CAS: 120-71-8; 2-Methoxy-5-Methylaniline

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CAS号77721-47-2 2-Methoxi-5-met... | CAS号104-93-8 4-甲基苯甲醚(MSO) | CAS号119-10-8 4-甲基-2-硝基苯甲醚 | CAS号106-43-4 对氯甲苯 | CAS号89-60-1 4-氯-3-硝基甲苯 | CAS号108-88-3 甲苯 | CAS号119-33-5 邻硝基对甲苯酚 | CAS号64-19-7 冰醋酸 | CAS号59741-04-7 2-甲氧基-5-甲基苯基异氰酸酯 | CAS号39522-26-4 6-甲基-2H-1,4-苯并噁... | CAS号40947-69-1 对克利西丁-对氨基苯磺酸偶合剂 | CAS号50597-88-1 3-碘-4-甲氧基甲苯 | CAS号88686-30-0 4-甲氧基-7-甲基苯并噻唑-2-胺 | CAS号25045-36-7 2-甲氧基-5-甲基苯甲酸 | CAS号88686-29-7 2-甲氧基-5-甲基苯基硫脲 | CAS号85968-72-5 乙酰乙酰克利西丁 | CAS号53078-70-9 2-甲氧基-5-甲基苯腈 | CAS号71058-34-9 4-(2-甲氧基-5-甲基苯基...

对甲苯甲醚置于吡啶,Tetra-N-Butylammonium Tetrakis(Pentafluorophenyl)Borate,三氟甲磺酸,哌啶体系中,用 二氯甲烷,乙腈 用作溶剂,化学反应 12.0H,以13%的收率获得2-甲氧基-5-甲基苯胺
参考文献:通过电化学生成的苄基氨基ulf离子进行的无金属苯甲胺ch胺化反应
标题:通过电化学生成的苄基氨基ulf离子进行的无金属苯甲胺ch胺化反应
摘要:在n-甲苯磺酰基二苯硫亚胺的存在下对甲苯衍生物进行电化学氧化,得到相应的苄基氨基离子,将其在非电解条件下用碘化四丁基铵处理,得到n-甲苯磺酰基苄基胺.该转变可作为无金属和化学氧化剂的苄基ch氨基化方法.由于n-甲苯磺酰基二苯硫亚胺具有很高的氧化潜能,因此本方法可用于从功能化的甲苯衍生物合成各种苄胺.
Doi:10.1002/chem.201604484

专利信息

专利号:US-7956169-B1
优先权日:2010-06-16
标题 :Synthesis of novel azo-dyes and their use in oligonucleotide synthesis
发明人：LAIKHTER ANDREI; SRIVASTAVA SURESH C; SRIVASTAVA NAVEEN P
权利人:CHEMGENES CORP
摘要:The invention provides a novel group of azo quencher compositions that are useful as quenchers of fluorescence and to methods for making and using them. The quenchers contain an azo bond and 1,3,3-trimethyl-2-methyleneindoline ring system. The quenchers can be derivatized to facilitate their conjugation to a variety of biologically relevant compounds, including lipids, nucleic acids, peptides, proteins, and the like.

专利号:WO-9108265-A1
优先权日:1989-12-02
标 题:Azo compounds and their use as dyes, 1-sulpho-6-carboxyl-amino naphthaline, its use as a diazo component and process for the production of these compounds
发明人：SPRINGER HARTMUT; HUSSONG KURT
权利人:HOECHST AG
摘要:The description relates to azo compounds corresponding to formula (1) below, having fibre-reactive properties and making valuable dyes. They can dye hydroxy and/or carbonamide group-containing synthetic and natural materials, especially fibre materials, like wool and especially cellulose fibre materials in bright colours. Formula (1) in which: M is hydrogen or a salt-forming metal like an alkaline metal; K is a residue of general formulae (2A) or (2B) in which: E is the residue of an intermediate component common in disazo dyes which can act as a coupling and as a diazo component, e.g. the residue of a 1-(aminophenyl) or -amino-naphthyl) pyrazolon, aminonaphthol, anilin or 1-amino naphthalin compound; v is the figure zero or 1; K is the residue of a water-soluble coupling component, preferably from the naphthol, aminonaphthol, anilin, pyrazolon, hydroxypyridon and acetoacetyl arylide series, whereby this coupling component contains 1 or 2 fibre-reactive groups of the vinyl sulphonate series; D is a benzol or naphthalin residue, whereby its substituents R?1 and R?2 are common ones in azo dyes, e.g. (besides hydrogen) lower alkyl, lower alkoxy, halogen, sulpho and carboxyl; the group -SO2?-Y is a fibre-reactive group of the vinyl sulphone series; a is the figure zero, 1 or 2; and k is the number 1 or 2. A description is also given of the compound 2-amino naphthaline-1-sulphonic acid-6-carboxylic acid which may be used as a pre-product in the production of dyes, e.g. as diazo component in the synthesis of dyes of general formula (1).

