CAS: 344790-87-0; 1-Butyl-3-Methylimidazolium Thiocyanate

该化合物是一种有硫氰酸亚离子离子和基碳化的离子液体,这种化合物在极地溶剂和非极地溶剂中都具有高度的热稳定性,低粘度和高溶解性,因此适合在催化,电化学和分离过程中应用,其硫氰酸盐的混合物能够与金属离子进行协调,促进金属提取和合成化学反应介质的使用,该离子还显示出有利的导导性,这在电化学装置中具有优势,由于其可调料特性和可忽略的蒸气压力,[BMIM][SCN]被认为是工业和研究环境中传统挥发性有机溶剂的一种绿色替代品.

结构式图片

相似化合物

65039-05-6 79917-90-1 85100-77-2

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CAS号284049-75-8 1-丁基-3-甲基咪唑醋酸盐 | CAS号540-72-7 硫氰酸钠 | CAS号79917-90-1 氯化(1-丁基-3-甲基咪唑) | CAS号333-20-0 硫氰酸钾 | CAS号65039-05-6 1-丁基-3-甲基碘化咪唑鎓 | CAS号200621-67-6 [2-(furan-2-yl)... | CAS号21486-46-4 (1-oxo-1-phenyl... | CAS号19203-00-0 1,2-diphenyl-2-... | CAS号65679-14-3 4-溴苯甲酰基硫氰酸盐 | CAS号6097-27-4 2-(4-甲基苯基)-2-氧代硫氰酸乙酯 | CAS号6097-26-3 1-(4-甲氧基苯基)-2-硫... | CAS号5399-30-4 苯乙酰基硫氰酸酯 | CAS号19339-59-4 4-氯苯甲酰甲基硫氰酸酯 | CAS号19942-78-0 硫氰酸辛酯

合成工艺路线路线简述

    1-丁基-3-甲基碘化咪唑置于amberlist A-26 Scn(-) Form体系中,用 甲醇 用作溶剂,化学反应生成1-丁基-3-甲基咪唑硫氰酸盐
    参考文献:Imidazolium Ionic Liquids: A Simple Anion Exchange Protocol
    标题:Imidazolium Ionic Liquids: A Simple Anion Exchange Protocol
    摘要:开发了一种高效且简单的协议,用于在咪唑盐离子液体中广泛阴离子范围的碘化物或溴化物定量交换.通过两种不同的程序将选定的阴离子加载到阴离子交换树脂中,随后用于提供纯化便利的离子对.
    Doi:10.1039/b915743N

    海关参考信息

    专利信息


    专利号:US-2010191010-A1
    优先权日:2007-07-02
    标题 :Process for the synthesis of carbamates using co2
    发明人:BOSMAN JORIS KAREL PETER; CARR ROBERT HENRY
    权利人:HUNTSMAN INT LLC
    摘要:Process for the synthesis of non cyclic carbamate derivatives from amine compounds, alcohols and CO 2 in the presence of ionic liquids and optionally in the presence of a base.

    专利号:US-9512080-B2
    优先权日:2012-07-10
    标 题:Synthesis of acridinium compounds by N-alkylation of acridans
    发明人:NATRAJAN ANAND; WEN DAVID
    权利人:SIEMENS HEALTHCARE DIAGNOSTICS INC
    摘要:A method is provided for N-alkylation of acridine compounds by reduction of acridines to corresponding acridans to improve the reactivity of the acridine nitrogen, and subsequent N-alkylation of the acridans in ionic liquid solvents to provide the corresponding acridinium compounds in high yield. This inventive process improves chemical conversion, and does not require the use of highly toxic alkylating agents, such as 1,3-propane sultone.

    专利号:US-12392085-B2
    优先权日:2020-04-28
    标题 :Use of in-situ ionic liquid (IL) and deep eutectic solvent (DES) synthesis using chemically synthesized or biomass-derived ions in the pretreatment of biomass
    发明人:MAGURUDENIYA HARSHA D; ACHINIVU EZINNE; SIMMONS BLAKE A; GLADDEN JOHN M
    权利人:UNIV CALIFORNIA; NATIONAL TECH AND ENGINEERING SOLUTIONS OF SANDIA LLC; NAT TECH & ENG SOLUTIONS SANDIA LLC
    摘要:The present invention provides for a method to deconstruct a biomass comprising: (a) introducing one or more individual components of an ionic liquid (IL) or deep eutectic solvent (DES) to a biomass, wherein the one or more individual components, and optionally any components already present in the biomass, form an IL or DES, or mixture thereof, which solubilizes the biomass to form a solubilized biomass mixture, wherein at least one individual component is introduced to the biomass separately from any other individual component; (b) optionally introducing an enzyme and/or a microbe to the solubilized biomass mixture such that the enzyme and/or microbe produces a sugar from the solubilized biomass mixture; and, (c) optionally separating the sugar from the solubilized biomass mixture.

