CAS: 4207-56-1; Mono(N,N,N-Trimethylbenzenaminium) Tribromide

该化合物是一种四硝基铵盐,其特点是三甲基苯丙胺和三溴离子的酸性结构,其特点是三甲基苯丙胺和三溴离子.这种化合物一般是白色的,是白色的,是白色的,可溶于水和酒精等极地溶剂中.它具有合金特性,意味着它可以吸收空气中的湿气. 溴离子的存在表明有机合成中可能应用,特别是用作溴化剂.此外,由于其四硝基铵结构,它可能具有表面活性特性,因而在各种配方中有用.安全考虑包括谨慎处理它,因为四硝基铵化合物可以是刺激剂,并可能对环境造成危害.

英文名称Mono(N,N,N-Trimethylbenzenaminium) Tribromide
中文名称苯基三甲基三溴化铵
IUPAC名称Mono(N,N,N-trimethylbenzenaminium) tribromide
其它别名苯基三甲基三溴化胺; 三甲基苯基三溴化铵; Trimethylphenylammonium Tribromide
CAS编号4207-56-1
MFCD编号:MFCD00011789
EINECS号:224-127-8
FDA UNII编号:9V4E7J2MSS
分子式:C9H14Br3N
分子量:375.93
产品CID: 1434228
产品分类有机原料→分子砌块→芳环类化合物→苯类化合物

相似结构搜索
产品信息参考;;;;
InChIKey: PRXNKYBFWAWBNZ-UHFFFAOYSA-N
InChI=1S/C9H14N.Br3/c1-10(2,3)9-7-5-4-6-8-9;1-3-2/h4-8H,1-3H3;/q+1;-1…
计算化学: 氢键受体数1.0氢键供体数0.0可旋转键数1.0

MSDS等安全信息

GHS象形图
GHS符号GHS05;
注释: Corrosion
危险类别皮肤腐蚀类别1C
皮肤腐蚀类别1B
严重眼损伤类别1
警示词Danger(危险)
危险描述H314 |造成严重皮肤灼伤和眼损伤.
H318 |造成严重眼损伤.
防范说明P260-P264-P280-P301+P330+P331-P304+P340-P363-P405-P501
危险等级8
UN编号3261.0
危险品标志C
包装等级Ⅱ
安全声明26-36/37/39-45-24/25
危险类别码34-37
WGK Germany3

欧盟法规

REACH注册C&L通报REACH预注册

上下游产品

N,N,N-trimethylanilinium bromide N,N-dimethyl-anilineN,N-dimethyl-aniline dimethyl sulfate methyl bromideN,N,N-trimethylanilinium bromide 3-benzoyloxy-ω-bromoacetophenone (E)-2-bromo-1-[2-(2-nitrostyryl)-1-(phenylsulfonyl)-1H-indol-3-yl]-ethanone

合成工艺路线路线简述

合成目标产物 Phenyltrimethylammonium Tribromide 主要起始原料 Phenyltrimethylammonium Bromide
(文献来源)合成步骤主要原料 Phenyltrimethylammonium Bromide

专利信息

专利号:EP-0842924-B1
优先权日:1996-11-14
标题 :Pyridine intermediates, useful in the synthesis of beta-adrenergic receptor agonists
发明人：WRIGHT STEPHEN WAYNE
权利人:PFIZER
摘要:The present invention relates to certain compounds of the formula (I), which are useful in the synthesis of certain beta -adrenergic receptor agonists. The invention also relates to a process for synthesizing the compounds of formula (I) and to compounds of the formula (II), wherein R<1>, R<2> and R<4> are defined herein, which are useful in the synthesis of the compounds of formula (I). The invention also relates to a process for synthesizing a compound of formula (II). The invention further relates to processes for synthesizing compounds of formula (Z*), R<1>, R<2> and Y<2*> are defined herein.o

专利号:US-2005192445-A1
优先权日:2004-03-01
标题:Semi-synthesis of taxane intermediates and aziridine analogues and their conversion to paclitaxel and docetaxel
发明人：NAIDU RAGINA
权利人:PHYTOGEN LIFE SCIENCES INC
摘要:A process is provided for the semi-synthesis of taxane intermediates and aziridine analogues of cephalomannne and baccatin III intermediates, and the conversion of such intermediates and analogues to paclitaxel and docetaxel.

