专利号:US-5239052-A 优先权日:1990-08-30 标 题 :Process for synthesis of aromatic sulfides 发明人:HAY ALLAN S; WANG ZHI Y 权利人:HAY ALLAN S; WANG ZHI Y 摘要:Aromatic sulfides including diarylsulfides and poly(arylene sulfides) are produced in a novel synthesis in high yield under moderate conditions by heating an aromatic disulfide in the presence of aromatic halide, in which the halide is chloride, bromide or iodide; the diaryl sulfides are useful precursors and starting materials for a range of compounds and the poly(arylene sulfides) are important high temperature engineering thermoplastics.
专利号:US-5177183-A 优先权日:1990-08-30 标 题:Process for synthesis of aromatic sulfides 发明人:HAY ALLAN S; WANG ZHI Y 权利人:HAY ALLAN S; WANG ZHI Y 摘要:Aromatic sulfides including diarylsulfides and poly(arylene sulfides) are produced in a novel synthesis in high yield under moderate conditions by heating an aromatic disulfide in the presence of aromatic halide, in which the halide is chloride, bromide or iodide; the diaryl sulfides are useful precursors and starting materials for a range of compounds and the poly(arylene sulfides) are important high temperature engineering thermoplastics.
专利号:US-5001271-A 优先权日:1988-04-14 标题 :Synthesis of benzyl mercaptan 发明人:LABAT YVES 权利人:ELF AQUITAINE 摘要:This invention relates to the preparation of benzyl mercaptan by reacting benzyl chloride and ammonium sulfhydrate. n In the process according to the invention, the reaction is carried out under autogenous pressure in a closed reactor in two steps. The first comprises adding the benzyl chloride to an aqueous solution of ammonium sulfhydrate at a temperature below 80° C. The second comprises heating the reaction mixture to a temperature in the range 80° to 100° C.
专利号:EP-0704432-B1 优先权日:1994-09-29 标题 :Process for the preparation of asymmetric disulphides 发明人:HIVER PATRICIA NATHALIE; SCHWENDIMANN CHRISTIAN RENE; DICKO AMADOU; PAQUER DANIEL ANDRE 权利人:LORRAINE LAMINAGE 摘要:Synthesis of dissymmetric disulphides of formula R-S-S-R' (V) comprising: (i) preparing a cpd. of formula R'-Br (II) from a cpd. of formula R-'H (I); (ii) reacting (II) with sodium thiosulphate to form a salt of formula R'S2O3<->Na<+> (III); and (iii) reacting (III) with a thiolate deriv. of formula RS<->K<+> (IV) to form (V), is characterised in that step (ii) is effected in dimethyl-sulphoxide. R, R' = optionally substituted hydrocarbyl.
专利号:US-11850579-B2 优先权日:2017-07-05 标题 :Catalysts for polyesterol synthesis 发明人:RUEBENACKER MARTIN; ZARBAKHSH SIRUS 权利人:BASF SE 摘要:This invention relates to catalysts for polyesterol synthesis and the use of a di-thio compound as catalyst for the production of polyester-polyols.
专利号:JP-2020525635-A 优先权日:2017-07-05 标 题:Catalyst for synthesis of polyesterol
[参考文献]: Homan Kang, Et Al. Direct Identification Of On-Bead Peptides Using Surface-Enhanced Raman Spectroscopic Barcoding System For High-Throughput Bioanalysis. Sci Rep. 2015 May 28:5:10144.
合成参考文献
摘要:Koutentis, P. A.; Ioannidou, H. A., Science of Synthesis Knowledge Updates, (2010) 1, 358. 摘要:Witt, D., Science of Synthesis Knowledge Updates, (2011) 3, 258. 摘要:Łyżwa, P., Science of Synthesis Knowledge Updates, (2011) 2, 470. 摘要:Inamoto, K., Science of Synthesis: Cross Coupling and Heck-Type Reactions, (2012) 2, 434. 摘要:Kaneda, K.; Mitsudome, T., Science of Synthesis: Catalytic Reduction in Organic Synthesis, (2017) 1, 351.