CAS: 139100-06-4; 2-Bromo-3-Dodecylthiophene

该化合物是一种溴化的硫苯衍生物,具有三点方位的多丁基侧链,该化合物主要用作合成同聚聚合物和有机半导体的关键中间体,特别是用于有机电子学的应用,如实地效应晶体管和光电装置.溴代基亚化物能够产生有效的交叉反应(如铃木或静态结合),便利受控聚合或功能化.多丁基链增加有机溶剂的溶性,改进薄膜沉积的可处理性.其明确界定的结构和再活性使它成为调整先进材料的光电子特性的宝贵建筑块.由于对水和空气的敏感性,该化合物通常在不热的条件下处理.

结构式图片

相似化合物

145543-83-5 69249-61-2 303734-52-3

欧盟法规

ECHA物质C&L通报

上下游产品

3-dodecylthiophene laurylmagnesium bromide 1-dodecylbromide 3,3-didodecyl-2,2′;5′,2″;5″,2-quaterthiophene 5,5'''-dibromo-3,3'''-bis(dodecyl)-2,2':5',2'':5'',2'''-quarterthiophene 58H78O6S4C58H78O6S4

合成工艺路线路线简述

    溴代十二烷置于n-溴代丁二酰亚胺(Nbs),1,3-Bis[(Diphenylphosphino)Propane]Dichloronickel(II),Magnesium体系中,用 四氢呋喃,N,N-二甲基甲酰胺 用作溶剂,化学反应生成2-溴-3-十二烷基噻吩
    参考文献:Synthesis Of Donor-acceptor Copolymer Using Benzoselenadiazole As Acceptor For Otft
    标题:Synthesis Of Donor-acceptor Copolymer Using Benzoselenadiazole As Acceptor For Otft
    摘要:合成的共聚物具有较低的能隙,并表现出约0.1 Cm2 V−1 S−1的空穴迁移率.
    Doi:10.1039/c5Ra23805F

    海关参考信息

    专利信息


    专利号:US-9328109-B2
    优先权日:2013-01-14
    标 题:Process for the preparation of benzohetero [1, 3] diazole compounds disubstituted with heteroaryl groups
    发明人:BIANCHI GABRIELE; PO' RICCARDO
    权利人:ENI SPA
    摘要:Process for the preparation of a benzohetero-[1,3]diazole compound disubstituted with brominated heteroaryl groups which comprises reacting at least one dihalogenated benzohetero[1,3]diazole compound with at least one brominated heteroaryl compound. Said benzohetero[1,3]diazole compound disubstituted with brominated heteroaryl groups can be advantageously used in the synthesis of compounds useful in the construction of solar concentrators (LSCs—“Luminescent Solar Concentratorsâ€?). Furthermore, said benzohetero[1,3]diazole compound disubstituted with brominated heteroaryl groups can be advantageously used in the synthesis of photoactive polymers useful in the construction of photovoltaic devices (or solar devices) such as, for example, photovoltaic cells (or solar cells), photovoltaic modules (or solar modules), on both rigid or flexible supports. Furthermore, said benzohetero[1,3]diazole compound disubstituted with brominated heteroaryl groups can be advantageously used as precursor of monomeric units in the synthesis of semiconductr polymers.

    专利号:CN-101213234-B
    优先权日:2005-04-01
    标 题:Living Synthesis of Conductive Polymers Including Regioregular Polymers, Polythiophenes and Block Copolymers

    专利号:CN-101213234-A
    优先权日:2005-04-01
    标题 :Living synthesis of conducting polymers including regioregular polymers, polythiophenes, and block copolymers

    专利号:CN-101402629-A
    优先权日:2008-11-19
    标 题 :Synthesis and uses of terthienyl and derivatives thereof

    专利号:US-7102017-B2
    优先权日:2004-06-10
    标 题 :Processes to prepare small molecular thiophene compounds
    发明人:LIU PING; WU YILIANG; ONG BENG S; BIRAU MARIA
    权利人:XEROX CORP
    摘要:A process composed of subjecting a reaction mixture comprising a reaction medium, a coupling agent, and a precursor to a coupling temperature to preferentially form a desired small molecular thiophene compound in a single-step synthesis, wherein the precursor consists of: (i) an optional divalent linkage, and (ii) a plurality of thiophene units, each thiophene unit being represented by structure (A) n nwherein each thiophene unit is bonded at either or both of the second ring position and the fifth ring position.
    濮阳惠成电子材料股份有限公司
    ⚠️ 未注册 · 未认证企业
    ⚠️ 该商家尚未完成注册及企业认证,请用户仔细辨别,谨慎交易。
    数据来源于公开网络搜索,平台未作核实,请自行辨别。
    🏢敬请 企业认领
    🏬开设公司展台
    📢获取免费会员权益
    🎖️点亮专属注册企业标签
    📇展现公司完整信息 样本查看立即注册认领 →
    网址: http://www.huichengchem.com
    企业联系电话:19638638286👤
    📞濮阳惠成电子材料股份有限公司 ⚠️参考联系方式
    联系人:张经理
    电话:19638638286
    手机:19638638286
    传真:0393-8961801
    邮箱:info@huichengchem.com
    通信地址: 河南省濮阳市胜利路西段
    邮编: 457001
    🆔 联系时候可告知是从"百琢研"平台获取的信息.
    ⚠️ 声明: 该企业未认证、未认领,请自行辨别信息的真实性和可靠性。咨询或交易时请注意风险评估与信息核实,百琢研不参与任何交易。企业认领注册入口→

    地址:河南省濮阳市胜利路西段
    ⚠️ 未注册 · 未认证企业
    注册入口 备注: 📌 数据来源说明:本展台内容基于各搜索引擎等公开数据整理,仅作展示用途。请用户自行辨别
    ✉️ 若企业需抹除展台内容或有异议, 请通过页面底部联系方式告知我们,我们会尽快处理。
    第 1 / 1 页
    现货

    供应商参考报价(招募中)

    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    合成参考文献


    参考文献:10.1055/s-0040-1719827
    摘要:Swager TM, Yoshinaga K. Revisiting the Heck Reaction for Fluorous Materials Applications. Synlett. 2021 Aug 20;32(17):1725–9. doi: 10.1055/s-0040-1719827.
    📝 需求与反馈
    尽可能描述清楚需求与问题信息
    ×

    通知