CAS: 106-46-7; 1,4-Dichlorobenzene

上下游产品

CAS号108-90-7 氯苯 | CAS号106-39-8 对氯溴苯 | CAS号1204518-00-2 (4-chlorophenyl... | CAS号106-37-6 对二溴苯 | CAS号106-47-8 对氯苯胺 | CAS号100-00-5 对硝基氯苯 | CAS号95-94-3 1,2,4,5-四氯苯 | CAS号122-01-0 4-氯苯甲酰氯 | CAS号7203-90-9 1-Triazene,1-(4... | CAS号106-50-3 对苯二胺 | CAS号10541-64-7 Methane,bis(2,5... | CAS号1078-97-3 1,4-亚苯基双(氯二甲基硅烷) | CAS号106022-00-8 2-(2,5-dichloro... | CAS号41464-42-0 2,3',5,5'四氯联苯 | CAS号38212-33-8 1-(4-氯苯基)哌嗪 | CAS号3367-54-2 Piperazine,1,4-... | CAS号38379-99-6 2,2'3,5',6-五氯联苯 | CAS号372-18-9 1,3-二氟苯 | CAS号352-33-0 对氯氟苯 | CAS号625-98-9 间氯氟苯

1,4-二溴苯置于trans-Bis(Glycinato)Copper(II) Monohydrate,四甲基氯化铵体系中,用 乙醇 用作溶剂,化学反应 24.0H,以90%的收率获得1,4-二氯苯
参考文献:甘氨酸铜(II)配合物是芳基和杂芳基溴化物向氯化物的芳族finkelstein反应的有效多相催化剂
标题:甘氨酸铜(II)配合物是芳基和杂芳基溴化物向氯化物的芳族finkelstein反应的有效多相催化剂
摘要:由氯化铜和甘氨酸轻松合成的甘氨酸铜(II)配合物1通过多种技术进行了表征,包括ftir,Xrd,Tga和sem分析.发现合成后的铜络合物是通过芳基和杂芳基溴化物的芳族finkelstein反应以高到极好的收率合成芳基和杂芳基氯化物的简单有效的催化剂.所开发的糖基铜(II)催化剂可轻松地从反应混合物中回收并成功重复使用数次,而不会降低催化效率.所开发的方法代表了使用非均相催化剂通过芳族finkelstein反应合成芳基和杂芳基氯化物的第一个实例.
Doi:10.1016/j.Apcata.2013.12.022

专利信息

专利号:US-11926589-B2
优先权日:2019-07-09
标 题 :Process for the synthesis of non-racemic cyclohexenes
发明人：REISMAN SARAH; ROMBOLA MICHAEL; LADD CAROLYN L; MCLAUGHLIN MARTIN JOHN; ZUEND STEPHAN; GOETZ ROLAND
权利人:BASF CORP; CALIFORNIA INST OF TECHN
摘要:This invention relates to a process for the synthesis of a non-racemic cyclohexene compound of formula (I) by a Diels-Alder reaction of a compound of formula (II) with a compound of formula (III) wherein R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 and Y have the meanings as defined in the description in the presence of a catalyst comprising at least one m-valent metal cation M m+ wherein the metal M is selected from Scandium (Sc), Yttrium (Y), Lanthanum (La), Cerium (Ce), Praseodymium (Pr), Neodymium (Nd), Promethium (Pm), Samarium (Sm), Europium (Eu), Gadolinium 15 (Gd), Terbium (Tb), Dysprosium (Dy), Holmium (Ho), Erbium (Er), Thulium (Tm), Ytterbium (Yb), Lutetium (Lu), Gallium (Ga) and Indium (In), and m is an integer of 1, 2 or 3, and a chiral ligand of the formula (IV) wherein R 10a , R 10b , R 10c , R 10d , R 10a′ , R 10b′ , R 10c′ , R 10d′ , Z and Z′ have the meanings as defined in the description.

专利号:US-8153839-B2
优先权日:2005-09-14
标题:Method for synthesis of keto acids or amino acids by hydration of acetylene compound
发明人：OGO SEIJI; FUKUZUMI SHUN-ICHI
权利人:OGO SEIJI; FUKUZUMI SHUN-ICHI; JAPAN SCIENCE & TECH AGENCY
摘要:An object of the present invention is to provide a method for synthesis of keto acids by hydration of an acetylene compound (acetylene-carboxylic acids) under mild conditions free from harmful mercury catalysts and a method for synthesis of amino acids from acetylene-carboxylic acids in a single container (one-pot or tandem synthesis). In one embodiment of the method according to the present invention for synthesis of keto acids, acetylene-carboxylic acids is hydrated in the presence of a metal salt represented by General Formula (1), n nwhere M 1 represents an element in Group VIII, IX, or X of the periodic table, and X 1 , X 2 , or X 3 ligand represents halogen, H 2 O, or a solvent molecule, and k represents a valence of a cation species, and Y represents an anion species, and L represents a valence of the anion species, and each of K and L independently represents 1 or 2, and k×m=L×n.

