90-05-1 = 1138-52-9 + 120-95-6 + 1620-98-0 + 1020-31-1 + 4130-42-1 + 94-71-3 + 876-20-0 + 2934-05-6 + 5076-72-2 + 59056-76-7 + 52417-48-8 + 33963-27-8 + 2078-54-8 + 2444-28-2 + 128-39-2 + 1879-09-0 + 87-97-8 + 79-74-3 + 2050-46-6 反应条件:1.1 Catalysts: Tungstic Acid (H2Wo4); Rt -> 300 °C; 6 H,300 °C 标题:Highly Selective Conversion Of Guaiacol To Tert-Butylphenols In Supercritical Ethanol Over A H2Wo4 Catalyst 作者:Mai,Fuhang; Et Al 参考文献:Rsc Advances 日期:2019 卷标:9(5) 页码:2764-2771
3,5-二叔丁基苯胺 反应生成3,5-二叔丁基苯酚 参考文献:Mueller,E. Et Al.,Justus Liebigs Annalen Der Chemie,1964,Vol. 673,P. 40-59 标题:Mueller,E. Et Al.,Justus Liebigs Annalen Der Chemie,1964,Vol. 673,P. 40-59
专利号:US-7098354-B2 优先权日:2002-10-25 标 题:Racemoselective synthesis of rac-diorganosilylbis(2-methylbenzo[e]indeyl)zirconium compounds 发明人:DAMRAU HANS-ROBERT; MUELLER PATRIK; GARCIA VALERIE; SIDOT CHRISTIAN; TELLIER CHRISTIAN; LELONG JEAN-FRANCOIS 权利人:BASELL POLYOLEFINE GMBH 摘要:The present invention relates to a specific process for the diastereoselective synthesis of rac-diorganosilylbis(2-methylbenzo[e]indenyl)zirconium compounds of the formula I, n nby reacting the silyl-bridged bisindenyl ligand with a dihalozirconium bis(3,5-di-tert-butylphenoxide)-base adduct to form the diorganosilylbis(2-methylbenzo[e]indenyl)zirconium bis(3,5-di-tert-butylphenoxide) and subsequently replacing the phenoxide groups by X using suitable replacement reagents to give the compound of the formula I; where the substituents X can be identical or different and are each F, Cl, Br, I or linear, cyclic or branched C 1-10 -alkyl; and the substituents R can be identical or different and are each linear, cyclic or branched C 1-10 -alkyl or C 6-10 -aryl; and also to the use of these compounds as catalysts.
专利号:US-5670465-A 优先权日:1993-01-08 标题 :Preparation of p-fuchsones and synthesis of p-dihydroxylated aromatic compounds therefrom 发明人:COSTANTINI MICHEL; MANAUT DANIEL; MICHELET DANIEL 权利人:RHONE POULENC CHIMIE 摘要:p-Dihydroxylated aromatic compounds are prepared via the oxidation of p-fuchsones, the latter advantageously being synthesized by reacting a phenolic compound having at least one hydrogen atom in the para-position to the hydroxyl function with a non-enolizable ketonic compound, in the presence of a catalytically effective amount of an acid catalyst and, optionally, a cocatalytically effective amount of an ionizable sulfur-containing compound.
专利号:US-2004110228-A1 优先权日:2002-04-01 标 题:Combinatorial organic synthesis of unique biologically active compounds 发明人:MCALPINE SHELLI R; TAYLOR RACHEL E; BOLLA MEGAN L; SEGALL ANCA M 摘要:The invention provides a method for making a combinatorial library of cyclic compounds, such as Holliday junction-trapping compounds, comprising the steps of (a) obtaining a plurality of trimers according to the generic structure X 1- X 2- X 3 , wherein X 1 , X 2 and X 3 can be independently any naturally or nonnaturally occurring amino acids or peptidomimetics thereof; (b) optionally coupling a spacer S to the trimer at either end; (c) cyclizing two trimers or trimer-spacer conjugates in a head-to-tail orientation; thereby obtaining a combinatorial library of compounds, wherein the library does not include an unmodifed or naturally occurring Holliday Junction-trapping compounds. The invention additionally provides methods macrocyclic compounds that are synergimycin derivatives.
专利号:EP-0492350-B1 优先权日:1990-12-17 标 题 :Process for the production of (S)-vinyl and (S) allenyl gaba 发明人:EVANS JONATHAN C 权利人:MERRELL PHARMA INC 摘要:The present invention is directed to a stereospecific synthesis of (S)-vinyl-GABA, (S)-allenyl-GABA, (S)-5-allenylpyrrolidinone, and (S)-5-vinyl-pyrrolidinone. Another aspect is directed to a class of 1,5-disubstituted-pyrrolidinone intermediates as well as a new class of chiral lactic acid derivatives. t
专利号:US-10017391-B2 优先权日:2015-04-23 标题:Direct polymer templating synthesis of mesoporous carbon 发明人:DAI SHENG; NELSON KIMBERLY M 权利人:UT BATTELLE LLC; UNIV TENNESSEE RES FOUND 摘要:The invention is directed to a method for fabricating a mesoporous carbon composite material. The method comprises providing a precursor composition and subjecting the precursor material to a curing step followed by carbonization step. The precursor composition comprises (i) a templating component comprised of a linear homopolymer material, (ii) a phenolic compound or material, (iii) a crosslinkable aldehyde component, and (iv) an acid catalyst.
专利号:US-5208345-A 优先权日:1990-12-17 标 题:Process for the production of (S)-vinyl and allenyl gaba 发明人:EVANS JONATHAN C 权利人:MERRELL DOW PHARMA 摘要:The present invention is directed to a new class of pyrrolidinone derivatives that are useful as chemical intermediates in the synthesis of S-allenyl and S-vinyl GABA, both of which are antiepileptic agents.
[参考文献]: Janarthanam Rathna, Et Al. Anti-Biofilm Mechanisms Of 3,5-Di-Tert-Butylphenol Against Clinically Relevant Fungal Pathogens. Biofouling. 2016 Oct;32(9):979-93. [参考文献]: Jian-Hua Chen, Et Al. Characterization Of Volatile Organic Compounds Emitted From Endophytic Burkholderia Cenocepacia Etr-B22 By Spme-Gc-Ms And Their Inhibitory Activity Against Various Plant Fungal Pathogens. Molecules. 2020 Aug 19;25(17):3765.
合成参考文献
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