CAS: 12257-42-0; Bicyclo[2.2.1]Hepta-2,5-Diene-Rhodium(I) Chloride Dimer

该化合物是一种高效的基催化剂,含有44.0%的按重量计的,这种有机金属化合物因其在循环添加和聚合反应中的稳定性和回活动性而特别受到重视,其角体结构提高了催化性能,提供了较高的选择性和在复杂的有机变异中的产量.高含量确保了同质催化活动的最佳活动,使它成为精细化学合成和学术研究的首选.它与一系列溶剂和子质的兼容性进一步扩大了其在专门应用中的效用.建议在惰性条件下进行适当的惰性处理以保持其催化性.

英文名称Bicyclo[2.2.1]Hepta-2,5-Diene-Rhodium(I) Chloride Dimer
中文名称氯降冰片二烯铑二聚体
IUPAC名称bis(bicyclo[2.2.1]hepta-2,5-diene);rhodium(2+);dichloride
其它别名(Bicyclo[2.2.1]Hepta-2,5-Diene)Chlororhodium(I) Dimer; Bicyclo[2.2.1]Hepta-2,5-Diene; Rhodium(2+); Dichloride; Bis((2,3,5,6-Eta)-Bicyclo(2.2.1)Hepta-2,5-Diene)Di-Mu-Chlorodirhodium; Rhodiu
CAS编号12257-42-0
MFCD编号:MFCD00198060
EINECS号:235-510-4
分子式:C14H16Cl2Rh
分子量:460.99
产品CID: 323366
产品分类有机原料 → 有机金属类化合物 → 有机铑

相似结构搜索
产品信息参考;
InChIKey: HCZNBZKRJTYNCE-UHFFFAOYSA-L
InChI=1S/2C7H8.2ClH.Rh/c2*1-2-7-4-3-6(1)5-7;;;/h2*1-4,6-7H,5H2;2*1H;/q;;;;+2/p-2…
计算化学: 氢键受体数2.0氢键供体数0.0可旋转键数0.0

物理性质

熔点239-241 °C (分解)
沸点89.5 °C at 760 mmHg
闪点 °C
密度3>g/ cm3
PSA:0.0
LogP:4.2856
蒸汽压66mmHg at 25°C
溶解性Sol Chloroform And Benzene; Insol Ether And Light Petroleum
敏感性常温常压下稳定避免的物料氧化物水分 / 潮湿
外观形态黄色至橙色粉末
储存条件2-8°C
产品应用该化合物用于在油脂水成,油脂氢化和油脂异构体化中的催化剂.

MSDS等安全信息

GHS象形图
GHS符号GHS02 & GHS07;
注释: Flame & Exclamation mark
危险类别易燃固体类别1
Self-heat. 1
急性毒性类别4(吸入)
急性毒性类别4(经皮)
急性毒性类别4(经口)
皮肤腐蚀/刺激类别2
严重眼刺激类别2
水生慢性毒性类别4
警示词Danger(危险)
危险描述H228 |易燃固体.
H251 |自热:可能起火.
H332 |吸入有害.
H312 |皮肤接触有害.
H302 |吞咽有害.
H315 |造成皮肤刺激.
H319 |造成严重眼刺激.
H413 |可能对水生生物造成长期有害影响.
防范说明P304+P340-P305+P351+P338-P405-P501a-P261-P280a
危险品标志Xi,Xn
安全声明37/39-26
危险类别码36/37/38
WGK Germany3

欧盟法规

ECHA物质C&L通报REACH预注册

上下游产品

CAS号81229-44-9 | CAS号204906-22-9 bicyclo[2.2.1]h...

合成工艺路线路线简述

专利信息

专利号:US-7230135-B2
优先权日:2000-12-13
标题 :Synthesis of P-chiral bisphospholane ligands and their transition metal complexes for use as asymmetric hydrogenation catalysts
发明人：HOGE II GARRETT STEWART; GOEL OM PRAKASH
权利人:WARNER LAMBERT CO
摘要:P-chiral bisphospholane ligands and methods for their preparation are described. Use of metal/P-chiral bisphospholane complexes to catalyze asymmetric transformation reactions to provide high enantiomeric excesses of formed compounds is also described.

专利号:US-2003236433-A1
优先权日:2000-12-13
标题 :Synthesis of P-chiral bisphospholane ligands and their transition metal complexes for use as asymmetric hydrogenation catalysts

专利号:US-2004215027-A1
优先权日:2000-12-13
标题 :Synthesis of P-chiral bisphospholane ligands and their transition metal complexes for use as asymmetric hydrogenation catalysts

专利号:US-2002087017-A1
优先权日:2000-12-13
标题 :Synthesis of P-chiral bisphospholane ligands and their transition metal complexes for use as asymmetric hydrogenation catalysts

专利号:US-6605745-B2
优先权日:2000-12-13
标题:Synthesis of P-chiral bisphospholane ligands and their transition metal complexes for use as asymmetric hydrogenation catalysts

专利号:US-6750171-B2
优先权日:2000-12-13
标题:Synthesis of P-chiral bisphospholane ligands and their transition metal complexes for use as asymmetric hydrogenation catalysts