5-Phenyl-1-(Tributylstannyl)Tetrazole置于盐酸,Sodium Hydroxide,甲基三苯氧基碘磷体系中,用 乙醇 作为反应溶剂,化学反应生成 2,4-二苯基咪唑 参考文献:A New Synthesis Of Imidazoles 标题:A New Synthesis Of Imidazoles 摘要:烯烃通过其环氧化物与2-三正丁基锡四氮唑(2)反应,随后采用改进的方法与三甲基苯氧基磷阳离子碘化物脱水,最后对所得的乙烯基四氮唑(4)进行光解,转化为咪唑. DOI:10.1039/c39820000714
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参考标题:Iedda Reaction Of The Molecular Iodine-Catalyzed Synthesis Of 1,3,5-Triazines Via Functionalization Of The Sp3 C-H Bond Of Acetophenones With Amidines: An Experimental Investigation And Dft Study 作者:Abhishek R. Tiwari,Shilpa R. Nath,Kaustubh A. Joshi,Bhalchandra M. Bhanage |发布日期:2017.12.15 摘要:Diels-Alder (Iedda)-Type Reaction To Synthesize 1,3,5-Trizines From Acetophenones And Amidines. The Use Of Molecular Iodine In A Catalytic Amount Facilitates The Functionalization Of The Sp3 C-H Bond Of Acetophenones. This Is A Simple And Efficient Methodology For The Synthesis Of 1,3,5-Triazines In Good To Excellent Yields Under Transition-Metal-Free And Peroxide-Free Conditions. The Reaction Is Believed To
合成参考文献
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