专利号:US-11512062-B2
优先权日:2018-10-15
标题:Process for the synthesis of piperazinyl-ethoxy-bromophenyl derivates and their application in the production of compounds containing them
发明人：BEAUREGARD LOUIS-PHILIPPE; BERTRAND MARTIAL; GIGUERE PASCALL; HARDOUIN CHRISTOPHE; SCHIAVI BRUNO
权利人:SERVIER LAB
摘要:Process for the industrial synthesis of the compound of formula (I):

专利号:US-7585986-B2
优先权日:2004-02-24
标题 :Semi-synthesis of taxane intermediates and aziridine analogues and their conversion to paclitaxel and docetaxel
发明人：NAIDU RAGINA
权利人:CHATHAM BIOTEC LTD
摘要:A process is provided for the semi-synthesis of taxane intermediates and aziridine analogues of cephalomannine and baccatin III intermediates, and the conversion of such intermediates and analogues to paclitaxel and docetaxel.

专利号:US-2003032817-A1
优先权日:2001-05-15
标题:Process for the synthesis of oxandrolone
发明人：CABAJ JOHN E; KAIRYS DAVID L; ZIZELMAN PAUL M
摘要:A process is disclosed for synthesizing oxandrolone 1 involving the bromination of compound 2 to obtain compound 3, followed by the highly selective de-bromination of compound 3 to obtain compound 4, followed by the oxidation of compound 4 to obtain compound 6, and finally the reduction of compound 6 to obtain oxandrolone 1.

专利号:US-6958145-B2
优先权日:2000-06-28
标题:Synthesis of cyclic compounds
发明人：KUMAR NARESH; READ ROGER WAYNE
权利人:UNISEARCH LTD
摘要:A method for the preparation of a compound of formula (II) wherein R 1 and R 2 are independently H, alkyl, alkoxy, oxoalkyl, alkenyl, aryl or arylalkyl whether unsubstituted or substituted, optionally interrupted by one or more hetero atoms, straight chain or branched chain, hydrophilic, hydrophobic or fluorophilic; R 3 , R 4 , R 5 and R 6 are independently or all hydrogen or halogen; provided that at least two of the R 3 , R 4 , R 5 and R 6 are halogens.

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主要参考文献

1: Kaluđerović LM, Tomić ZP, Ašanin DP, Đurović-Pejčev RD, Kresović BJ. Examination of the influence of phenyltrimethylammonium chloride (PTMA) concentration on acetochlor adsorption by modified montmorillonite. J Environ Sci Health B. 2018 Apr
30:1-7. doi: 10.1080/03601234.2018.1462930. [Epub ahead of print] doi: 10.1016/j.ijbiomac.2018.04.064. [Epub ahead of print] doi: 10.1016/j.carbpol.2017.04.024. Epub 2017 Apr 14. doi: 10.1021/acs.est.7b01277. Epub 2017 May 10. doi: 10.1016/j.jchromb.2017.01.047. Epub 2017 Feb 1. doi: 10.1021/acs.est.6b01733. Epub 2016 Jul 19. doi: 10.1002/anie.201511197. Epub 2016 Jan 28. doi: 10.1021/acs.analchem.5b01077. Epub 2015 Jul 22. doi: 10.1021/mp500807k. Epub 2015 May 18. doi: 10.1007/s11356-014-3656-3. Epub 2014 Oct 3. doi: 10.1159/000353534. Epub 2013 Sep 5.
12: Fraser D, DeRoo CS, Cody RB, Armitage RA. Characterization of blood in an encrustation on an African mask: spectroscopic and direct analysis in real time mass spectrometric identification of haem. Analyst. 2013 Aug 21;138(16):4470-4. doi: 10.1039/c3an00633f. Epub 2013 Jun 18. doi: 10.1007/s10162-012-0347-y. Epub 2012 Sep 12.

合成参考文献

参考文献:10.1007/s11030-018-9829-0
摘要:Akhtar R, Naqvi SAR, Zahoor AF, Saleem S. Nucleophilic ring opening reactions of aziridines. Mol Divers. 2018 May;22(2):447–501. doi: 10.1007/s11030-018-9829-0.

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CAS: 4207-56-1; Mono(N,N,N-Trimethylbenzenaminium) Tribromide

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上下游产品

合成工艺路线路线简述

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