CAS: 13799-90-1; 2,5-Dichloroterephthalic Acid

该化合物是磷酸的氯化衍生物,其特点是在苯环的2和5个位置替换氯原子,该化合物是有机合成中的宝贵中间体,特别是在生产特殊聚合物,染料和液晶材料方面,其二氯替代可增强交叉和凝聚反应的回活性和选择性,使其对量身定制分子设计有用.该化合物显示极地有机溶剂的热稳定性和溶性良好,便于将其纳入先进材料,其结构特性还有助于协调化学,并成为功能化芳香系统的一种前体.

结构式图片

相似化合物

46052-84-0 1897-43-4 1967-31-3

欧盟法规

ECHA物质C&L通报REACH预注册

上下游产品

2,5-Dichloro-P-Carboxybenzaldehyde 128230-05-7
二甲基2,5-二氯苯-1,4-二羧酸酯 Dimethyl 2,5-Dichloro-Terephthalate 3293-89-8
2-氨基-5-氯对苯二甲酸二甲酯 Dimethyl-2-Amino-5-Chloroterephthalate 32888-87-2

合成工艺路线路线简述

  • 合成目标产物 2,5-Dichloroterephthalic Acid 主要起始原料 2,5-Dichloro-P-Xylene
  • (文献来源)合成步骤主要原料 2,5-Dichloro-P-Xylene
2,5-Dichloro-P-Carboxybenzaldehyde置于sodium Hydroxide,Potassium Permanganate体系中,化学反应生成2,5-二氯对苯二甲酸
参考文献:Shcherbina,F. F.; Ral'Chuk,I. A.; Yazlovitskii,A. V.,Journal Of Applied Chemistry Of The Ussr,1990,Vol. 63,# 2.2,P. 445-448
标题:Shcherbina,F. F.; Ral'Chuk,I. A.; Yazlovitskii,A. V.,Journal Of Applied Chemistry Of The Ussr,1990,Vol. 63,# 2.2,P. 445-448

海关参考信息

专利信息


专利号:US-7943723-B2
优先权日:2006-12-21
标 题:Process for the synthesis of ethers of aromatic acids
发明人:RITTER JOACHIM C
权利人:DU PONT
摘要:The inventions disclosed herein include processes for the preparation of an ether of an aromatic acid, processes for the preparation of products into which such an ether can be converted, the use of such processes, and the products obtained and obtainable by such processes. A key feature of the processes described is the use of a solvent comprising an alcohol ROH and an alcoholate RO − M + .

专利号:US-8207374-B2
优先权日:2006-12-21
标 题:Process for the synthesis of ethers of aromatic acids
发明人:RITTER JOACHIM C
权利人:RITTER JOACHIM C; DU PONT
摘要:Ethers of aromatic acids are produced from halogenated aromatic acids in a reaction mixture containing a copper (I) or copper (II) source and a diketone ligand that coordinates to copper.

专利号:US-2011060118-A1
优先权日:2009-09-02
标 题:Process for the synthesis of fluorinated ethers of aromatic acids
发明人:RITTER JOACHIM C; MOLOY KENNETH GENE; POLLINO JOEL M; MAHAJAN DU SURBHI
权利人:DU PONT
摘要:Fluorinated ethers of aromatic acids are produced from halogenated aromatic acids in a reaction mixture containing a copper (I) or copper (II) source and a Schiff base ligand that coordinates to copper. The fluorinated ethers of aromatic acids made using the process described herein can be applied to, e.g., fibers, yarns, carpets, garments, films, molded parts, paper and cardboard, stone, and tile to impart soil, water and oil resistance. By incorporating the fluorinated ethers of aromatic acids, or diesters thereof, into polymer backbones, more lasting soil, water and oil resistance, as well as improved flame retardance, can be achieved.

专利号:US-7985825-B2
优先权日:2006-12-21
标 题 :Process for the synthesis of ethers of aromatic acids
发明人:RITTER JOACHIM C
权利人:DU PONT
摘要:Ethers of aromatic acids are produced from halogenated aromatic acids in a reaction mixture containing a halogenated aromatic acid such as is described by the structure of Formula II n nwherein each X is independently Cl, Br or I; the reaction mixture further comprising;n (i) a polar protic solvent, a polar aprotic solvent or an alcoholic solvent containing the alcoholate RO-M+ (wherein M is Na or K), wherein the polar protic solvent, polar aprotic solvent or alcoholic solvent is either ROH or is a solvent that is less acidic than ROH; (ii) a copper (I) or copper (II) source; and (iii) an amino acid ligand that coordinates to copper, wherein the ligand comprises an amino acid in which the amine nitrogen and the carboxyl carbon are separated by no more than two carbon atoms.

专利号:US-2011060117-A1
优先权日:2009-09-02
标题:Process for the synthesis of fluorinated ethers of aromatic acids
发明人:RITTER JOACHIM C; MOLOY KENNETH GENE; POLLINO JOEL M; MAHAJAN DU SURBHI
权利人:DU PONT
摘要:Fluorinated ethers of aromatic acids are produced from halogenated aromatic acids in a reaction mixture containing a copper (I) or copper (II) source and a diamine ligand that coordinates to copper. The fluorinated ethers of aromatic acids made using the process described herein can be applied to, e.g., fibers, yarns, carpets, garments, films, molded parts, paper and cardboard, stone, and tile to impart soil, water and oil resistance. By incorporating the fluorinated ethers of aromatic acids, or diesters thereof, into polymer backbones, more lasting soil, water and oil resistance, as well as improved flame retardance, can be achieved.

专利号:US-2011060161-A1
优先权日:2009-09-02
标题 :Process for the synthesis of fluorinated ethers of aromatic acids
发明人:RITTER JOACHIM C; MOLOY KENNETH GENE; POLLINO JOEL M; DU SURBHI MAHAJAN
权利人:DU PONT
摘要:Fluorinated ethers of aromatic acids are produced from halogenated aromatic acids in a reaction mixture containing a copper (I) or copper (II) source and a diketone ligand that coordinates to copper. The fluorinated ethers of aromatic acids made using the process described herein can be applied to, e.g., fibers, yarns, carpets, garments, films, molded parts, paper and cardboard, stone, and tile to impart soil, water and oil resistance. By incorporating the fluorinated ethers of aromatic acids, or diesters thereof, into polymer backbones, more lasting soil, water and oil resistance, as well as improved flame retardance, can be achieved.
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