专利号:US-2008032964-A1
优先权日:2006-04-10
标题:Process for the synthesis of azetidinone
发明人：KANSAL VINOD K; AHMAD SUHAIL; MARIAPPAN SHANMUGAVEL; TYAGI BHUPENDRA; PERLMAN NURIT; LE PAIH JACQUES; ZANOTTI-GEROSA ANTONIO
权利人:KANSAL VINOD K; AHMAD SUHAIL; MARIAPPAN SHANMUGAVEL; TYAGI BHUPENDRA; PERLMAN NURIT; LE PAIH JACQUES; ZANOTTI-GEROSA ANTONIO
摘要:Provided are intermediates useful for the synthesis of hydroxyl-alkyl substituted azetidinones, processes of their preparation, and processes for the synthesis of certain hydroxyl-alkyl substituted azetidinones. Also provided are processes for the synthesis of 1-(4-fluorophenyl)-3(R)-[3-(4-fluorophenyl)-3(S)-hydroxypropyl]-4(S)-(4-hydroxyphenyl)-2-azetidinone, or ezetimibe.

专利号:US-2025002654-A1
优先权日:2023-06-22
标 题:Methods and applications for synthesis of carbazole phosphazene based polymer and recovery of valuable metal elements from electronic waste materials
发明人：SADAK ALI ENIS; CUCU EVREN; ARI ENGIN BETUL; TUNC MURAT; ALTUNDAS RAMAZAN
权利人:TURKIYE BILIMSEL VE TEKNOLOJIK ARASTIRMA KURUMU
摘要:A synthesis method for carbazole phosphazene based polymer and a method for the recovery of precious metal elements from electronic waste materials are provided. The developed method allows for the efficient and cost-effective synthesis of carbazole phosphazene based polymer in a single step, with high yield and easy purification. In the method for the recovery of precious metal elements from electronic waste materials, a two-step metal leaching process is employed using solutions with different acidity levels, resulting in the high-efficiency recovery of precious metal elements. The carbazole phosphazene based polymer represented by Formula 2 exhibits high selectivity in the adsorption of precious metal elements, particularly gold. Therefore, it can be applied in the recovery of gold and other precious metals from electronic waste materials in the method for the recovery of precious metal elements.

专利号:US-8569560-B2
优先权日:2006-10-13
标题 :Synthesis of terminal alkenes from internal alkenes via olefin metathesis
发明人：SCHRODI YANN; PEDERSON RICHARD L; KAIDO HIROKI; TUPY MICHAEL J
权利人:ELEVANCE RENEWABLE SCIENCES
摘要:This disclosure relates generally to olefin metathesis, and more particularly relates to the synthesis of terminal alkenes from internal alkenes using a cross-metathesis reaction catalyzed by an olefin metathesis catalyst. According to one aspect, for example, a method is provided for synthesizing a terminal olefin, the method comprising contacting, in the presence of a ruthenium alkylidene metathesis catalyst, an olefinic substrate comprised of at least one internal olefin with a cross metathesis partner comprised of an alpha olefinic reactant, under reaction conditions effective to allow cross-metathesis to occur, wherein the reaction conditions include a reaction temperature of at least 35° C. The methods, compositions, reactions and reaction systems herein disclosed have utility in the fields of catalysis, organic synthesis, and industrial chemistry.

专利号:US-9012625-B2
优先权日:2009-04-07
标 题 :Method for the synthesis of a trisaccharide
发明人：DÉKANY GYULA; Ã?GOSTON KÃ?ROLY; BAJZA ISTVAN; BOUTET JULIEN; BØJSTRUP MARIE; FANEFJORD METTE; PÉREZ FIGUEROA IGNACIO; HEDEROS MARKUS; HORVATH FERENC; KOVÃ?CS-PÉNZES PIROSKA; KRÖGER LARS; OLSSON JOHAN; RÖHRIG CHRISTOPH; SCHROVEN ANDREAS; VRASIDAS IOANNIS
权利人:DÉKANY GYULA; Ã?GOSTON KÃ?ROLY; BAJZA ISTVAN; BOUTET JULIEN; BØJSTRUP MARIE; FANEFJORD METTE; PÉREZ FIGUEROA IGNACIO; HEDEROS MARKUS; HORVATH FERENC; KOVÃ?CS-PÉNZES PIROSKA; KRÖGER LARS; OLSSON JOHAN; RÖHRIG CHRISTOPH; SCHROVEN ANDREAS; VRASIDAS IOANNIS; GLYCOM AS
摘要:The present invention relates to an improved synthesis of a trisaccharide of the formula (1), novel intermediates used in the synthesis and the preparation of the intermediates.