CAS: 99685-96-8; C60 Fullerene

该化合物是一个球分子,由60个碳原子组成,其结构类似于足球,由12个五角形和20个六角形面体组成.碳的光球具有独特的特性,包括高度稳定性,显著的电子亲近性以及作为半导体的能力.Fullene-C60在水中是无法溶解的,但在甲苯和苯等有机溶剂中是可溶解的.其分子结构允许将各种原子或分子封装起来,导致药物的交付,材料科学和纳米技术的潜在应用.此外,它展示了有趣的光学特性,使它成为光学和光伏研究的课题.Fulleen-C60还展示了抗氧化性特性,这些特性对生物系统有影响.由于其独特的特性,它在科学研究和潜在的商业应用方面引起了极大兴趣,尽管其生产和使用必须受到环境和健康方面的考虑的认真管理.

结构式图片

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上下游产品

PERYLENE 60-Ih-[1,9-d]isoxazole3'-[4-(phenylmethoxy)phenyl][5,6]fullereno-C60-Ih-[1,9-d]isoxazole60-Ih)[5,6]fullerene-3′-carboxylateethyl 3′H-cyclopropa[1,9](C60-Ih)[5,6]fullerene-3′-carboxylate 60-Ih)[5,6]fullerene-3′-carboxylatetert-butyl 3′H-cyclopropa[1,9](C60-Ih)[5,6]fullerene-3′-carboxylate 75H10FNO3C75H10FNO3

合成工艺路线路线简述

  • 99685-96-8 = 99685-96-8
    反应条件:1.1 Reagents: Magnesium Catalysts: Titanocene Dichloride Solvents: Toluene,Tetrahydrofuran
    标题:Preparation Of Bis(Diethylaluminum)[60]Fullerenes From Diethylaluminum Chloride And [60]Fullerene In Presence Of Magnesium And Titanocene Dichloride Catalyst
    参考文献:Russian Federation
(Ammonia)6(Lithium)3C60 以 Neat (No Solvent) 作为反应溶剂,化学反应生成 足球烯
参考文献:扩大的富勒分子和电子定位-富锂氨化c(60)相.
标题:扩大的富勒分子和电子定位-富锂氨化c(60)相.
摘要:讨论了具有由锂配位的氨配体组成的复合抗衡离子的碱金属富勒酸盐的合成和表征.以身体为中心的立方堆积以及随之而来的低密度的富勒阴离子产生了富勒阴离子的t(1U)外电子局部化.x = 3和5个成员的电子行为证明了这一点,后者代表了对每个阴离子含5个电子的局域电子富勒离子的电子行为的首次详细研究.
DOI:10.1039/b402817A

专利信息


专利号:US-2020087149-A1
优先权日:2015-07-22
标 题 :Method for the synthesis of nanofluids
发明人:TALAEI ZEINAB; RASHIDI ALIMORAD; AMROLLAHI BIYOUKI AZADEH; MAHJOUB ALLREZA; LOTFI ROGHAYYEH; RASHTCHI MARYAM
权利人:RES INSTITUTE OF PETROLEUM INDUSTRY
摘要:The present invention relates to a method for the synthesis of nanofluids including functionalization of carbon nanostructures through a new method comprising the addition of carbon nanostructures to water; ultrasonication of the solution; addition of persulfate salt and one or several metal hydroxides of the first column of the periodic table to the aqueous solution containing carbon nanostructure; re-exposing the solution to ultrasonic waves; and then, the separation of the functionalized carbon nanostructures from the solution and washing the carbon nanostructures with water to neutralize them and mixing the nanoparticles obtained from the previous step with the fluid. By presenting a new method for the synthesis of the functionalized carbon nanostructures with specific amount of functional groups and their application in the synthesis of nanofluids, an increase in the stability and thermal conductivity of nanofluids takes place.

专利号:US-10954178-B1
优先权日:2020-08-28
标题 :Synthesis of haloindenes
发明人:WNUK STANISLAW F; HOWLADER MD ABU HASAN
权利人:WNUK STANISLAW F; HOWLADER MD ABU HASAN; THE FLORIDA INTERNATIONAL UNIV BOARD OF TRUSTEES
摘要:The subject invention provides an expedited synthesis of 5, 6, and 7-iodoindenes from the corresponding aminoindan-1-ones in more than 70% yield, employing readily available precursors and reagents. A three-step sequence involves diazotization-iodination of aminoindan-1-one followed by reduction and dehydration. The method has a general character and can be extended for the preparation of various 4-, 5-, 6- or 7-haloindenes using different halogen sources for diazotization-halogenation reaction.

专利号:US-7192567-B1
优先权日:1999-09-17
标题 :Precursor soot synthesis of fullerenes and nanotubes without formation of carbonaceous soot
发明人:REILLY PETER T A
权利人:UT BATTELLE LLC
摘要:The present invention is a method for the synthesis of fullerenes and/or nanotubes from precursor soot without the formation of carbonaceous soot. The method comprises the pyrolysis of a hydrocarbon fuel source by heating the fuel source at a sufficient temperature to transform the fuel source to a condensed hydrocarbon. The condensed hydrocarbon is a reaction medium comprising precursor soot wherein hydrogen exchange occurs within the reaction medium to form reactive radicals which cause continuous rearrangement of the carbon skeletal structure of the condensed hydrocarbon. Then, inducing dehydrogenation of the precursor soot to form fullerenes and/or nanotubes free from the formation of carbonaceous soot by continued heating at the sufficient temperature and by regulating the carbon to hydrogen ratio within the reaction medium. The dehydrogenation process produces hydrogen gas as a by-product. The method of the present invention in another embodiment is also a continuous synthesis process having a continuous supply of the fuel source. The method of the present invention can also be a continuous cyclic synthesis process wherein the reaction medium is fed back into the system as a fuel source after extraction of the fullerenes and/or nanotube products. The method of the present invention is also a method for producing precursor soot in bulk quantity, then forming fullerenes and/or nanotubes from the precursor bulk.

