2-羟基-2-甲基丁腈置于硫酸,苯体系中,化学反应生成 惕各酸乙酯 参考文献:The Preparation Of Tiglic And Angelic Acids And Esters1 标题:The Preparation Of Tiglic And Angelic Acids And Esters1 摘要: DOI:10.1021/jo01149A038
专利号:US-8008526-B2 优先权日:2005-03-17 标 题 :Synthesis reaction catalyst and method of synthesizing compound using the same 发明人:TANAKA HIROHISA; KANEKO KIMIYOSHI 权利人:DAIHATSU MOTOR CO LTD; HOKKO CHEM IND CO 摘要:To improve a catalytic activity of a composite oxide, to carry out a reaction in a high yield, and to provide a synthesis reaction catalyst having excellent handling properties and a method of a synthesizing a compound using the same, a synthesis reaction catalyst containing a palladium-containing perovskite-type composite oxide having a specific surface area of 0.5 to 9.5 m 2 /g is used in Suzuki Cross-Couplings given by the following general scheme (14).
专利号:US-2004106808-A1 优先权日:2000-12-22 标题:Processes for preparing calanolide a and intermediates thereof 发明人:TERASHIMA SHIRO; KOYAKUMARU KENICHI 摘要:The present invention provides a production method of Calanolide A according to the following method n n n wherein each symbol is as defined in the specification, as a more convenient and industrially practical method for the synthesis of Calanolide A from an easily available starting material.
专利号:US-7592473-B2 优先权日:2005-03-17 标题:Method of synthesizing compound 发明人:TANAKA HIROHISA; KANEKO KIMIYOSHI 权利人:DAIHATSU MOTOR CO LTD; HOKKO CHEM IND CO 摘要:In order to provide a method of synthesizing a compound in which activity of a catalyst is maintained even when the catalyst is recovered after the completion of the coupling reaction using a palladium-containing perovskite-type composite oxide as the catalyst and used repeatedly and the reaction can be carried out in a high yield, a palladium-containing perovskite-type composite oxide is used as a synthesis reaction catalyst and a reaction solvent containing an alkoxy alcohol is used as a reaction solvent in Suzuki Cross-Couplings given by the following general formula (15).
专利号:US-9884316-B2 优先权日:2014-03-10 标题:Mononuclear ruthenium complex and organic synthesis reaction using same 发明人:NAGASHIMA HIDEO; SUNADA YUSUKE; OGUSHI HAJIME; SAKUTA KOJI 权利人:UNIV KYUSHU NAT UNIV CORP; SHINETSU CHEMICAL CO 摘要:A neutral or cationic mononuclear ruthenium divalent complex represented by formula (1) can actualize exceptional catalytic activity in at least one reaction among a hydrosilylation reaction, hydrogenation reaction, and carbonyl compound reduction reaction. n n(In the formula, R 1 -R 6 each independently represent a hydrogen atom or an alkyl group, aryl group, aralkyl group, organooxy group, monoorganoamino group, diorganoamino group, monoorganophosphino group, diorganophosphino group, monoorganosilyl group, diorganosilyl group, triorganosilyl group, or organothio group optionally substituted by X; at least one pair comprising any of R 1 -R 3 and any of R 4 -R 6 together represents a crosslinkable substituent; X represents a halogen atom, organooxy group, monoorganoamino group, diorganoamino group, or organothio group; L each independently represent a two-electron ligand other than CO and thiourea ligands; two L may bond to each other; and m represents an integer of 3 or 4.)
专利号:US-10363551-B2 优先权日:2015-03-09 标 题:Mononuclear iron complex and organic synthesis reaction using same 发明人:NAGASHIMA HIDEO; SUNADA YUSUKE; SAWANO Mina; NODA DAISUKE; SAKUTA KOJI 权利人:UNIV KYUSHU NAT UNIV CORP; SHINETSU CHEMICAL CO 摘要:A mononuclear iron bivalent complex having iron-silicon bonds, which is represented by formula (1), can exhibit an excellent catalytic activity in at least one reaction selected from three reactions, i.e., a hydrosilylation reaction, a hydrogenation reaction and a reaction for reducing a carbonyl compound. n n n n n n n n n n (In the formula, R 1 to R 6 independently represent a hydrogen atom, an alkyl group which may be substituted by X, or the like; X represents a halogen atom, or the like; L 1 represents at least one two-electron ligand selected from an isonitrile ligand, an amine ligand, an imine ligand, a nitrogenated heterocyclic ring, a phosphine ligand, a phosphite ligand and a sulfide ligand, wherein, when multiple L 1 's are present, two L 1 's may be bonded to each other; L 2 represents a two-electron ligand that is different from a CO ligand or the above-mentioned L 1 , wherein, when multiple L 2 's are present, two L 2 's may be bonded to each other; and m 1 represents an integer of 1 to 4 and m 2 represents an integer of 0 to 3, wherein the sum total of m 1 and m 2 (i.e., m 1 +m 2 ) satisfies 3 or 4.)
专利号:US-2009023943-A1 优先权日:2005-03-17 标题 :Synthesis Reaction Catalyst and Method of Synthesizing Compound Using the Same
[参考文献]: Eric Grondin, Et Al. Physiological And Biochemical Characteristics Of The Ethyl Tiglate Production Pathway In The Yeast Saprochaete Suaveolens. Yeast. 2015 Jan;32(1):57-66. [参考文献]: R J Bartelt, Et Al. Aggregation Pheromones Indrosophila Borealis Anddrosophila Littoralis. J Chem Ecol. 1988 Apr;14(4):1319-27.
合成参考文献
摘要:Landelle, G.; Paquin, J.-F., Science of Synthesis Knowledge Updates, (2011) 2, 450. 摘要:Landelle, G.; Paquin, J.-F., Science of Synthesis Knowledge Updates, (2011) 2, 454. 摘要:Landelle, G.; Paquin, J.-F., Science of Synthesis Knowledge Updates, (2011) 2, 445. 摘要:Haufe, G., Science of Synthesis Knowledge Updates, (2019) 3, 250. 摘要:Cuenca, A. B.; Fernández, E., Science of Synthesis: N-Heterocyclic Carbenes in Catalytic Organic Synthesis, (2016) 1, 335.