CAS: 17154-34-6; Diphenyl(Trimethylsilyl)Phosphine

该化合物是一种有机磷化合物,在磷中心有苯和三甲基硅替代物,这种试剂因其在合成化学中的效用而具有价值,特别是作为磷离子或前体在金属催化和有机金属反应过渡过程中的效用.三甲基硅组增强了它的稳定性和反应性,使之适合受控磷转移反应.它的性能和电子特性促进了交叉相交和核循环替代过程中的选择性转变.该化合物由于其空气和水分敏感性的性质,通常在惰性条件下处理,其在磷基合成中的多功能使得它成为先进的有机和无机应用的有用工具.

结构式图片

相似化合物

6002-34-2 2129-89-7 6372-40-3

欧盟法规

ECHA物质C&L通报

上下游产品

chloro-trimethyl-silane triphenylphosphine diphenylphosphane dibenzofurandiphenylphosphanyl-acetonitrile [(N,N-dimethylamino)methyl]diphenylphosphine Diphenyl-(3,3,3-trifluoro-2-trimethylsilanyloxy-propyl)-phosphane Diphenyl-(3,3,3-trichloro-2-trimethylsilanyloxy-propyl)-phosphane

合成工艺路线路线简述

    三甲基氯硅烷,二苯基氯化膦置于lithium体系中,用 四氢呋喃 用作溶剂,化学反应 3.5H,反应生成二苯基(三甲基硅基)膦
    参考文献:Fluorescence Enhancement By Hydroperoxides Based On A Change In The Intramolecular Charge Transfer Character Of Benzofurazan
    标题:Fluorescence Enhancement By Hydroperoxides Based On A Change In The Intramolecular Charge Transfer Character Of Benzofurazan
    摘要:新型试剂与氢过氧化物反应后,观测到强烈的荧光信号.
    Doi:10.1039/b500419E

    海关参考信息

    专利信息


    专利号:WO-2008131270-A1
    优先权日:2007-04-18
    标题:Method for generating alkali metal phosphides through reduction of tri-substituted phosphines with alkali metal porous oxide compositions
    发明人:LEFENFELD MICHAEL; DYE JAMES L; NANDI PARTHA; JACKSON JAMES
    权利人:SIGNA CHEMISTRY LLC; UNIV MICHIGAN STATE; LEFENFELD MICHAEL; DYE JAMES L; NANDI PARTHA; JACKSON JAMES
    摘要:Alkali metal phosphides are useful intermediates for the synthesis of a variety of phosphine derivatives. Many of these phosphine derivatives are important industrial compounds with applications as synthetic intermediates or as ligands in a variety of homogeneous and heterogeneous synthetic processes. Alkali metal diarylphosphides in particular have been used in the synthesis of many phosphine ligands of importance. The invention relates to methods for generating and using alkali metal phosphides by reduction of the phosphorus sigma bonds of tri-substituted phosphorus derivatives with Group I metal/porous oxide compositions. Formula (I).

    专利号:US-12291489-B2
    优先权日:2016-07-01
    标 题 :Synthesis of nanocomposites and their use in enhancing plant nutrition
    发明人:BISWAS PRATIM; RALIYA RAMESH
    权利人:BISWAS PRATIM; RALIYA RAMESH; WASHINGTON UNIVERSITY ST LOUIS
    摘要:The present disclosure is related to the development of improved fertilizer for precision and sustainable agriculture. A method was developed wherein efficient NPK nanocomposite for plant nutrition was synthesized in a single step using aerosol science and technology concepts. Further a formulation was prepared by addition of ZnO, TiO 2 and other nanoparticles to the NPK nanocomposite. Also, an aerosol based foliar application technique was developed for the precise delivery of nanoparticles to the plants.

    专利号:US-2019202750-A1
    优先权日:2016-07-01
    标 题 :Synthesis of nanocomposites and their use in enhancing plant nutrition

    专利号:WO-2018005930-A1
    优先权日:2016-07-01
    标题:Synthesis of nanocomposites and their use in enhancing plant nutrition

    专利号:US-8975269-B2
    优先权日:2009-08-31
    标 题 :Six-membered N-heterocyclic carbene-based catalysts for asymmetric reactions
    发明人:MCQUADE D TYLER; PARK JIN KYOON; REXFORD MATTHEW D; LACKEY HERSHEL H
    权利人:UNIV FLORIDA STATE RES FOUND
    摘要:The present invention provides a catalyst complex or ligand, and compositions thereof, for use in a variety of organic reactions having high reactivity and enantioselectivity. The catalyst is a N-heterocyclic carbene having three fused rings with first and second rings being six-membered rings and the third being a five-membered ring. The first ring is fused to the second and has four substituents. The second ring has two nitrogens flanking a carbene atom with one nitrogen bound to a substituent. The carbene atom may optionally be bonded to a metal. The third ring is fused to the second ring and contains two nitrogens. The third ring of the catalyst has a double bond and two substituents on adjacent non-fused carbons. A non-fused nitrogen of the third ring is partially bonded to another substituent. Methods for the synthesis and use of the catalyst embodiments of the present invention are also provided.

    专利号:CN-118440115-A
    优先权日:2024-05-23
    标题 :Asymmetric synthesis method of axial chiral biaryl-aryl phosphine oxide
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    合成参考文献


    摘要:Hayashi, M., Science of Synthesis Knowledge Updates, (2013) 2, 174.
    摘要:Hayashi, M., Science of Synthesis Knowledge Updates, (2013) 2, 185.
    摘要:Hayashi, M., Science of Synthesis Knowledge Updates, (2013) 2, 188.
    摘要:Landais, Y., Science of Synthesis Knowledge Updates, (2013) 3, 60.
    摘要:Landais, Y., Science of Synthesis Knowledge Updates, (2013) 3, 65.
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