专利号:US-12209023-B2
优先权日:2017-01-25
标题:Low temperature, high yield synthesis of hydrogen terminated highly porous amorphous silicon, and nanomaterials and composites from Zintl phases
发明人:WAGNER MICHAEL J; BANEK NATHAN A
权利人:UNIV GEORGE WASHINGTON
摘要:The present disclosure relates to an improved process for the synthesis of hydrogen terminated silicon from Zintl phases. The hydrogen terminated silicon is useful, for example, as explosives, chemical and biochemical sensors, optoelectronic materials and Li-ion battery anode ion storage materials. The present disclosure also relates to an improved process for the synthesis of nanomaterials and composites from Zintl phases. The nanomaterials and composites are useful, for example, as ion storage materials.

专利号:US-2004062708-A1
优先权日:2000-10-10
标 题 :Process for the synthesis of nanotubes of transition metal dichalcogenides
发明人:REMSKAR MAJA; MRZEL ALES; SKRABA ZORA; MIHAILOVIC DRAGAN D; MUSEVIC IGOR
摘要:A process of the synthesis of nanotubes of transition metal dichalcogenides by chemical transport with the addition of fullerences is provided to obtain nanotubes of transistion metal dichalcogenides. The nanotubes are hexagonally arranged in form of needle-like bundles. The process comprises chemical transport, in which the fullerences exist in the vapour phase. The chemical fullerences are used at conditions, in which the fullerences exist in the vapour phase. The chemical transport reaction occurs in a quartz ampoule, sealed at a pressure lower than 0.66 Pa. The temperature in the hot part of the ampoule is higher than 830° C.

专利号:US-9676707-B2
优先权日:2015-02-18
标题 :Process for the synthesis of [6,6]-phenyl-C61butyric acid pentyl ester (PC61BP)
发明人:KUMAR RACHANA; NAQVI Samya; GUPTA NEHA; CHAND SURESH
权利人:COUNCIL SCIENT IND RES
摘要:A total green, eco-friendly process for the synthesis of new acceptor molecule [6,6]-phenyl-C 61 -butyric acid pentyl ester (PC61BP) in high yields is carried under aerobic conditions showing better performance as acceptor in organic solar cells. More importantly this process causes the low cost synthesis of PC61BP in good yield without involving harmful and costly catalysts or chemicals.
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主要参考文献

[参考文献]: D Franskevych,Et Al. Fullerene C 60 Penetration Into Leukemic Cells And Its Photoinduced Cytotoxic Effects. Nanoscale Res Lett.2017 Dec;12(1):40.
[参考文献]: Atsushi Ikeda, Et Al. Nmr Spectroscopic Study Of The Complexation Behaviors Of Deuterated Cyclodextrins And [参考文献]: Boris Jovanovi, Et Al. Histopathology Of Fathead Minnow (Pimephales Promelas) Exposed To Hydroxylated Fullerenes. Nanotoxicology. 2014 Nov;8(7):755-63.
[参考文献]: Chun Zhang, Et Al. Supramolecular Gel-Assisted Formation Of Fullerene Nanorods. Chemistry. 2012 Nov 19;18(47):14954-6.
[参考文献]: Jason W Kelsey, Et Al. Effect Of C60 Fullerenes On The Accumulation Of Weathered P,P'-Dde By Plant And Earthworm Species Under Single And Multispecies Conditions. Environ Toxicol Chem. 2013 Apr;32(5):1117-23.

合成参考文献


参考文献:10.1021/jp203420m
摘要:Ziehlke H, Fitzner R, Koerner C, Gresser R, Reinold E, Bäuerle P, Leo K, Riede MK. Side chain variations on a series of dicyanovinyl-terthiophenes: a photoinduced absorption study. J Phys Chem A. 2011 Aug 04;115(30):8437–46. doi: 10.1021/jp203420m.
参考文献:10.1186/1556-276x-6-452
摘要:Zarenia M, Pereira JM, Peeters FM, de Aquino Farias G. Topological confinement in an antisymmetric potential in bilayer graphene in the presence of a magnetic field. Nanoscale Research Letters. 2011 Jul 14;6(1):452. doi: 10.1186/1556-276x-6-452.
参考文献:10.1007/s00894-011-1158-5
摘要:Sheka EF. Computational synthesis of C60 cyano- and azopolyderivatives. Journal of Molecular Modeling. 2011 Jul 15;18(4):1409–20. doi: 10.1007/s00894-011-1158-5.
参考文献:10.1021/nn201331n
摘要:Ratnikova TA, Nedumpully Govindan P, Salonen E, Ke PC. In VitroPolymerization of Microtubules with a Fullerene Derivative. ACS Nano. 2011 Jul 25;5(8):6306–14. doi: 10.1021/nn201331n.
参考文献:10.1016/j.tox.2011.06.015
摘要:Manzetti S. Quantum toxicology--a potential perspective in toxicology Toxicology. 2011 Oct 09;288(1-3):56–7. doi: 10.1016/j.tox.2011.06.015.
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