专利号:US-4468523-A 优先权日:1982-06-16 标题 :Synthesis of dialkyl oxalates by the heterogeneously catalyzed oxidative carbonylation of alcohols 发明人:LEONARD JOHN J; SOFRANKO JOHN A 权利人:ATLANTIC RICHFIELD CO 摘要:Synthesis of dialkyl oxalates by the oxidative carbonylation of liquid monohydric saturated alcohols of from 1 to 20 carbon atoms with carbon monoxide and oxygen or an oxygen-containing gas in the presence of a catalytic amount of a catalyst comprising palladium or a salt thereof in combination with vanadium in the oxide (V 2 O 5 , V 2 O 4 , V 2 O 3 ) form and titanium or a non-hydrolyzable salt thereof, said catalyst being present in a heterogeneous phase.
专利号:US-4451666-A 优先权日:1982-08-06 标题:Synthesis of oxalate esters by the oxidative carbonylation of alcohols with a heterogeneous manganese promoted Pd-V-P catalyst 发明人:SOFRANKO JOHN A; GAFFNEY ANNE M 权利人:ATLANTIC RICHFIELD CO 摘要:Synthesis of dialkyl oxalates by the heterogeneous catalyzed oxidative carbonylation of liquid monohydric saturated alcohols of from 1 to 20 carbon atoms with carbon monoxide and oxygen or an oxygen-containing gas in the presence of a catalytic amount of a catalyst comprising palladium or a salt thereof in combination with a crystalline vanadium-phosphorus-manganese containing compound.
专利号:US-9040444-B2 优先权日:2009-12-22 标 题:Semi continuous process for the synthesis of a catalyst for use in the manufacture of polyolefins 发明人:SINGALA KAMLESH; SINGH SAURABH; GUPTA VIRENDRAKUMAR 权利人:SINGALA KAMLESH; SINGH SAURABH; GUPTA VIRENDRAKUMAR; RELIANCE IND LTD 摘要:A semi-continuous process and system thereof, for the synthesis of a narrow particle size distribution Zeigler Natta procatalyst for use in the manufacture of polyolefins. The process comprises: (a) mixing a reaction mixture containing a titanium compound; (b) charging a first reactor with said reaction mixture; (c) removing excess reactants from said first reactor as a filtrate; (d) feeding said filtrate to at least one further reactor; and continuously removing excess reactants from said at least further reactor.
专利号:US-9605089-B2 优先权日:2010-07-12 标题 :Attrition resistant catalyst system for manufacture of polyolefins 发明人:GUPTA VIRENDRAKUMAR; SINGH SAURABH; JOSEPH JOMICHAN; SINGALA KAMLESH J; DESAI BHAVESH K 权利人:RELIANCE IND LTD 摘要:The present invention relates to regular shaped magnesium particles containing attrition resistant precursors and procatalysts thereof and processes for their synthesis and their use in the manufacture of polyolefins. More particularly, the present invention relates to a process for the synthesis of a said precursor particles which give highly active and improved surface area procatalysts for producing high bulk density polyolefin resins containing low fines and capable of incorporating high rubber content. In particular, the present invention relates to process for the synthesis of an attrition resistant precursors to prepare an attrition resistant Zeigler Natta procatalysts synthesized by using the precursors and to the polyolefin resin synthesized using the said procatalysts.
专利号:US-8835656-B2 优先权日:2012-01-30 标 题 :Linker and support for solid phase synthesis of nucleic acid 发明人:TSUKAMOTO MASAKI; SUZUKI NORITAKA; HAYAKAWA YOSHIHIRO; MAETA ERI; MORI KENJIRO; MINOMI KENJIRO 权利人:NITTO DENKO CORP; UNIV NAGOYA NAT UNIV CORP 摘要:The invention provides a universal linker capable of synthesizing nucleic acid having a hydroxy group at the 3′ terminal, a universal support carrying the linker, and a synthesis method of nucleic acid using the universal support. The linker contains a compound represented by the formula n nwherein each symbol is as defined in the specification.
专利号:US-5702928-A 优先权日:1994-07-18 标题 :Process for producing optically active triazole compounds and method of racemizing optically active triazole compounds 发明人:KAWADA NAOKI; YAMAZAKI NORITSUGU; IMOTO TAKAFUMI; IKURA KIYOSHI 权利人:DAICEL CHEM 摘要:PCT No. PCT/JP95/01416 Sec. 371 Date May 24, 1996 Sec. 102(e) Date May 24, 1996 PCT Filed Jul. 17, 1995 PCT Pub. No. WO96/02664 PCT Pub. Date Feb. 1, 1996A process for the asymmetric synthesis of a compound represented by general formula (II-R) easily at a low cost by using a lipase, and a process for producing a compound to be utilized in the above synthesis. (II-R)
[参考文献]: Fabrice Gritti, Et Al. Effect Of The Flow Rate On The Measurement Of Adsorption Data By Dynamic Frontal Analysis. J Chromatogr A. 2005 Mar 25;1069(1):31-42. [参考文献]: Mohammad Saraji, Et Al. Combined Hollow Fiber-Based Liquid-Liquid-Liquid Microextraction And In-Situ Differential Pulse Voltammetry To Improve Selectivity, Sensitivity, And Interference Elimination In Electrochemical Analysis. Talanta. 2010 Sep 15;82(4):1588-93. [参考文献]: Suvi-Katriina Ruokonen, Et Al. Effect Of Ionic Liquids On The Interaction Between Liposomes And Common Wastewater Pollutants Investigated By Capillary Electrophoresis. J Chromatogr A. 2015 Jul 31:1405:178-87.
合成参考文献
摘要:Yorimitsu, H.; Oshima, K., Science of Synthesis: Water in Organic Synthesis, (2012) 1, 646. 摘要:S13 | EUCOSMETICS | Combined Inventory of Ingredients Employed in Cosmetic Products (2000) and Revised Inventory (2006) | DOI:10.5281/zenodo.2624118 摘要:International Journal of Toxicology 31(Suppl.3):342-372, 2012 摘要:Ying, J.; Wu, X.-F., Science of Synthesis: Knowledge Updates, (2024) 1, 289.