CAS: 16184-89-7; 4'-Bromo-2,2,2-Trifluoroacetophenone

相似化合物

76911-73-4 80418-13-9 80418-12-8

上下游产品

CAS号431-47-0 三氟乙酸甲酯(TFAM) | CAS号106-37-6 对二溴苯 | CAS号80418-12-8 (R)-1-(4-溴苯基)-2... | CAS号383-63-1 三氟乙酸乙酯 | CAS号583-53-9 1,2-二溴苯 | CAS号81290-20-2 (三氟甲基)三甲基硅烷 | CAS号586-75-4 4-溴苯甲酰氯 | CAS号104863-67-4 N-甲氧基-N-甲基-2,2,... | CAS号340-07-8 1-三氟乙酰基哌啶 | CAS号58808-59-6 4-(三氟乙酰基)苯甲酸 | CAS号2369-31-5 4'-PHENYL-2,2,2... | CAS号80418-12-8 (R)-1-(4-溴苯基)-2... | CAS号85559-46-2 4-[3-(三氟甲基)-3H-... | CAS号1004294-77-2 2,2,2-Trifluoro... | CAS号173974-88-4 1-(4-bromopheny... | CAS号70783-32-3 4-苯氧基-2,2,2-三氟苯乙酮 | CAS号842169-72-6 1-(4-溴苯基)-2,2,2... | CAS号893407-18-6 2,2,2-三氟-1-(4'-... | CAS号62263-12-1 methyl 4-(2,2,2...

1-(4-溴苯基)-2,2,2-三氟乙醇置于2-碘酰基苯甲酸体系中,用 乙酸乙酯 用作溶剂,化学反应生成4'-溴-2,2,2-三氟苯乙酮
参考文献:用原位生成的芳基三氟甲基硝酮捕获芳烃能够获得三氟甲基化苯并恶唑啉
标题:用原位生成的芳基三氟甲基硝酮捕获芳烃能够获得三氟甲基化苯并恶唑啉
摘要:在此,我们报告了一个罕见的例子,利用原位生成的芳基三氟甲基硝酮捕获芳基,以获得一类重要的三氟甲基化苯并恶唑啉.这种三组分策略涉及硝酮形成/[3 + 2]环加成/热重排级联,并以高产率提供三氟甲基化苯并恶唑啉.对于芳基三氟重氮乙烷,亚硝基芳烃和芳烃,该反应的范围相当广泛.所提出的反应途径通过关键反应中间体苯基三氟甲基硝酮和苯并异恶唑啉的分离和表征得到支持.
Doi:10.1021/acs.Orglett.3C02895

专利信息

专利号:US-8957237-B2
优先权日:2011-12-19
标 题 :Method for the direct synthesis of alkylhalogenosilanes
发明人：ROSIER CÉCILE
权利人:BLUESTAR SILICONES FRANCE; BLUESTAR SILICONES FRANCE
摘要:An improved industrial method for the direct synthesis of alkylhalogenosilanes is described. Specifically, a method is described for preparing alkylhalogenosilanes by reacting, in a fluidized bed reactor, and alkyl halogenide, preferably CH3Cl, with a solid body, which is referred to as a contact body and which includes powdered silicon and a catalytic system including at least one copper catalyst and β1 and β2 promoter activities.

专利号:US-8030510-B2
优先权日:2005-06-22
标 题 :Process for the direct synthesis of alkylhalosilanes
发明人：COLIN PASCALE; GARCIA-ESCOMEL CRISTINA; MASTEAU JEAN-CLAUDE
权利人:RHODIA CHIMIE SA
摘要:Process for preparing alkylhalosilanes are provided. The process involve reacting an alkyl halide with a solid body formed of silicon and a catalytic system.

专利号:US-7154005-B2
优先权日:2004-09-09
标 题:Synthesis of alpha fluoroalkyl amines
发明人：O'SHEA PAUL; GOSSELIN FRANCIS
权利人:MERCK FROSST CANADA LTD
摘要:This invention describes the reaction of an alpha fluoroalkyl ketone with a bis(trialkylsilyl)amide to give a stable N-trialkylsilyl imine. Treatment of the N-trialkylsilyl imine with an alcohol leads to solvolysis of the trialkylsilyl group and yields a stable mixture of an aminal and an imine in high yield. Catalytic reduction of this mixture, or of the individual components, in the presence of a chiral catalyst leads to a fluoroalkyl amine with high enantioselectivity and high yield.

专利号:US-7202192-B2
优先权日:2002-12-09
标题 :Composite catalysts for the direct synthesis of alkylhalosilanes
发明人：COLIN PASCALE
权利人:RHODIA CHIMIE SA
摘要:The alkylhalosilanes are directly synthesized by reacting an alkyl halide with silicon in the presence of a catalytically effective amount of (α) a copper metal or a copper-based compound catalyst and (β) a catalyst promoter intermixture therefor which comprises an effective minor amount of an additive β1 selected from the group consisting of tin, a tin-based compound and mixture thereof, an effective minor amount of an additive β2 selected from the group consisting of cesium, potassium and rubidium, and compound and mixture thereof, and an effective minor amount of an additive β3 selected from the group consisting of the element phosphorus, a phosphorus-based compound and mixture thereof.

专利号:US-2017271563-A1
优先权日:2016-03-15
标题 :Method and apparatus for controlled semiconductor growth during synthesis of quantum dot materials
发明人：Durgan Chris; BERTRAM MATTHEW; CARILLO MATTHEW J; ARCHER PAUL
权利人:Durgan Chris; BERTRAM MATTHEW; CARILLO MATTHEW J; ARCHER PAUL
摘要:Techniques and mechanisms for synthesizing quantum dot structures. In an embodiment, a first reaction is performed to dissolve a precursor of a semiconductor material, wherein water is created as a by-product of the first reaction. Some or all of the water is removed and another chemical compound is added, wherein the chemical compound is a primary alcohol or a 1,2-diol. After the addition of the chemical compound, a second reaction is performed to grow at least some nanocrystalline portion of the quantum dot. In another embodiment, the chemical compound is 1,2-hexanediol, 1,2-dodecanediol or 1-octadecanol.

专利号:US-2005283018-A1
优先权日:2002-12-09
标题 :Composite catalysts for the direct synthesis of alkylhalosilanes