99685-96-8 = 99685-96-8 反应条件:1.1 Reagents: Magnesium Catalysts: Titanocene Dichloride Solvents: Toluene,Tetrahydrofuran 标题:Preparation Of Bis(Diethylaluminum)[60]Fullerenes From Diethylaluminum Chloride And [60]Fullerene In Presence Of Magnesium And Titanocene Dichloride Catalyst 参考文献:Russian Federation
专利号:US-2020087149-A1 优先权日:2015-07-22 标 题 :Method for the synthesis of nanofluids 发明人:TALAEI ZEINAB; RASHIDI ALIMORAD; AMROLLAHI BIYOUKI AZADEH; MAHJOUB ALLREZA; LOTFI ROGHAYYEH; RASHTCHI MARYAM 权利人:RES INSTITUTE OF PETROLEUM INDUSTRY 摘要:The present invention relates to a method for the synthesis of nanofluids including functionalization of carbon nanostructures through a new method comprising the addition of carbon nanostructures to water; ultrasonication of the solution; addition of persulfate salt and one or several metal hydroxides of the first column of the periodic table to the aqueous solution containing carbon nanostructure; re-exposing the solution to ultrasonic waves; and then, the separation of the functionalized carbon nanostructures from the solution and washing the carbon nanostructures with water to neutralize them and mixing the nanoparticles obtained from the previous step with the fluid. By presenting a new method for the synthesis of the functionalized carbon nanostructures with specific amount of functional groups and their application in the synthesis of nanofluids, an increase in the stability and thermal conductivity of nanofluids takes place.
专利号:US-10954178-B1 优先权日:2020-08-28 标题 :Synthesis of haloindenes 发明人:WNUK STANISLAW F; HOWLADER MD ABU HASAN 权利人:WNUK STANISLAW F; HOWLADER MD ABU HASAN; THE FLORIDA INTERNATIONAL UNIV BOARD OF TRUSTEES 摘要:The subject invention provides an expedited synthesis of 5, 6, and 7-iodoindenes from the corresponding aminoindan-1-ones in more than 70% yield, employing readily available precursors and reagents. A three-step sequence involves diazotization-iodination of aminoindan-1-one followed by reduction and dehydration. The method has a general character and can be extended for the preparation of various 4-, 5-, 6- or 7-haloindenes using different halogen sources for diazotization-halogenation reaction.
专利号:US-7192567-B1 优先权日:1999-09-17 标题 :Precursor soot synthesis of fullerenes and nanotubes without formation of carbonaceous soot 发明人:REILLY PETER T A 权利人:UT BATTELLE LLC 摘要:The present invention is a method for the synthesis of fullerenes and/or nanotubes from precursor soot without the formation of carbonaceous soot. The method comprises the pyrolysis of a hydrocarbon fuel source by heating the fuel source at a sufficient temperature to transform the fuel source to a condensed hydrocarbon. The condensed hydrocarbon is a reaction medium comprising precursor soot wherein hydrogen exchange occurs within the reaction medium to form reactive radicals which cause continuous rearrangement of the carbon skeletal structure of the condensed hydrocarbon. Then, inducing dehydrogenation of the precursor soot to form fullerenes and/or nanotubes free from the formation of carbonaceous soot by continued heating at the sufficient temperature and by regulating the carbon to hydrogen ratio within the reaction medium. The dehydrogenation process produces hydrogen gas as a by-product. The method of the present invention in another embodiment is also a continuous synthesis process having a continuous supply of the fuel source. The method of the present invention can also be a continuous cyclic synthesis process wherein the reaction medium is fed back into the system as a fuel source after extraction of the fullerenes and/or nanotube products. The method of the present invention is also a method for producing precursor soot in bulk quantity, then forming fullerenes and/or nanotubes from the precursor bulk.
专利号:US-12209023-B2 优先权日:2017-01-25 标题:Low temperature, high yield synthesis of hydrogen terminated highly porous amorphous silicon, and nanomaterials and composites from Zintl phases 发明人:WAGNER MICHAEL J; BANEK NATHAN A 权利人:UNIV GEORGE WASHINGTON 摘要:The present disclosure relates to an improved process for the synthesis of hydrogen terminated silicon from Zintl phases. The hydrogen terminated silicon is useful, for example, as explosives, chemical and biochemical sensors, optoelectronic materials and Li-ion battery anode ion storage materials. The present disclosure also relates to an improved process for the synthesis of nanomaterials and composites from Zintl phases. The nanomaterials and composites are useful, for example, as ion storage materials.
专利号:US-2004062708-A1 优先权日:2000-10-10 标 题 :Process for the synthesis of nanotubes of transition metal dichalcogenides 发明人:REMSKAR MAJA; MRZEL ALES; SKRABA ZORA; MIHAILOVIC DRAGAN D; MUSEVIC IGOR 摘要:A process of the synthesis of nanotubes of transition metal dichalcogenides by chemical transport with the addition of fullerences is provided to obtain nanotubes of transistion metal dichalcogenides. The nanotubes are hexagonally arranged in form of needle-like bundles. The process comprises chemical transport, in which the fullerences exist in the vapour phase. The chemical fullerences are used at conditions, in which the fullerences exist in the vapour phase. The chemical transport reaction occurs in a quartz ampoule, sealed at a pressure lower than 0.66 Pa. The temperature in the hot part of the ampoule is higher than 830° C.
专利号:US-9676707-B2 优先权日:2015-02-18 标题 :Process for the synthesis of [6,6]-phenyl-C61butyric acid pentyl ester (PC61BP) 发明人:KUMAR RACHANA; NAQVI Samya; GUPTA NEHA; CHAND SURESH 权利人:COUNCIL SCIENT IND RES 摘要:A total green, eco-friendly process for the synthesis of new acceptor molecule [6,6]-phenyl-C 61 -butyric acid pentyl ester (PC61BP) in high yields is carried under aerobic conditions showing better performance as acceptor in organic solar cells. More importantly this process causes the low cost synthesis of PC61BP in good yield without involving harmful and costly catalysts or chemicals.
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合成参考文献
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