    专利号:US-2014001420-A1
    优先权日:2011-09-30
    标题 :Method of preparing metal nanoparticles
    发明人:DRZAL LAWRENCE T; DO IN-HWAN
    权利人:DRZAL LAWRENCE T; DO IN-HWAN
    摘要:A method for the synthesis of new metal based metal nanoparticles by the combination of conducting polymers and room temperature ionic liquids to produce nanoparticle electro-catalysts with very high catalytic activity and controllable size and high surface area to volume ratios.

    专利号:US-9765044-B2
    优先权日:2013-03-15
    标 题 :Synthesis of novel ionic liquids from lignin-derived compounds
    发明人:SOCHA AARON; SINGH SEEMA; SIMMONS BLAKE A; BERGERON MAXIME
    权利人:UNIV CALIFORNIA; SANDIA CORP
    摘要:Methods and compositions are provided for synthesizing ionic liquids from lignin derived compounds comprising: contacting a starting material comprising lignin with a depolymerization agent to depolymerize the lignin and form a mixture of aldehyde containing compounds; contacting the mixture of aldehyde containing compounds with an amine under conditions suitable to convert the mixture of aldehyde containing compounds to a mixture of amine containing compounds; and contacting the mixture of amine containing compounds with an acid under conditions suitable to form an ammonium salt, thereby preparing the ionic liquid.

    专利号:US-11053439-B2
    优先权日:2019-02-05
    标题:Methods for synthesis of inorganic nanostructures using molten salt chemistry
    发明人:CURLEY JOHN J; TU ALEXANDER; GUO WENZHOU; WANG CHUNMING; IPPEN CHRISTIAN; HOTZ CHARLES
    权利人:NANOSYS INC
    摘要:The invention relates to highly luminescent nanostructures with strong blue light absorbance, particularly core/shell nanostructures comprising an In(1-x)GaxP core and ZnSe and/or ZnS shell layers, wherein 0
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    主要参考文献

    [参考文献]: Daisuke Sugioka, Et Al. Single-Step Preparation Of Two-Dimensionally Organized Gold Particles Via Ionic Liquid/metal Sputter Deposition. Phys Chem Chem Phys. 2015 May 21;17(19):13150-9.

    合成参考文献


    参考文献:10.1007/978-981-16-5395-7_7
    摘要:Shirota H. Intermolecular Vibrations in Aprotic Molecular Liquids and Ionic Liquids. 2021. In: Physical Chemistry in Action.
    参考文献:10.1007/s12274-023-5403-x
    摘要:Zhu M, Xia Y, Qin L, Zhang K, Liang J, Zhao C, Hong D, Jiang M, Song X, Wei J, Zhang P, Tian Y, Jin Z. Reducing surficial and interfacial defects by thiocyanate ionic liquid additive and ammonium formate passivator for efficient and stable perovskite solar cells. Nano Res. 2023 Jan 21;16(5):6849–58. doi: 10.1007/s12274-023-5403-x.
    参考文献:10.1007/s10953-022-01226-3
    摘要:Zhang L, Zhang T, Wang Y, Jiang B, Wu Y, Wang Z, Ge M, Long-Huang, Jiao Y. Thermodynamics and Activity Coefficients at Infinite Dilution for Organic Solutes in Trialkyl-Substituted Imidazolium-Based Ionic Liquid 1-Propyl-2,3-dimethylimidazolium Thiocyanate. J Solution Chem. 2022 Dec 17;52(2):147–65. doi: 10.1007/s10953-022-01226-3.
    参考文献:10.1007/978-981-99-5509-1_6
    摘要:Sahu L, Mishra S. Applications of Ionic Liquids in Solvent Extraction of Optically Active Metals Gallium and Indium-An Overview. 2023. In: Springer Proceedings in Materials.
    参考文献:10.1007/978-3-031-62574-9_9
    摘要:Ercan KE, Yurtseven MA, Yilmaz C. Development of Mono and Bipropellant Systems for Green Propulsion Applications. 2024. In: Space Technology Library.
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