre-reactive groups of the vinyl sulphonate series; D is a benzol or naphthalin residue, whereby its substituents R?1 and R?2 are common ones in azo dyes, e.g. (besides hydrogen) lower alkyl, lower alkoxy, halogen, sulpho and carboxyl; the group -SO2?-Y is a fibre-reactive group of the vinyl sulphone series; a is the figure zero, 1 or 2; and k is the number 1 or 2. A description is also given of the compound 2-amino naphthaline-1-sulphonic acid-6-carboxylic acid which may be used as a pre-product in the production of dyes, e.g. as diazo component in the synthesis of dyes of general formula (1).

    专利号:US-4719053-A
    优先权日:1980-08-01
    标题 :Beta-chloroethylsulfonylmethyl-benzoic halides as intermediates
    发明人:SCHLAEFER LUDWIG; HAEHNLE REINHARD
    权利人:HOECHST AG
    摘要:New beta -chloroethylsuflonylmethyl-benzoic acid halides which can serve as fibre-reactive anchors for thesynthesis of novel organic, water-soluble compounds, preferably dyestuffs, having fibre-reactive and fibre-finishing properties, such as preferably dyestuff properties, and containing, as a fibre-reactive group, one or two beta -chloroethylsufonylmethylbenzoic acid amide groups. For the synthesis of these novel fibre-finishing compounds, said new beta -chloroethylsulfonylmethyl-benzoic acid halide compounds are reacted with an organic, water-soluble compound having fibre-finishing properties and continuing one or two amino groups. Also precursors of the fibre-finishing, fibre-reactive compounds, containing said beta -chloroethylsulfonylmethyl-benzxoic acid amid grouping, can be employed for their synthesis. The novel fibre-finishing compounds can be applied onto suitable fibre materials, such as especially cellulose fibre material and natural or synthetic polyamide fibre materials, and fixed on these fibre materials in a manner similar to application and fixation methods usual in the technique for fibre-reactive compounds. The fibre-finished material, such as dyed material, shows very good wet fastnesses.

    专利号:US-5508389-A
    优先权日:1990-09-27
    标题 :Process for producing concentrated aqueous solutions of anionic azo dyes
    发明人:MISCHKE PETER; HOHMANN KURT; SCHWAB ECKHARD; SITTIG MANFRED
    权利人:HOECHST AG
    摘要:PCT No. PCT/EP91/01830 Sec. 371 Date Mar. 26, 1993 Sec. 102(e) Date Mar. 26, 1993 PCT Filed Sep. 25, 1991 PCT Pub. No. WO92/06140 PCT Pub. Date Apr. 16, 1992.If highly concentrated aqueous solutions of azo dyes are prepared directly by diazotization and coupling reactions, appreciable difficulties generally result as a consequence of the fact that the diazotization and coupling reactions give rise to viscous phases which lead to stirring problems in the reaction apparatus used, which in turn results in an incomplete synthesis. The novel process for preparing concentrated aqueous dye solutions of an anionic dye in an aqueous medium overcomes this disadvantage by carrying out the diazotization of the aromatic amine diazo component and/or the coupling reaction between the diazonium salt and the coupling component in the presence of an auxiliary which exerts a viscosity-reducing effect on pasty phases. Examples of such auxiliaries are optionally alkyl-substituted naphthalenesulfonic acid-formaldehyde condensation products, ligninsulfonates, polyacrylates and copolymers of maleic anhydride and methacrylic acid or acrylic acid.

    专利号:TW-201518323-A
    优先权日:2013-07-25
    标题 :Synthesis of biological conjugates of APELIN polypeptides

    专利号:DE-2928136-A1
    优先权日:1979-07-12
    标 题:PHOSPHOROUS AZO COMPOUNDS AND THE PRODUCTION AND USE THEREOF AS PEST CONTROL, LIGHT-SENSITIVE MATERIALS AND AS SUBSTANCES FOR THE SYNTHESIS OF PYRAZOLONES

    专利号:ES-2278787-T3
    优先权日:2000-10-07
    标 题:METHOD FOR SYNTHESIS OF PEPTIDES, MIMETIC PEPTIDES AND PROTEINS.
    江苏兴盛化工有限公司
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    合成参考文献


    参考文献:10.1007/s10895-021-02851-9
    摘要:Golcs Á, Kovács K, Vezse P, Huszthy P, Tóth T. New Polymerizable Tetraaza Macrocycle Containing Two Acridine Units for Selective Fluorescence Sensing of Metal Ions. Journal of Fluorescence. 2021 Dec 29;32(2):473–81. doi: 10.1007/s10895-021-02851-9.
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