CAS: 10025-97-5; Iridium(Iv) Chloride

该化合物是一种高度多种用途的无机化合物,主要用于催化,电化学和材料科学,其主要优点包括:在恶劣条件下异常稳定,适合高温和腐蚀性环境;该化合物具有很强的催化作用,特别是由于独特的电子特性,在氢化和氧化反应方面尤为如此;它还因其在合成环乙二烯和其他先进材料的基复合体方面的作用而备受珍视;以无水和水化形式提供的,二氯化提供精确的再活动控制,确保研究和工业应用的一贯性能;其高纯度和定义精密的同位素测量法使它成为专门化学工艺的可靠选择.

结构式图片

相似化合物

10025-83-9 16941-92-7 16920-56-2

欧盟法规

ECHA物质ECHA物质C&L通报REACH预注册

上下游产品

iridium tetrachloride monohydratecis-trichloro tridibenzyl sulfide iridium(III)

合成工艺路线路线简述

    四氯化铱 以 Solid 用作溶剂,化学反应生成四氯化铱
    参考文献:Kamiya,Nobuyuki; Hoshino,Ken-Ichi; Ota,Ken-Ichiro,Nippon Kagaku Kaishi/journal Of The Chemical Society Of Japan
    标题:Kamiya,Nobuyuki; Hoshino,Ken-Ichi; Ota,Ken-Ichiro,Nippon Kagaku Kaishi/journal Of The Chemical Society Of Japan

    专利信息


    专利号:US-2024424490-A1
    优先权日:2021-01-25
    标 题 :Method of synthesis of carbon-supported platinum group metal or metal alloy nanoparticles
    发明人:WNUK PAWEL; LEWERA ADAM; JURCZAKOWSKI RAFAL; POWALA FILIP; KOLODZIEJCZYK JAN
    权利人:UNIV WARSZAWSKI
    摘要:The presented invention relates to a method of synthesis of carbon-supported platinum group metal or metal alloy nanoparticles, which comprises the following steps:n adsorbing on carbon support complexes of a platinum group metal with a urea complexing agent selected from a group comprising urea, urea derivative, a mixture of urea with at least one urea derivative, and a mixture of at least two urea derivatives; and reducing the complexes adsorbed on the carbon support to metal nanoparticles, forming a product of carbon-supported metal nanoparticles. nn The invention also provides the use of the carbon-supported platinum group metal or metal alloy nanoparticles obtained by the method of the invention as catalyst. n The present invention further relates to a method of adsorption of precursors of platinum group metals on the surface of a carbon support and use of complexes of platinum group metals with urea complexing agent for adsorption of platinum group metal precursors on carbon support.

    专利号:US-6376423-B2
    优先权日:1997-04-11
    标 题 :Catalyst for preparation of synthesis gas and process for preparing carbon monoxide
    发明人:YAGI FUYUKI; NAGUMO ATSURO; WADA YUKITAKA; SHIMURA MITSUNORI; ASAOKA SACHIO; WAKAMATSU SHUHEI
    权利人:CHIYODA CHEM ENG CONSTRUCT CO
    摘要:Disclosed are a catalyst for producing a synthesis gas using a carbon-containing organic compound as a raw material and a process for producing carbon monoxide. The catalyst for producing a synthesis gas is composed of a carrier formed of a metal oxide and at least one catalytic metal selected from rhodium, ruthenium, iridium, palladium and platinum and supported on the carrier and is characterized in that the catalyst has a specific surface area of 25 m 2 /g or less, in that the electronegativity of the metal ion of the carrier metal oxide is 13.0 or less and in that the amount of the supported catalytic metal is 0.0005-0.1 mole %, in terms of a metal, based on the carrier metal oxide. The process for producing carbon monoxide includes a step of reacting a carbon-containing organic compound with carbon dioxide in a pressurized condition to produce a synthesis gas, and a step of concentrating carbon monoxide in the thus obtained synthesis gas and is characterized in that the above-described catalyst is used as a catalyst in the synthesis gas producing step.

    专利号:US-6340437-B1
    优先权日:1997-04-11
    标 题:Process for preparing synthesis gas by autothermal reforming
    发明人:YAGI FUYUKI; NAGUMO ATSURO; WADA YUKITAKA; SHIMURA MITSUNORI; ASAOKA SACHIO; WAKAMATSU SHUHEI
    权利人:CHIYODA CHEM ENG CONSTRUCT CO
    摘要:Disclosed is a process for producing a synthesis gas by an autothermal reforming method including a step of partially oxidizing a carbon-containing organic compound to produce a high temperature mixed gas, and a synthesis producing step of reacting the unreacted carbon-containing organic compound contained in the high temperature mixed gas with carbon dioxide and/or steam, wherein a catalyst having a considerably suppressed carbon deposition activity is used as a catalyst for the synthesis gas producing step. The catalyst is characterized in that the catalyst comprises a carrier formed of a metal oxide, and at least one catalytic metal selected from rhodium, ruthenium, iridium, palladium and platinum and supported on the carrier, in that the catalyst has a specific surface area of 25 m 2 /g or less, in that metal ion of the carrier metal oxide has electronegativity of 13.0 or less, and in that the amount of the catalytic metal supported is 0.0005-0.1 mole %, in terms of a metal, based on the carrier metal oxide.

    专利号:US-2024253022-A1
    优先权日:2021-06-04
    标 题 :Hydroxyapatite catalysts for isobutanol synthesis
    发明人:LONG RICHARD; RUAN TIAN; SCHIPPER DESMOND; Havran Mueller Vesna
    权利人:UOP LLC; CHINA PETROLEUM & CHEM CORP
    摘要:Metal-doped hydroxyapatite catalysts for isobutanol and propanol synthesis have been developed which exhibit good isobutanol yield in propanol-methanol and ethanol-methanol reactions. The metal-doped hydroxyapatites include, but are not limited to, one or more of metal-doped Mg x PO y , Ca x PO y , Sr x PO y and Ba x PO y . The metal-doped hydroxyapatites may have different phosphorus to alkaline earth ratios. Methods for making isobutanol and propanol using the metal-doped hydroxyapatite catalysts are also provided.

    专利号:WO-2022158990-A1
    优先权日:2021-01-25
    标 题 :Method of synthesis of carbon-supported platinum group metal or metal alloy nanoparticles

    专利号:US-2025058379-A1
    优先权日:2022-12-13
    标 题 :Method of preparing iridium nanocrystal
    发明人:WANG YANFEI; YU YINGLONG; SHAO CHENYI; LONG CHUAN; ZHAO QINFENG; WANG JINGJING; HE YEHENG; LI QINGXUN
    权利人:PETROCHINA CO LTD
    摘要:The present application provides a preparation method for iridium nanocrystal, including the following steps: mixing an iridium salt, an alcohol solvent and a centrifugal waste liquid to form a mixed solution, and adding an alkali solution in an inert atmosphere for a heating reaction. After centrifugation, an iridium nanocrystal is obtained. The centrifugal waste liquid is a waste liquid produced in the pre-synthesis process of iridium nanocrystal. The preparation method can shorten the reaction time, and the obtained iridium nanocrystal has the advantages of high yield and low cost.
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    合成参考文献


    摘要:Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases., 21(7)(55), 1977
    摘要:Cotton FA, Wilkinson G; Advanced Inorganic Chemistry 5th ed NY, NY: John Wiley and Sons, p. 902 (1988)
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