CAS: 569-51-7; Benzene-1,2,3-Tricarboxylic Acid

该化合物是一种芳香三色三色酸,其特点是附于苯环的三色三色基酸,典型的是一种在室温下结晶的白色晶体,可溶于水,由于存在多种碳二烯酸组,该化合物具有极性,反映了它的极性,其溶点因纯度和形式而异,其形成酯类和氢化物的能力也各不相同,它有助于合成各种聚合物和催化剂.由于树脂,涂层和粘合剂的活性能和增强材料特性的能力,它也被用于生产树脂,涂层和粘合剂.此外,它可以作为有机合成的建筑块,并研究其在制药和农用化学化学品中的潜在用途.安全考虑包括谨慎处理它,因为它可能会对皮肤和眼睛造成刺激.

结构式图片

欧盟法规

ECHA物质C&L通报REACH预注册

上下游产品

1,8-Naphthalic anhydride 1,6-dimethylnaphthalene 1,2,3-trimethylbenzene fluoranthene benzene-1,2,3-tricarboxylic acid trimethyl ester benzene-1,2,3-tricarboxylic acid-1,3-dimethyl ester 5-nitro-1,2,3-benzenetricarboxylic acid Chinizarin-5-carbonsaeure (5,8-Dihydroxy-anthrachinon-1-carbonsaeure)

合成工艺路线路线简述

  • 93-03-8 + 90-05-1 + 121-34-6 + 121-33-5 + 498-00-0 + 91-10-1 = 569-51-7 + 528-44-9 + 65-85-0 + 100-21-0 + 144-62-7 + 554-95-0 + 110-15-6
    反应条件:1.1R:O2,C:12293-21-9,Rt -> 160°C; 30 H,160°C,3 Mpa
    标题:A Combined Experimental And Theoretical Study On Vanadium-Catalytic Oxidation Of Lignin To Produce Carboxylic Acids
    作者:By Lu,Ting Et Al
    参考文献:Fuel Processing Technology 日期:2022 卷标:238 页码:107493
3-Dimethylhydrazonophthalic Anhydride置于水,硝酸体系中,化学反应 1.0H,反应生成 1,2,3-苯三甲酸
参考文献: Aromatic Compounds From Furanics[fr] Composés Aromatiques Dérivés Des Furaniques
标题: Aromatic Compounds From Furanics[fr] Composés Aromatiques Dérivés Des Furaniques
摘要:描述了一种从呋喃化合物通过与二烯醚反应制备酚,苯甲酸,酯和酐的方法,其中呋喃化合物与肼和/或肟反应,然后与二烯醚反应.

海关参考信息

专利信息


专利号:US-9763452-B2
优先权日:2012-06-11
标 题 :Synthesis of MOFs
发明人:MORRIS RUSSELL EDWARD; WHEATLEY PAUL STEWART; WARRENDER STEWART; DUNCAN MORVEN
权利人:UNIV COURT UNIV ST ANDREWS; UNIVERISTY COURT OF THE UNIV OF ST ANDREWS
摘要:The present invention relates to the synthesis of a variety of metal organic frameworks (MOFs) using low temperature and solvents which are considered to be not particularly harmful to the environment. There is also provided novel MOFs which may be made by the desired processes.

专利号:US-12263464-B2
优先权日:2018-03-14
标题 :Method for in-situ synthesis of metal organic frameworks (MOFs), covalent organic frameworks (COFs) and zeolite imidazolate frameworks (ZIFs), and applications thereof
发明人:PAHWA DEEPAK; PAHWA VARUN; CHOUDHARY ANIL KUMAR; SONIA; JHA VIVEK KUMAR; CHAUHAN ANJALI; YADAV ANNU
权利人:DESICCANT ROTORS INTERNATIONAL PRIVATE LTD
摘要:The present invention relates to a method for the in situ synthesis of of MOFs (metal organic frameworks), COFs (covalent organic frameworks), and ZIFs (Zeolitic imidazolate framework), onto and within different types of porous substrates, and their applications. The present invention provides a unique and easy to utilize method by which a number of MOFs, COFs and ZIFs can be synthesized directly onto and within a porous substrate with high performance efficiency ensuring higher grammage in formation of adsorbent product onto and within the substrate.

专利号:US-2022089618-A1
优先权日:2019-01-29
标题:Solid-State Synthesis Of Precursors Of Metal-Organic Frameworks
发明人:MAJANO GERARDO J; FALKOWSKI JOSEPH M
权利人:EXXONMOBIL RES & ENG CO
摘要:Metal-organic frameworks (MOFs) are highly porous entities comprising a multidentate ligand coordinated to multiple metal atoms, typically as a coordination polymer. MOFs are usually produced from a solvent in powder form under hydrothermal or solvothermal synthesis conditions. Alternately, powder-form precursors of MOFs may be formed by milling or mulling a substantially solid mixture of a metal salt and a multidentate organic ligand, optionally in the presence of a small amount of a solvent. The powder-form precursors may then undergo heating, typically in the absence of applied shear, to produce the corresponding MOF. Mulling may be differentiated from milling at least in that mulling applies to the substantially solid mixture at a non-constant pressure and milling applies a constant pressure while forming the powder-form precursor. In some cases, mulling may promote more effective formation of the powder-form precursor compared to milling.

专利号:US-11896947-B2
优先权日:2016-06-17
标题:System and process for continuous and controlled production of metal-organic frameworks and metal-organic framework composites
发明人:MOTKURI RADHA KISHAN; BONTHA JAGANNADHA R; MCGRAIL B PETER
权利人:BATTELLE MEMORIAL INSTITUTE
摘要:A MOF production system and method of making are detailed for continuous and controlled synthesis of MOFs and MOF composites. The system can provide optimized yields of MOFs and MOF composites greater than or equal to 95%.

专利号:US-10710971-B2
优先权日:2015-03-20
标题:Carbonate-promoted carboxylation reactions for the synthesis of valuable organic compounds
发明人:KANAN MATTHEW W; BANERJEE AANINDEETA
权利人:UNIV LELAND STANFORD JUNIOR; THE BOARD OF THE TRUSTEES OF THE LELAND STANFORD JUNIOR UNIV
摘要:A method for synthesizing a dicarboxylate containing an aromatic heterocycle is provided. A carboxylic acid containing a heterocycle is provided. A CO32− salt is provided to form a mixture, which converts the carboxylic acid containing an aromatic heterocycle to a carboxylate containing an aromatic heterocycle. CO2 gas is provided to the mixture. The mixture is heated to a temperature to at least partially melt the carboxylate containing an aromatic heterocycle.

专利号:US-10737239-B2
优先权日:2015-11-27
标题 :Ultrafast high space-time-yield synthesis of metal-organic frameworks
发明人:BURCKHART JULIA; MARX STEFAN; ARNOLD LENA; HOFMANN CLAUS; Müller Ulrich
权利人:BASF SE
摘要:The invention relates to a process for the preparation of metal-organic frameworks (MOFs) in form of a homogenous powder, and a process wherein the metal-organic framework is molded into shaped bodies.
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合成参考文献


参考文献:10.1107/s160053681101436x
摘要:Sun L, Qiu TR, Deng H. catena-Poly[[octaaquabis(μ4-benzene-1,3,5-tricarboxylato)trizinc] tetrahydrate]. Acta Crystallogr E Struct Rep Online. 2011 Apr 22;67(5):m630–1. doi: 10.1107/s160053681101436x.
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