甲醇,甲基丙烯酸丙基三氯硅烷 反应生成3-(异丁烯酰氧)丙基三甲氧基硅烷 参考文献:Some Regularities Of Chlorosilanes Etherification 标题:Some Regularities Of Chlorosilanes Etherification 摘要:The Influence Of Reagents,Solvent Polarity,And Temperature On The Etherification Of Chlorosilanes Clch2Sicl3,Vinsicl(3),Prsicl3,And Ph3Sicl With Ethanol Was Studied. Influence Of Reaction Temperature On The Ratio Of The Synthesized Alkoxysilane And Related Side-Product Siloxane Is Revealed. Use Of Excess Alcohol Is Shown To Increase The Content Of Siloxane. Introduction Of Fecl3 Does Not Affect The Synthesis. Solvents Are Shown To Influence The Reaction Rate: The Rate Constant Increases With Increasing Epsilon Parameter Of The Solvent. The Rate Constant Of Etherification Of Chlorosilanes With Ethanol Falls In The Series: Clch2Sicl3 > Vinsicl(3) > Prsicl3. An Explanation Of The Regularities Is Suggested. Doi:10.1134/s1070363209080118
专利号:US-7705136-B2 优先权日:2005-02-25 标 题 :Synthesis of 3′-, or 5′-, or internal methacrylamido-modified oligonucleotides 发明人:GOLOVA JULIA B; CHERNOV BORIS K 权利人:UCHICAGO ARGONNE LLC 摘要:New modifiers were synthesized for incorporation of a methacrylic function in 3′-, 5′- and internal positions of oligonucleotides during solid phase synthesis. A modifier was used for synthesis of 5′-methacrylated oligonucleotides for preparation of microarrays by a co-polymerization method.
专利号:US-6512081-B1 优先权日:1997-07-21 标题:Synthesis of dithioester chain transfer agents and use of bis(thioacyl) disulfides or dithioesters as chain transfer agents 发明人:RIZZARDO ENZIO; THANG SAN HOA; MOAD GRAEME 权利人:E I DUPONT NEMOURS AND COMPANY; COMMW SCIENT IND RES ORG 摘要:This invention relates to the synthesis of dithiocarboxylic acid esters by reaction of bis(thioacyl) disulphides, thioacetals or vinylidane bis(thioether) with free-radicals (optionally in the presence of monomers). The invention also relates to processes for the synthesis of polymers utilising these dithioesters as polymerisation regulators (chain transfer agents) or to the use of bis(thioacyl) disulphides to generate dithioester chain transfer agents in situ.
专利号:US-10732109-B2 优先权日:2017-11-28 标题 :Core-shell type nanosilica fluorescent probe and synthesis method and use thereof 发明人:XU MEIYING; LIU FEI; LIAO BING; LUO YESHEN; LI ENZE 权利人:GUANGDONG INST MICROBIOLOGY GUANGDONG DETECTION CT MICROBIOLOGY; GUANGDONG ACAD OF SCIENCES 摘要:Disclosed are a core-shell type nanosilica fluorescent probe and a synthesis method thereof, wherein the core-shell type nanosilica fluorescent probe is a nanoparticle with a core-shell structure. Also disclosed is a method using the core-shell type nanosilica fluorescent probe for selection of functional microorganisms having toxic aromatic hydrocarbon degrading activity, wherein the method enables efficient, intuitive and rapid specificity sorting and analyzing of individual cells with high sensitively.
专利号:US-6100350-A 优先权日:1996-02-23 标题 :Branched polymer synthesis 发明人:WILCZEK LECH; MCCORD ELIZABETH FORRESTER 权利人:DU PONT; COMMW SCIENT IND RES ORG 摘要:PCT No. PCT/US97/02913 Sec. 371 Date Aug. 19, 1998 Sec. 102(e) Date Aug. 19, 1998 PCT Filed Feb. 18, 1997 PCT Pub. No. WO97/31031 PCT Pub. Date Aug. 28, 1997This invention relates to a process for the synthesis of addition polymers containing branches upon branches and having a polymerizable olefin end group by a convenient one-pot copolymerization of selected vinyl monomers with chain polymerization initiators and a method to provide olefin end groups by chain transfer or termination agents; and polymers produced thereby.
专利号:US-6291620-B1 优先权日:1994-11-09 标 题:Polymer synthesis 发明人:MOAD GRAEME; MOAD CATHERINE LOUISE; KRSTINA JULIA; RIZZARDO EZIO; DARLING THOMAS ROBERT; BERGE CHARLES THOMAS 权利人:DU PONT; COMMW SCIENT IND RES ORG 摘要:Process for the synthesis of block polymers, homopolymers and copolymers of narrow polydispersity having formula (1) by contacting selected vinyl monomer(s), vinyl-terminated compound(s) and free radicals in which effective control of production of polymer is achieved by controlling the mole ratio of vinyl monomer(s), vinyl-terminated compound(s) and free radicals relative to one another; and polymers produced thereby
专利号:US-2024010511-A1 优先权日:2019-05-02 标 题 :Methods and compositions for synthesis of phosphor and its incorporation in a polymer matrix for light conversion 发明人:SAHI SUNIL 权利人:SOLGO INC; SOLGRO INC 摘要:The invention relates to methods and compositions for synthesizing a phosphor and preparing a surface-modified phosphor comprising a phosphor, a silica, and a silane, and articles comprising same. The invention also relates to a method of dispersion of the disclosed surface-modified phosphor with a blue emitting agent in a polymer matrix and uses thereof.
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合成参考文献
参考文献:10.3290/j.jad.a17857 摘要:Ozcan M, Cura C, Brendeke J. Effect of aging conditions on the repair bond strength of a microhybrid and a nanohybrid resin composite. J Adhes Dent. 2010 Dec;12(6):451–9. doi: 10.3290/j.jad.a17857. 参考文献:10.3290/j.jad.a17538 摘要:Vuorinen AM, Dyer SR, Vallittu PK, Lassila LV. Bonding of composite resin to dentin using rigid rod polymer modified primers. J Adhes Dent. 2010 Jun;12(3):175–82. doi: 10.3290/j.jad.a17538. 参考文献:10.4012/dmj.2011-012 摘要:Ikemura K, Tanaka H, Fujii T, Deguchi M, Negoro N, Endo T, Kadoma Y. Design of a new, multi-purpose, light-curing adhesive comprising a silane coupling agent, acidic adhesive monomers and dithiooctanoate monomers for bonding to varied metal and dental ceramic materials. Dent Mater J. 2011;30(4):493–500. doi: 10.4012/dmj.2011-012. 参考文献:10.4012/dmj.2011-011 摘要:Akimoto N, Sakamoto T, Kubota Y, Kondo Y, Momoi Y. A novel composite-to-composite adhesive bond mechanism. Dent Mater J. 2011;30(4):523–7. doi: 10.4012/dmj.2011-011. 参考文献:10.4012/dmj.2010-202 摘要:Hamano N, Chiang YC, Nyamaa I, Yamaguchi H, Ino S, Hickel R, Kunzelmann KH. Effect of different surface treatments on the repair strength of a nanofilled resin-based composite. Dent Mater J. 2011;30(4):537–45. doi: 10.4012/dmj.2010-202.