专利号:US-8119653-B2
优先权日:2006-07-07
标 题 :Belactosin derivatives as therapeutic agents/biological probes and their synthesis
发明人：ROMO DANIEL; CHO SUNG WOOK; SMITH JEFFREY W; RICHARDSON ROBYN D
权利人:ROMO DANIEL; CHO SUNG WOOK; SMITH JEFFREY W; RICHARDSON ROBYN D; TEXAS A & M UNIV SYS
摘要:Derivatives of belactosin and their synthesis are disclosed. In certain embodiments, compounds of the present invention exhibit anti-cancer, antiviral, antibiotic, and/or auto-immune therapeutic abilities. In general, methods of synthesis disclosed herein allow for introduction of a variety of substituents at numerous positions as well as the facile introduction of a beta-lactone ring moiety. The synthetic steps comprise, in preferred embodiments, a tandem Mukaiyama aldol lactonization reaction. Data demonstrating the utility of some of the derivatives as proteasome inhibitors is also disclosed.

专利号:US-4719053-A
优先权日:1980-08-01
标题 :Beta-chloroethylsulfonylmethyl-benzoic halides as intermediates
发明人：SCHLAEFER LUDWIG; HAEHNLE REINHARD
权利人:HOECHST AG
摘要:New beta -chloroethylsuflonylmethyl-benzoic acid halides which can serve as fibre-reactive anchors for thesynthesis of novel organic, water-soluble compounds, preferably dyestuffs, having fibre-reactive and fibre-finishing properties, such as preferably dyestuff properties, and containing, as a fibre-reactive group, one or two beta -chloroethylsufonylmethylbenzoic acid amide groups. For the synthesis of these novel fibre-finishing compounds, said new beta -chloroethylsulfonylmethyl-benzoic acid halide compounds are reacted with an organic, water-soluble compound having fibre-finishing properties and continuing one or two amino groups. Also precursors of the fibre-finishing, fibre-reactive compounds, containing said beta -chloroethylsulfonylmethyl-benzxoic acid amid grouping, can be employed for their synthesis. The novel fibre-finishing compounds can be applied onto suitable fibre materials, such as especially cellulose fibre material and natural or synthetic polyamide fibre materials, and fixed on these fibre materials in a manner similar to application and fixation methods usual in the technique for fibre-reactive compounds. The fibre-finished material, such as dyed material, shows very good wet fastnesses.

专利号:US-RE42890-E
优先权日:2003-05-23
标题 :Furazanobenzimidazoles
发明人：EBERLE MARTIN; BACHMANN FELIX; STREBEL ALESSANDRO; ROY SUBHO; SRIVASTAVA SUDHIR; SAHA GOUTAM
权利人:BASILEA PHARMACEUTICA AG
摘要:The invention relates to compounds of formula (I) wherein R represents aryl or heteroaryl, X is oxygen, a carbonyl group, an oxime derivative of a carbonyl group or an α,β-unsaturated carbonyl group, and the substituents R 1 to R 6 have the meanings given in the specification, for use as medicaments, to novel compounds of formula (I), to methods of synthesis of such compounds, to pharmaceutical compositions containing compounds of formula (I), to the use of a compounds of formula (I) for the preparation of a pharmaceutical composition for the treatment of neoplastic and autoimmune diseases, and to methods of treatment of neoplastic and autoimmune diseases using such compounds of formula (I) or of pharmaceutical compositions containing same

专利号:WO-0053313-A2
优先权日:1999-03-09
标 题:Lanthanide catalysts for synthesis of compounds and combinatorial libraries